Thermal barrier coating containing reactive protective materials and method for preparing same
    94.
    发明授权
    Thermal barrier coating containing reactive protective materials and method for preparing same 失效
    含有反应性保护材料的热障涂层及其制备方法

    公开(公告)号:US07226668B2

    公开(公告)日:2007-06-05

    申请号:US10317759

    申请日:2002-12-12

    IPC分类号: B32B15/04 F03B3/12

    摘要: A thermal barrier coating for an underlying metal substrate of articles that operate at, or are exposed to, high temperatures, as well as being exposed to environmental contaminant compositions. This coating comprises an inner layer nearest to the underlying metal substrate comprising a ceramic thermal barrier coating material, as well as an outer layer having an exposed surface and comprising a CMAS-reactive material in an amount up to 100% and sufficient to protect the thermal barrier coating at least partially against CMAS that becomes deposited on the exposed surface, the CMAS-reactive material comprising an alkaline earth aluminate or alkaline earth aluminosilicate where the alkaline earth is selected from barium, strontium and mixtures thereof, and optionally a ceramic thermal barrier coating material. This coating can be used to provide a thermally protected article having a metal substrate and optionally a bond coat layer adjacent to and overlaying the metal substrate. The thermal barrier coating can be prepared by forming the inner layer of the ceramic thermal barrier coating material, followed by depositing the CMAS-reactive material, or codepositing the CMAS-reactive material and the ceramic thermal barrier coating material, to form the outer layer.

    摘要翻译: 用于在高温下操作或暴露于高温以及暴露于环境污染物组合物的制品的基础金属基底的热障涂层。 该涂层包括最接近下面的金属基底的内层,其包括陶瓷热障涂层材料,以及具有暴露表面的外层,并且包含高达100%量的CMAS反应性材料,并足以保护热 至少部分地抵抗沉积在暴露表面上的CMAS的阻挡涂层,CMAS反应性材料包含碱土金属铝酸盐或碱土金属硅铝酸盐,其中碱土选自钡,锶及其混合物,以及任选的陶瓷热障涂层 材料。 该涂层可用于提供具有金属基底和任选的与金属基底相邻并覆盖金属基底的粘合涂层的热保护制品。 可以通过形成陶瓷热障涂层材料的内层,然后沉积CMAS反应性材料或共沉积CMAS反应性材料和陶瓷热障涂层材料来形成外层来制备热障涂层。

    Corrosion resistant sealant for outer EBL of silicon-containing substrate and processes for preparing same
    95.
    发明申请
    Corrosion resistant sealant for outer EBL of silicon-containing substrate and processes for preparing same 审中-公开
    含硅基材外层EBL用耐腐蚀密封剂及其制备方法

    公开(公告)号:US20060280954A1

    公开(公告)日:2006-12-14

    申请号:US11150099

    申请日:2005-06-13

    摘要: An article comprising a silicon-containing substrate, an environmental barrier coating (EBC) overlying the substrate, wherein the EBC comprises a higher metal silicate-containing outer barrier layer; and a corrosion resistant alumina/aluminate sealant for the higher metal silicate-containing outer barrier layer. A process is also provided for forming a corrosion resistant alumina/aluminate sealant layer over the higher metal silicate-containing outer barrier layer. Also provided is an alternative process for treating a porous higher metal silicate-containing outer barrier layer with a liquid composition comprising an corrosion resistant alumina/aluminate sealant precursor to infiltrate the porous higher metal silicate-containing outer barrier layer with the alumina/aluminate sealant precursor in an amount sufficient to provide, when converted to the corrosion resistant alumina/aluminate sealant, protection of the environmental barrier coating against environmental attack; and converting the infiltrated alumina/aluminate sealant precursor within the porous higher metal silicate-containing outer barrier layer to the corrosion resistant alumina/aluminate sealant.

    摘要翻译: 一种制品,其包含含硅基材,覆盖所述基材的环境阻挡涂层(EBC),其中所述EBC包含较高含金属硅酸盐的外阻挡层; 和用于较高含金属硅酸盐的外阻挡层的耐腐蚀氧化铝/铝酸盐密封剂。 还提供了一种用于在高含金属硅酸盐的外阻挡层上形成耐腐蚀氧化铝/铝酸盐密封剂层的方法。 还提供了一种用含有耐腐蚀氧化铝/铝酸盐密封剂前体的液体组合物来处理含多孔的高含金属硅酸盐的外部阻隔层的替代方法,以用氧化铝/铝酸盐密封剂前体渗透含多孔的高含金属硅酸盐的外部阻隔层 其量足以提供,当转化为耐腐蚀的氧化铝/铝酸盐密封剂时,保护环境屏障涂层免受环境攻击; 并将渗透的含氧化铝/铝酸盐密封剂前体在含多孔高含金属硅酸盐的外阻挡层内转化成耐蚀氧化铝/铝酸盐密封剂。

    Thermal/environmental barrier coating for silicon-comprising materials
    98.
    发明申请
    Thermal/environmental barrier coating for silicon-comprising materials 审中-公开
    含硅材料的热/环境屏障涂层

    公开(公告)号:US20060166019A1

    公开(公告)日:2006-07-27

    申请号:US11040991

    申请日:2005-01-21

    IPC分类号: B32B15/04 B32B15/00

    摘要: An article comprising a substrate formed of a silicon-comprising material, such as an article exposed to the hostile thermal environment of a gas turbine engine. The article further comprises an environmental barrier layer formed by chemical vapor deposition and comprising mullite and alumina, and a top coat comprising alumina, stabilized zirconia or stabilized hafnia, wherein the zirconia or hafnia is stabilized with an oxide of a metal selected from the group consisting of magnesium, calcium, scandium, yttrium, and lanthanide metals, and mixtures thereof. The environmental barrier layer is compositionally graded and consists essentially of mullite at an interface of the environmental barrier layer with the substrate, and consists essentially of alumina at an interface of the environmental barrier layer with the top coat, the environmental barrier layer having a decreasing concentration of mullite and an increasing concentration of alumina in a direction away from the substrate. A method for preparing a thermal/environmental barrier coating on a substrate formed of a silicon-comprising material is also disclosed.

    摘要翻译: 一种制品,其包括由含硅材料形成的基底,例如暴露于燃气涡轮发动机的恶劣热环境的制品。 该制品还包括通过化学气相沉积形成并包括莫来石和氧化铝的环境屏障层,以及包含氧化铝,稳定的氧化锆或稳定的铪的面漆,其中所述氧化锆或铪被选自以下的金属的氧化物稳定: 的镁,钙,钪,钇和镧系金属,以及它们的混合物。 环境阻挡层在组成上是梯度的,并且基本上由环氧屏障层与基底的界面处的莫来石组成,并且在环境阻挡层与顶涂层的界面处基本上由氧化铝组成,环境阻挡层具有降低的浓度 的莫来石和在远离基底的方向上增加的氧化铝浓度。 还公开了在由含硅材料形成的基底上制备热/环境屏障涂层的方法。