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公开(公告)号：US06821583B2
公开(公告)日：2004-11-23
申请号：US10189169
申请日：2002-07-03
申请人： Grant Thomas Donald Shouldice , Shashikant Saraiya , Xing-Fu Zhong , Richard R. Durand, Jr. , Jianbing Huang , Patrick Friedman
发明人： Grant Thomas Donald Shouldice , Shashikant Saraiya , Xing-Fu Zhong , Richard R. Durand, Jr. , Jianbing Huang , Patrick Friedman
IPC分类号： B32B2730
CPC分类号： B41M5/506 , B41C1/1016 , B41C2210/02 , B41C2210/04 , B41C2210/06 , B41C2210/14 , B41C2210/22 , B41C2210/24 , B41C2210/262 , B41M5/52 , B41M5/5227 , B41M2205/12 , B41M2205/38 , Y10T428/24802 , Y10T428/31699 , Y10T428/31855 , Y10T428/31928 , Y10T428/31935 , Y10T428/31938
摘要： The present invention provides an imageable element, which includes: a substrate; a crosslinked layer disposed on the substrate; and an imageable ink-receptive layer disposed on the crosslinked layer, the imageable ink-receptive layer including an ablation free imageable composition. The present invention provides methods of producing the above imaged element.
摘要翻译： 本发明提供一种可成像元件，其包括：基板; 设置在所述基板上的交联层; 以及设置在所述交联层上的可成像的油墨接收层，所述可成像的墨接受层包括无消融成像的组合物。 本发明提供了制造上述成像元件的方法。
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2.发明授权Digital waterless lithographic printing plate having high resistance to water-washable inks 失效具有高耐水洗性油墨的数字无水平版印刷版公开(公告)号：US06730457B2
公开(公告)日：2004-05-04
申请号：US10190066
申请日：2002-07-05
IPC分类号： G03F711
CPC分类号： G03F7/0752 , B41C1/1016 , B41C2201/02 , B41C2201/04 , B41C2201/14 , B41C2210/02 , B41C2210/12 , B41C2210/16 , B41C2210/22 , B41C2210/24 , B41C2210/266
摘要： Thermally imageable elements and methods for their preparation and use are disclosed. The elements contain, in order, a substrate; an underlayer; and an ink-repellent layer. The underlayer contains a crosslinked allyl functional polyurethane. A photothermal conversion material is present in either in the underlayer or in an absorber layer between the underlayer and the ink-repellent layer. Thermal imaging and development removes the ink-repellent layer and reveals the underlayer in the exposed regions to form an imaged element useful as a waterless lithographic printing plate.
摘要翻译： 公开了可热成像的元件及其制备和使用方法。 这些元素依次含有底物; 底层 和拒油层。 底层含有交联的烯丙基官能聚氨酯。 光热转换材料存在于底层中或在底层和拒墨层之间的吸收层中。 热成像和显影去除了拒油层并且暴露在暴露区域中的底层以形成可用作无水平版印刷版的成像元件。
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公开(公告)号：US06899992B2
公开(公告)日：2005-05-31
申请号：US10290623
申请日：2002-11-08
IPC分类号： B41C1/10 , B41M5/36 , C07D239/46 , C07D487/04 , G03F7/027 , G03F7/035 , G03F7/038 , G03F7/004
CPC分类号： G03F7/0388 , B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , C07D239/47 , C07D487/04 , G03F7/027 , G03F7/035
摘要： QHB-Modified free radical polymerizable compounds and free radical polymerizable compositions that comprise these compounds are disclosed. A QBH-modified free radical polymerizable compound has at least one moiety that comprises at least one free radical polymerizable group; a supporting backbone, and at least one and preferably at least two moieties capable of forming four or more, typically four, hydrogen bonds with similar or complementary units on other molecules or portions of molecules. Free radical polymerizable compositions that contain these compounds may be used in any of the well-known applications for free radical polymerizable compositions. They are especially useful for the formation of imageable elements useful as lithographic printing plate precursors.
摘要翻译： 公开了QHB改性的可自由基聚合的化合物和包含这些化合物的自由基可聚合组合物。 QBH改性的自由基聚合性化合物具有至少一个包含至少一个可自由基聚合基团的部分; 支链骨架，以及能与其他分子或分子部分上的相似或互补单元形成四个或更多，通常四个氢键的至少一个，优选至少两个部分。 含有这些化合物的自由基可聚合组合物可用于任何用于自由基可聚合组合物的众所周知的应用。 它们对于形成可用作平版印刷版前体的可成像元件特别有用。
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4.发明授权公开(公告)号：US06911296B2
公开(公告)日：2005-06-28
申请号：US10299226
申请日：2002-11-19
申请人： Peter S. Pappas , Alan Monk , Shashikant Saraiya , Jianbing Huang
发明人： Peter S. Pappas , Alan Monk , Shashikant Saraiya , Jianbing Huang
IPC分类号： G03F7/039 , B41C1/10 , B41M5/36 , C08G18/28 , C08G18/38 , C08G18/54 , C08G73/02 , C08G73/06 , C08G77/26 , C08G85/00
CPC分类号： B41C1/1008 , B41C1/1016 , B41C2210/02 , B41C2210/06 , B41C2210/14 , B41C2210/22 , B41C2210/24 , B41C2210/26 , B41C2210/262 , B41C2210/264 , B41C2210/266 , C08G18/285 , C08G18/3848 , C08G18/542 , C08G73/0273 , C08G73/0694 , C08G83/008 , Y10S430/106 , Y10S430/107 , Y10S430/109 , Y10S430/11 , Y10S430/111 , Y10S430/145 , Y10S430/146 , Y10S430/165 , C09D163/00 , C08L101/00
摘要： The present invention also includes an imageable element, comprising a substrate and a thermally imageable composition comprising a thermally sensitive polymer which exhibits an increased solubility in an aqueous developer solution upon heating. The thermally sensitive polymer includes at least one covalently bonded unit and at least one thermally reversible non-covalently bonded unit, which includes a two or more centered H-bond within each of the non-covalently bonded unit. The present invention also includes a method of producing the imaged element. The present invention still further includes a thermally imageable composition comprising comprising a thermally sensitive polymer according to the present invention and a process for preparing the thermally sensitive polymer, which is a supramolecular polymer. The process includes contacting a hydrocarbyl-substituted isocytosine and a diisocyanate to produce a mono-adduct and contacting the mono-adduct and a polyfunctional material to produce the supramolecular polymer.
摘要翻译： 本发明还包括可成像元件，其包括基材和可热成像组合物，其包含热敏聚合物，其在加热时在显影剂水溶液中显示出增加的溶解度。 热敏聚合物包括至少一个共价键合单元和至少一个热可逆非共价键合单元，其包括在每个非共价键合单元内的两个或更多个中心H键。 本发明还包括一种制造成像元件的方法。 本发明还包括可热成像的组合物，其包含根据本发明的热敏聚合物和制备作为超分子聚合物的热敏聚合物的方法。 该方法包括使烃基取代的异胞嘧啶与二异氰酸酯接触以产生单加合物，并使单加成物与多官能物质接触以产生超分子聚合物。
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5.发明授权On-press developable IR sensitive printing plates using binder resins having polyethylene oxide segments 有权使用具有聚环氧乙烷链段的粘合剂树脂的印刷机可印刷的IR敏感印刷版公开(公告)号：US06899994B2
公开(公告)日：2005-05-31
申请号：US10119454
申请日：2002-04-10
IPC分类号： G03F7/004 , B41C1/10 , B41M5/36 , B41N1/14 , G03C1/498 , G03C1/675 , G03F7/00 , G03F7/021 , G03F7/033 , G03F7/40 , G03C1/73 , G03C1/76 , G03F7/032 , G03F7/028 , G03F7/20 , G03F7/30
CPC分类号： G03F7/033 , B41C1/1008 , B41C2210/04 , B41C2210/08 , B41C2210/24 , B41M5/368 , G03C1/04 , G03C1/49863 , G03F7/0212 , Y10S430/106 , Y10S430/117 , Y10S430/145
摘要： The present invention relates to a polymerizable coating composition suitable for the manufacture of printing plates developable on-press. The coating composition comprises (i) a polymerizable compound and (ii) a polymeric binder comprising polyethylene oxide segments, wherein the polymeric binder is selected from the group consisting of at least one graft copolymer comprising a main chain polymer and polyethylene oxide side chains, a block copolymer having at least one polyethylene oxide block and at least one non-polyethylene oxide block, and a combination thereof. The invention is also directed to an imageable element comprising a substrate and the polymerizable coating composition.
摘要翻译： 本发明涉及适用于制造可印刷印刷机的印版的可聚合涂料组合物。 涂料组合物包含（i）可聚合化合物和（ii）包含聚环氧乙烷链段的聚合物粘合剂，其中聚合物粘合剂选自至少一种包含主链聚合物和聚环氧乙烷侧链的接枝共聚物， 具有至少一个聚环氧乙烷嵌段和至少一个非聚环氧乙烷嵌段的嵌段共聚物及其组合。 本发明还涉及包含基材和可聚合涂料组合物的可成像元件。
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公开(公告)号：US07261998B2
公开(公告)日：2007-08-28
申请号：US10872209
申请日：2004-06-17
CPC分类号： B41M5/368 , B41C1/1008 , B41C2210/04 , B41C2210/06 , B41C2210/08 , B41C2210/10 , B41C2210/24 , G03C1/04 , G03C1/49863 , G03F7/0212 , G03F7/033 , Y10S430/106 , Y10S430/111 , Y10S430/117 , Y10S430/121 , Y10S430/145
摘要： The present invention provides an imageable element including a lithographic substrate and an imageable layer disposed on the substrate. The imageable layer includes a radically polymerizable component, an initiator system capable of generating radicals sufficient to initiate a polymerization reaction upon exposure to imaging radiation, and a polymeric binder having a hydrophobic backbone and including both constitutional units having a pendant cyano group attached directly to the hydrophobic backbone, and constitutional units having a pendant group including a hydrophilic poly(alkylene oxide) segment. When the imageable element is imaged and developed, the resulting printing plate may exhibit improved on-press solvent resistance and longer press life.
摘要翻译： 本发明提供一种可成像元件，包括平版印刷基板和设置在基板上的可成像层。 可成像层包括可自由基聚合的组分，能够产生足以在暴露于成像辐射时引发聚合反应的自由基的引发剂体系，以及具有疏水骨架的聚合物粘合剂，并且包括具有氰基侧基的两个结构单元直接连接到 疏水骨架和具有包括亲水性聚（环氧烷）链段）侧基的结构单元。 当可成像和显影成像元件时，所得到的印版可以表现出改进的耐压耐溶剂性和更长的印刷寿命。
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公开(公告)号：US06506536B2
公开(公告)日：2003-01-14
申请号：US09751650
申请日：2000-12-29
申请人： S. Peter Pappas , Alan Monk , Shashikant Saraiya , Jianbing Huang
发明人： S. Peter Pappas , Alan Monk , Shashikant Saraiya , Jianbing Huang
IPC分类号： C08G8500
CPC分类号： B41C1/1008 , B41C1/1016 , B41C2210/02 , B41C2210/06 , B41C2210/14 , B41C2210/22 , B41C2210/24 , B41C2210/26 , B41C2210/262 , B41C2210/264 , B41C2210/266 , C08G18/285 , C08G18/3848 , C08G18/542 , C08G73/0273 , C08G73/0694 , C08G83/008 , Y10S430/106 , Y10S430/107 , Y10S430/109 , Y10S430/11 , Y10S430/111 , Y10S430/145 , Y10S430/146 , Y10S430/165 , C09D163/00 , C08L101/00
摘要： The present invention also includes an imageable element, comprising a substrate and a thermally imageable composition comprising a thermally sensitive polymer which exhibits an increased solubility in an aqueous developer solution upon heating. The thermally sensitive polymer includes at least one covalently bonded unit and at least one thermally reversible non-covalently bonded unit, which includes a two or more centered H-bond within each of the non-covalently bonded unit. The present invention also includes a method of producing the imaged element. The present invention still further includes a thermally imageable composition comprising comprising a thermally sensitive polymer according to the present invention and a process for preparing the thermally sensitive polymer, which is a supramolecular polymer. The process includes contacting a hydrocarbyl-substituted isocytosine and a diisocyanate to produce a mono-adduct and contacting the mono-adduct and a polyfunctional material to produce the supramolecular polymer.
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8.发明授权Radiation sensitive diazo sulfo-acrylic adducts and method for producing a printing plate 失效辐射敏感重氮磺基丙烯酸加合物及其印刷方法
公开(公告)号：US5846685A
公开(公告)日：1998-12-08
申请号：US797675
申请日：1997-01-31
申请人： S. Peter Pappas , Jianbing Huang , Ajay Shah , Shashikant Saraiya
发明人： S. Peter Pappas , Jianbing Huang , Ajay Shah , Shashikant Saraiya
CPC分类号： G03F7/021
摘要： A radiation sensitive composition containing an adduct of a diazonium resin having pendant diazonium groups, with a sulfonated acrylic copolymer having pendant sulfonate groups. The sulfonated acrylic copolymer contains an acrylic moiety and a sulfonated styryl or acrylic moiety. The copolymer may optionally contain styryl moieties. The composition is useful as a radiation sensitive layer in imaging elements for graphic arts applications and is particularly useful in preparing durable, long-wear, printing plates.
摘要翻译： 一种辐射敏感性组合物，其含有具有侧面重氮基团的重氮化合物的加合物和具有磺酸根基侧基的磺化丙烯酸共聚物。 磺化丙烯酸共聚物含有丙烯酸部分和磺化苯乙烯基或丙烯酸部分。 共聚物可以任选地含有苯乙烯基部分。 该组合物可用作用于图形艺术应用的成像元件中的辐射敏感层，并且在制备耐用的长寿命印刷版中特别有用。
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公开(公告)号：US08383319B2
公开(公告)日：2013-02-26
申请号：US12546769
申请日：2009-08-25
申请人： Jianbing Huang , Shashikant Saraiya , Frederic E. Mikell , Eiji Hayakawa , Hirokazu Fujii , Akira Igarashi
发明人： Jianbing Huang , Shashikant Saraiya , Frederic E. Mikell , Eiji Hayakawa , Hirokazu Fujii , Akira Igarashi
CPC分类号： B41C1/1016 , B41C2201/02 , B41C2210/02 , B41C2210/04 , B41C2210/06 , B41C2210/14 , B41C2210/24 , B41C2210/262 , G03F7/092
摘要： Lithographic printing plate precursors have been designed so that they can be stored, shipped, and used in stacks without interleaf paper between individual precursors. This is achieved by incorporating polymeric particles having an average diameter of from about 3 to about 20 μm into the outermost precursor layer such as an imagable layer or topcoat. The polymeric particles comprise a core of a crosslinked polymer and have grafted hydrophilic polymeric surface groups that are grafted onto the particle surfaces by polymerizing hydrophilic monomers in the presence of the crosslinked polymeric particles. The lithographic printing plates can be either negative- or positive-working elements.
摘要翻译： 已经设计了平版印刷版前体，使得它们可以在堆叠中储存，运输和使用，而不需要在各个前体之间的中间纸。 这通过将具有约3至约20μm的平均直径的聚合物颗粒结合到最外层前体层中，例如可成像层或顶涂层来实现。 聚合物颗粒包含交联聚合物的核心并且具有通过在交联的聚合物颗粒的存在下聚合亲水单体而接枝到颗粒表面上的接枝的亲水聚合物表面基团。 平版印刷版可以是负片或正片元件。
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10.发明申请公开(公告)号：US20050170286A1
公开(公告)日：2005-08-04
申请号：US11091124
申请日：2005-03-28
IPC分类号： G03F7/004 , B41C1/10 , B41M5/36 , B41N1/14 , G03C1/498 , G03C1/675 , G03F7/00 , G03F7/021 , G03F7/033 , G03F7/40 , G03C1/76
CPC分类号： G03F7/033 , B41C1/1008 , B41C2210/04 , B41C2210/08 , B41C2210/24 , B41M5/368 , G03C1/04 , G03C1/49863 , G03F7/0212 , Y10S430/106 , Y10S430/117 , Y10S430/145
摘要： The present invention relates to a polymerizable coating composition suitable for the manufacture of printing plates, which may be developable on-press. The coating composition comprises (i) a polymerizable compound and (ii) a polymeric binder comprising polyethylene oxide segments, wherein the polymeric binder is selected from the group consisting of at least one graft copolymer comprising a main chain polymer and polyethylene oxide side chains, a block copolymer having at least one polyethylene oxide block and at least one non-polyethylene oxide block, and a combination thereof. The invention is also directed to an imageable element comprising a substrate and the polymerizable coating composition.
摘要翻译： 本发明涉及一种适用于制造印刷版的可聚合涂料组合物，其可印刷机可显影。 涂料组合物包含（i）可聚合化合物和（ii）包含聚环氧乙烷链段的聚合物粘合剂，其中聚合物粘合剂选自至少一种包含主链聚合物和聚环氧乙烷侧链的接枝共聚物， 具有至少一个聚环氧乙烷嵌段和至少一个非聚环氧乙烷嵌段的嵌段共聚物及其组合。 本发明还涉及包含基材和可聚合涂料组合物的可成像元件。
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