公开(公告)号：US06821583B2

公开(公告)日：2004-11-23

申请号：US10189169

申请日：2002-07-03

申请人： Grant Thomas Donald Shouldice ,  Shashikant Saraiya ,  Xing-Fu Zhong ,  Richard R. Durand, Jr. ,  Jianbing Huang ,  Patrick Friedman

发明人： Grant Thomas Donald Shouldice ,  Shashikant Saraiya ,  Xing-Fu Zhong ,  Richard R. Durand, Jr. ,  Jianbing Huang ,  Patrick Friedman

IPC分类号： B32B2730

CPC分类号： B41M5/506 ,  B41C1/1016 ,  B41C2210/02 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  B41M5/52 ,  B41M5/5227 ,  B41M2205/12 ,  B41M2205/38 ,  Y10T428/24802 ,  Y10T428/31699 ,  Y10T428/31855 ,  Y10T428/31928 ,  Y10T428/31935 ,  Y10T428/31938

摘要： The present invention provides an imageable element, which includes: a substrate; a crosslinked layer disposed on the substrate; and an imageable ink-receptive layer disposed on the crosslinked layer, the imageable ink-receptive layer including an ablation free imageable composition. The present invention provides methods of producing the above imaged element.

摘要翻译： 本发明提供一种可成像元件，其包括：基板; 设置在所述基板上的交联层; 以及设置在所述交联层上的可成像的油墨接收层，所述可成像的墨接受层包括无消融成像的组合物。 本发明提供了制造上述成像元件的方法。

公开(公告)号：US06787281B2

公开(公告)日：2004-09-07

申请号：US10155696

申请日：2002-05-24

申请人： Ting Tao ,  Jianbing Huang

发明人： Ting Tao ,  Jianbing Huang

IPC分类号： G03F7021

CPC分类号： B41C1/1008 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  B41C2210/266 ,  C07C245/20 ,  C07C305/06 ,  G03F7/0045 ,  G03F7/038

摘要： An acid generating agent useful for imaging photosensitive elements selected from compounds of formulae (I), (II) and (III). wherein R1 is selected from the group consisting of an unsubstituted and substituted hydrocarbon or aryl group; wherein X is selected from the group consisting of oxygen, sulfur and selenium; wherein Y is selected from the group consisting of sulfur, selenium and tellurium; wherein Ar1 is selected from the group consisting of an unsubstituted and substituted aryl group; wherein R2, R3 and R4 are individually selected from the group consisting of an unsubstituted and substituted hydrocarbon or aryl group or any two of them are bonded together to form a ring structure; and wherein R5 and R6 are individually selected from the group of an unsubstituted and substituted hydrocarbon or aryl group, or are bonded to each other to form a ring structure.

摘要翻译： 用于成像选自式（I），（II）和（III）的化合物的光敏元件的酸产生剂，其中R 1选自未取代和取代的烃或芳基;其中X是 选自氧，硫和硒;其中Y选自硫，硒和碲;其中Ar 1选自未取代和取代的芳基;其中R 2 R 3和R 4各自独立地选自未取代的和取代的烃基或芳基，或者它们中的任何两个键合在一起形成环结构; 其中R 5和R 6分别选自未取代和取代的烃基或芳基，或彼此键合形成环结构。

公开(公告)号：US06610458B2

公开(公告)日：2003-08-26

申请号：US09911159

申请日：2001-07-23

申请人： Nicki R. Miller ,  Barbara Nüssel ,  Jianbing Huang

发明人： Nicki R. Miller ,  Barbara Nüssel ,  Jianbing Huang

IPC分类号： G03F7038

CPC分类号： B41C1/1041 ,  Y10S430/145 ,  Y10S430/146 ,  Y10S430/165

摘要： A direct-to-press imaging method comprises: (a) applying an imageable coating to a printing cylinder, wherein the imageable coating comprises a composition such as a thermally switchable polymer which changes affinity for a printing fluid upon exposure to imaging radiation such as infrared radiation delivered imagewise via a laser, and the imageable coating is substantially insoluble in the printing fluid; (b) imagewise exposing the imageable coating to actinic radiation to obtain an imaged coating; (c) printing a plurality of copies of an image from the imaged coating; and (d) reapplying the imageable coating as desired by repeating steps (a) through (c) at least once without substantially removing the prior imaged coating before reapplying the imageable coating.

摘要翻译： 直接成像成像方法包括：（a）将可成像涂层施加到印刷滚筒，其中可成像涂层包括诸如可热切换聚合物的组合物，其在暴露于诸如红外线的成像辐射时改变对印刷液体的亲和​​性 通过激光成像的辐射辐射，并且可成像的涂层基本上不溶于印刷液体;（b）将可成像的涂层成像曝光到光化辐射以获得成像的涂层;（c）从成像的 涂层; 和（d）通过重复步骤（a）至（c）至少一次，根据需要重新施加可成像涂层，而在重新施加可成像涂层之前基本上不去除现有的成像涂层。

公开(公告)号：US06555283B1

公开(公告)日：2003-04-29

申请号：US09589334

申请日：2000-06-07

申请人： Xing-Fu Zhong ,  Jianbing Huang ,  S. Peter Pappas

发明人： Xing-Fu Zhong ,  Jianbing Huang ,  S. Peter Pappas

IPC分类号： G03F7021

CPC分类号： B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/04 ,  B41C2210/12 ,  B41C2210/14 ,  B41C2210/16 ,  B41C2210/22 ,  B41C2210/24 ,  B41M5/368 ,  G03F7/016 ,  G03F7/021 ,  G03F7/031 ,  G03F7/0752

摘要： This invention relates to an imageable element that can be imaged and developed to produce a printing plate. The imageable element comprises a substrate and a radiation-sensitive imageable composition applied to the substrate. The imageable composition comprises (a) a first layer having (i) a photosensitive composition which undergoes a decrease in solubility in developer upon absorption of actinic radiation and (ii) an inhibitor, and (b) a second layer comprising an ink-repellent polymeric material. In one embodiment, the inhibitor is activated by heat or radiation of longer wavelength than actinic radiation. Upon activation, the inhibitor retards the solubility decrease of the photosensitive composition upon absorption of actinic radiation. In another embodiment, the inhibitor initially retards the solubility decrease of the photosensitive composition upon absorption of actinic radiation. However, the inhibitor is deactivated by heat or radiation of longer wavelength than actinic radiation, and upon deactivation the inhibitor no longer retards the solubility decrease of the photosensitive composition.

摘要翻译： 本发明涉及可成像和显影以产生印版的可成像元件。 可成像元件包括施加到基底的基底和辐射敏感可成像组合物。 可成像组合物包含（a）第一层，其具有（i）在吸收光化辐射时在显影剂中溶解度降低的光敏组合物和（ii）抑制剂，和（b）包含拒油聚合物 材料。 在一个实施方案中，抑制剂通过比光化辐射更长波长的热或辐射活化。 激活时，抑制剂在吸收光化辐射时阻碍光敏组合物的溶解度降低。 在另一个实施方案中，抑制剂最初延迟光敏组合物在吸收光化辐射时的溶解度降低。 然而，抑制剂通过比光化辐射更长波长的热或辐射而失活，并且在失活时，抑制剂不再延迟感光组合物的溶解度降低。

公开(公告)号：US06352811B1

公开(公告)日：2002-03-05

申请号：US09469490

申请日：1999-12-22

申请人： Jayanti Patel ,  Shahhikant Saraiya ,  Celin Savariar-Hauck ,  Jianbing Huang ,  Frederic Mikell ,  Ken-ichi Shimazu ,  Nishith Merchant

发明人： Jayanti Patel ,  Shahhikant Saraiya ,  Celin Savariar-Hauck ,  Jianbing Huang ,  Frederic Mikell ,  Ken-ichi Shimazu ,  Nishith Merchant

IPC分类号： G03F709

CPC分类号： B41C1/1016 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/26 ,  B41C2210/262 ,  B41C2210/264 ,  B41C2210/266 ,  B41M5/368 ,  B41M5/42 ,  B41M5/44 ,  B41M5/465

摘要： A thermal lithographic printing plate, which can be imaged by thermal energy typically by imagewise exposure with an infrared emitting laser, a thermal printing head, etc., is made up of a hydrophilic substrate, and a composite layer structure composed of two layer coatings. Preferably, the first layer of the composite is composed of an aqueous developable polymer mixture containing a solubility inhibiting material and a photothermal conversion material which is contiguous to the hydrophilic substrate. The second layer of the composite is insoluble in the aqueous solution, is ink receptive, and is composed of one or more non-aqueous soluble polymers which are soluble or dispersible in a solvent which does not dissolve the first layer. The plate is exposed with an infrared laser or a thermal print head, and upon aqueous development of the imaged plate, the exposed portions are removed exposing hydrophilic substrate surfaces receptive to conventional aqueous fountain solutions. The unexposed portions contain the ink-receptive image areas. The second layer may also contain a photothermal conversion material. Alternatively, the composite layer may be free of photothermal conversion material when thermal imaging is carried out using a thermal printing head.

摘要翻译： 可以通过热能成像通过用红外发射激光成像曝光，热打印头等来成像的热平版印刷版由亲水基材和由两层涂层组成的复合层结构构成。 优选地，复合材料的第一层由含有可溶解性抑制材料和与亲水基底邻接的光热转换材料的水性可显影聚合物混合物组成。 复合材料的第二层不溶于水溶液，是油墨接受的，并且由一种或多种可溶于或不溶于不溶于第一层的溶剂中的非水溶性聚合物组成。 该板用红外激光或热打印头曝光，并且在成像板的水性显影时，去除曝光部分，暴露接受常规水性喷泉溶液的亲水底物表面。 未曝光部分包含吸墨图像区域。 第二层也可以含有光热转换材料。 或者，当使用热敏打印头进行热成像时，复合层可以不含光热转换材料。

公开(公告)号：US06251559B1

公开(公告)日：2001-06-26

申请号：US09368261

申请日：1999-08-03

申请人： Jianbing Huang ,  Jerome Kesselman

发明人： Jianbing Huang ,  Jerome Kesselman

IPC分类号： G03F7004

CPC分类号： B41N3/00

摘要： Imagable articles comprising positive working polymeric resins coating onto substrates are given a heat treatment comprising their controlled slow cooling from an elevated temperature. The imagable articles include precursors for lithographic printing plates and for printed circuits. The controlled slow cooling improves the development characteristics of the coatings after an imaging step.

摘要翻译： 包含涂覆在基底上的正性聚合物树脂的可想象的制品被给予热处理，其包括从高温控制的缓慢冷却。 可成像制品包括平版印刷版和印刷电路用前体。 受控的慢冷却改善了成像步骤后涂层的显影特性。