Abstract:
Azo dyes of the formula ##STR1## where L.sup.1 is hydrogen, C.sub.1 -C.sub.8 -alkyl or phenyl,L.sup.2 and L.sup.3 are each substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl, or together a radical of the formula ##STR2## where n is 0, 1 or 2, Y.sup.1 and Y.sup.4 are hydrogen, hydroxymethyl, 1,2-dihydroxyethyl or a radical of the formula COO.sym.M.sup..crclbar. or SO.sub.3.sup..crclbar. M.sup..sym., Y.sup.2 and Y.sup.3 are halogen or hydroxymethyl, and M.sup..sym. is the equivalent of a cation,L.sup.4 is hydrogen, substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl, substituted or unsubstituted phenyl, halogen, C.sub.1 -C.sub.8 -alkoxy, substituted or unsubstituted phenoxy, C.sub.1 -C.sub.8 -alkylthio, C.sub.1 -C.sub.8 -alkylsulfonyl, substituted or unsubstituted phenylthio, substituted or unsubstituted phenylsulfonyl, C.sub.1 -C.sub.8 -alkoxycarbonyl, C.sub.3 -C.sub.6 -alkenyloxycarbonyl or phenoxycarbonyl,X is nitrogen or the radical C--L.sup.5, where L.sup.5 is as defined in the specification,K is the radical of a coupling component, andnovel crystal forms of thienylazobenzene dyes are useful for dyeing or printing textile materials.
Abstract:
An adjustably positionable pivot joint connection assembly for wheel guide arms in motor vehicles For the purpose of centering connection bolts in oblong holes, the latter are provided with centering snugs arranged on their end faces and directed towards one another. The centering snugs engage the bolt to hold it in its center position in certain rotative positions of the bolt. The bolt includes a longitudinally extending notch which engages over one of the centering snugs when in an end position of the oblong hole, rotated so the notch is aligned with the snug.
Abstract:
Dye mixtures comprising at least six isochromatic dyes of the formula ##STR1## where D is the radical of a diazo component of the aniline, aminothiophene, aminothiazole, aminoisothiazole or aminobenzisothiazole series andone of the radicals X.sup.1 and X.sup.2 is amino and the other is a radical of the formula ##STR2## where L is unsubstituted or substituted C.sub.2 -C.sub.8 -alkyleneR.sup.1 is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl andR.sup.2 is hydrogen, C.sub.1 -C.sub.4 -alkyl, benzyl, phenyl, or C.sub.1 -C.sub.8 -alkanoyl,and the use thereof for dyeing or printing textile materials, and dye mixtures comprising thienylazopyridine dyes and anthraquinone dyes and the use thereof for dyeing or printing textile materials.
Abstract:
There are described dye mixtures containinga) an azo dye of the formula I ##STR1## where Hal is chlorine or bromine, b) the azo dye of the formula II ##STR2## where L is allyl or optionally hydrogen, and c) an azo dye of the formula III and/or IV ##STR3## where R.sup.1 is nitro or substituted or unsubstituted C.sub.1 -C.sub.4 -alkylsulfonyl,R.sup.2 and R.sup.3 are each hydrogen, chlorine or bromine,R.sup.4 and R.sup.5 are each hydrogen or chlorine,R.sup.6 and R.sup.7 are each hydrogen, phenyl or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl,X.sup.1 is hydrogen, hydroxyl, methoxy, acetylamino or nitro,X.sup.2, X.sup.3, X.sup.4 and X.sup.5 are each hydrogen, methyl or methoxy, andX.sup.6 is hydroxyl, 2-hydroxyethoxy, formyl or methoxycarbonylamino,dye preparations containing the novel dye mixtures, and the use of the novel dye mixtures for dyeing or printing polyesters in textile form.
Abstract:
Azo dyes useful for dyeing natural or synthetic substrates have the formula ##STR1## where n is from 1 to 4,q is 1 or 2,L.sup.1 is hydrogen or C.sub.1 -C.sub.3 -alkyl,L.sup.2 is acetyl, carbamoyl or hydroxysulfonyl, andD is the radical of a diazo component.
Abstract:
Azo dyes useful for dyeing or printing textile fibers or fabrics and for thermal transfer have the formula ##STR1## where R.sup.1 and R.sup.2 are each substituted or unsubstituted C.sub.1 -C.sub.10 -alkyl or substituted or unsubstituted C.sub.3 -C.sub.4 -alkenyl or R.sup.1 may also be hydrogen,R.sup.3 is hydrogen or C.sub.1 -C.sub.6 -alkyl,R.sup.4 and R.sup.5 are each hydrogen, C.sub.1 -C.sub.6 -alkyl, halogen, C.sub.1 -C.sub.6 -alkoxy, amino or mono- or di(C.sub.1 -C.sub.4 -alkyl)amino, andD is a radical of the thiophene, thiazole, isothiazole, benzothiophene, thienothiophene or thienothiazole series.
Abstract:
A process for preparing polyaryl ethers of the formula I or Ia ##STR1## by condensation of at least one appropriate bisphenol with at least one appropriate aromatic dichloride in the presence of an alkali metal carbonate in a dipolar aprotic solvent, is carried out in the presence of a catalyst selected from the alkali metal nitrites and the group of compounds of the formula II ##STR2## where r.sup.1 and r.sup.3 are each hydrogen, C.sub.7 -C.sub.16 -phenylalkyl, C.sub.1 -C.sub.12 -alkoxy, fluorine, chlorine, bromine, iodine or nitro, and R.sup.2 is nitro or nitroso, or ##STR3## where R.sup.4 is hydrogen, C.sub.1 -C.sub.4 alkyl, fluorine, chlorine, bromine or iodine.
Abstract:
Azo dyes useful for marking mineral oils have the formula ##STR1## where R.sup.1 and R.sup.2 are hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sup.3 is hydrogen or C.sub.1 -C.sub.8 -alkyl which may be substituted by hydroxyl and interrupted by from 1 to 3 oxygen atoms,R.sup.4 is C.sub.1 -C.sub.8 -alkyl which may be substituted by hydroxyl and interrupted by from 1 to 3 oxygen atoms, andX is cyano or substituted or unsubstituted C.sub.1 -C.sub.8 -alkoxycarbonyl,with the proviso that the molecule contains at least one hydroxyalkyl radical.
Abstract:
A process for the preparation of aromatic carbonyl or sulfonyl compounds with a diaryl ether structure by reacting phenols with halogenated carbonyl- or sulfonylaromatic compounds in a dipolar aprotic solvent is carried out in the presence of catalytic amounts of alkali metal nitrite or an aromatic nitro, nitroso, azo, azoxy or hydrazo compound.