公开(公告)号：US20070149695A1

公开(公告)日：2007-06-28

申请号：US11275331

申请日：2005-12-23

申请人： Klaus Hintzer ,  Harald Kaspar ,  Helmut Traunspurger ,  Tilman Zipplies

发明人： Klaus Hintzer ,  Harald Kaspar ,  Helmut Traunspurger ,  Tilman Zipplies

IPC分类号： D06M15/277

CPC分类号： D06M15/277 ,  C08F14/18 ,  C08F2/24

摘要： A method for polymerizing, in an aqueous medium, at least one fluorinated monomer in the presence of a non-copolymerizable, non-fluorinated surfactant. The surfactant is generally selected from a non-ionic surfactant, a primary anionic surfactant, or a combination thereof. Fluorinated surfactants are not utilized. The resulting partially fluorinated polymer in the aqueous medium is either a semi-crystalline polymer or a crystalline polymer.

摘要翻译： 一种在水性介质中在不可共聚的非氟化表面活性剂存在下聚合至少一种氟化单体的方法。 表面活性剂通常选自非离子表面活性剂，初级阴离子表面活性剂或其组合。 不使用氟化表面活性剂。 在水性介质中得到的部分氟化聚合物是半结晶聚合物或结晶聚合物。

公开(公告)号：US07064170B2

公开(公告)日：2006-06-20

申请号：US10690088

申请日：2003-10-21

申请人： Harald Kaspar ,  Peter J. Scott ,  Klaus Hintzer ,  Gernot Löhr

发明人： Harald Kaspar ,  Peter J. Scott ,  Klaus Hintzer ,  Gernot Löhr

IPC分类号： C08F12/20

CPC分类号： C08F214/18

摘要： Provided is a process for making a copolymer of fluorinated olefin and hydrocarbon olefin selected from ethylene, propylene and mixtures thereof, the process comprising a substantially emulsifier free aqueous emulsion polymerization of said fluorinated olefin and said hydrocarbon olefin, optionally in the presence of fluoropolymer particles and/or fluorinated liquid in a form suitable to improve the copolymerization of fluorinated olefin and hydrocarbon olefin.

摘要翻译： 提供了制备氟化烯烃和选自乙烯，丙烯及其混合物的烃烯烃的共聚物的方法，该方法包括所述氟化烯烃和所述烃烯烃的基本上无乳化剂的水乳液聚合，任选在含氟聚合物颗粒和 /或氟化液体，其形式适合改善氟化烯烃和烃烯烃的共聚。

公开(公告)号：US06906145B2

公开(公告)日：2005-06-14

申请号：US10282677

申请日：2002-10-29

申请人： Ludo Govaerts ,  Dirk H. Arren ,  Tatsuo Fukushi ,  William D. Coggio ,  Klaus Hintzer ,  Harald Kaspar

发明人： Ludo Govaerts ,  Dirk H. Arren ,  Tatsuo Fukushi ,  William D. Coggio ,  Klaus Hintzer ,  Harald Kaspar

IPC分类号： F16L11/04 ,  B32B1/08 ,  B32B7/10 ,  B32B25/08 ,  B32B27/28 ,  B32B27/30 ,  C08K5/00 ,  C08K5/54 ,  C08L27/12 ,  C08L27/22 ,  C08F8/06 ,  C08F8/12 ,  C08F8/42

CPC分类号： B32B27/28 ,  B32B1/08 ,  B32B7/10 ,  B32B25/08 ,  C08K5/54 ,  Y10T428/1393 ,  C08L27/12

摘要： The present invention comprises a substrate having a fluoropolymer on at least one of its surfaces wherein one of the substrates or the fluoropolymer comprises a hydride function MH wherein M is Si, Ge, Sn or Pb. The invention further comprises articles comprising the substrate and fluoropolymer; a method of bonding the fluoropolymer to the substrate; a fluoropolymer composition that contains the fluoropolymer, a polyhydroxy cure composition, and an organic composition comprising the hydride function MH; a premix that contains the fluoropolymer and the hydride function MH; and a fluoropolymer composition that comprises (a) a thermoplastic fluoropolymer comprising Cl, Brand/or I atoms and (b) an organic compound that comprises the hydride function MH.

摘要翻译： 本发明包括在其至少一个表面上具有含氟聚合物的基材，其中一个基材或含氟聚合物包含氢化物功能MH，其中M是Si，Ge，Sn或Pb。 本发明还包括包含基材和含氟聚合物的制品; 将含氟聚合物粘合到基材上的方法; 含氟聚合物的含氟聚合物组合物，多羟基固化组合物和包含氢化物功能MH的有机组合物; 含氟聚合物和氢化物功能MH的预混物; 和含氟聚合物组合物，其包含（a）包含Cl，Brand /或I原子的热塑性含氟聚合物和（b）包含氢化物功能MH的有机化合物。

公开(公告)号：US06489420B1

公开(公告)日：2002-12-03

申请号：US09604178

申请日：2000-06-27

申请人： Denis Duchesne ,  Harald Kaspar ,  Lisa P. Chen ,  Klaus Hintzer ,  Attila Molnar ,  Ludwig Mayer ,  Gernot Löhr

发明人： Denis Duchesne ,  Harald Kaspar ,  Lisa P. Chen ,  Klaus Hintzer ,  Attila Molnar ,  Ludwig Mayer ,  Gernot Löhr

IPC分类号： C08F21422

CPC分类号： C08F214/222 ,  C08F214/184 ,  C08F214/262 ,  Y10T428/3154 ,  Y10T428/31544

摘要： A fluoropolymer composition is provided. The polymer comprises interpolymerized units derived from (i) tetrafluoroethylene, (ii) vinylidene fluoride, (iii) at least one ethylenically unsaturated monomer of the formula CF2═CFRf where Rf is a perfluoroalkyl or a perfluoroalkoxy of 1 to 8 carbon atoms, and (iv) a perfluorovinyl ether of the formula CF2═CF—(OCF2CF(Rf))aOR′f where Rf is as described in (iii), R′f is a perfluoroaliphatic, preferably a perfluoroalkyl or a perfluoroalkoxy, of 1 to 8, preferably 1 to 3, carbon atoms, and a has a value of 0 to 3.

摘要翻译： 提供含氟聚合物组合物。 聚合物包含衍生自（i）四氟乙烯，（ii）偏二氟乙烯，（iii）至少一种式CF 2 = CFR f的烯键式不饱和单体的共聚单元，其中Rf是1至8个碳原子的全氟烷基或全氟烷氧基，和（ iv）式CF 2 = CF-（OCF 2 CF（R f））aOR'f的全氟乙烯醚，其中R f如（iii）中所述，R 1f是1至8的全氟脂族基，优选全氟烷基或全氟烷氧基， 优选为1〜3个碳原子，a为0〜3。

公开(公告)号：US06380313B1

公开(公告)日：2002-04-30

申请号：US09604392

申请日：2000-06-27

申请人： Maria P. Dillon ,  Harald Kaspar ,  Bernhard Hirsch ,  Klaus Hintzer ,  Karl-Dieter Weilandt

发明人： Maria P. Dillon ,  Harald Kaspar ,  Bernhard Hirsch ,  Klaus Hintzer ,  Karl-Dieter Weilandt

IPC分类号： C08L2712

CPC分类号： C08L23/02 ,  C08F214/184 ,  C08F214/186 ,  C08L27/12 ,  C08L27/16 ,  C08L27/18 ,  C08L71/02 ,  C08L2666/04 ,  C08L2666/22

摘要： A polymer processing aid composition, a melt processable polymer composition that uses the polymer processing aid, and a method of improving the melt processability of a thermoplastic polymer are provided. The polymer processing aid composition comprises a fluoropolymer that comprises interpolymerized units derived from a perfluorovinyl ether, preferably one having the formula CF2═CF—(OCF2CF(CF3))AORf where a has a value of 0 to 3 and Rf is a perfluoroaliphatic (preferably perfluoroalkyl or perfluoroalkoxy) having from 1 to 8 (preferably 1 to 3) carbon atoms.

摘要翻译： 提供聚合物加工助剂组合物，使用聚合物加工助剂的可熔融加工的聚合物组合物和改进热塑性聚合物的熔融加工性能的方法。 聚合物加工助剂组合物包含含氟聚合物，其含有衍生自全氟乙烯基醚的共聚单元，优选具有式CF 2 = CF-（OCF 2 CF（CF 3））AOR f的共聚单元，其中a为0至3，Rf为全氟脂族基（优选 全氟烷基或全氟烷氧基），其具有1至8个（优选1至3个）碳原子。

公开(公告)号：US10954318B2

公开(公告)日：2021-03-23

申请号：US13704064

申请日：2011-06-09

申请人： Jimmie R. Baran, Jr. ,  Duane D. Fansler ,  Klaus Hintzer ,  William J. Hunt ,  Harald Kaspar ,  Tilman C. Zipplies

发明人： Jimmie R. Baran, Jr. ,  Duane D. Fansler ,  Klaus Hintzer ,  William J. Hunt ,  Harald Kaspar ,  Tilman C. Zipplies

IPC分类号： C08F2/10 ,  C08F2/20 ,  C08F2/22 ,  C08K9/06 ,  C08F14/28 ,  C08F16/24 ,  C08F14/26 ,  C08F2/18 ,  C08K3/36

摘要： Described herein is a polymerizable composition substantially free of an organic emulsifier, methods of making, and articles thereof. The polymerizable composition comprises: a continuous phase; a polymerizable monomer; an initiator; and inorganic nanoparticles, wherein the inorganic nanoparticles are substantially free of groups that will copolymerize with the polymerizable monomer.

公开(公告)号：US09453086B2

公开(公告)日：2016-09-27

申请号：US13995615

申请日：2011-12-21

申请人： Klaus Hintzer ,  Michael Juergens ,  Gunther J. Kaempf ,  Harald Kaspar ,  Kai H. Lochhaas ,  Andre Streiter ,  Oleg Shyshkov ,  Tilman C. Zipplies ,  Herbert Koenigsmann

发明人： Klaus Hintzer ,  Michael Juergens ,  Gunther J. Kaempf ,  Harald Kaspar ,  Kai H. Lochhaas ,  Andre Streiter ,  Oleg Shyshkov ,  Tilman C. Zipplies ,  Herbert Koenigsmann

IPC分类号： C08F14/18 ,  C02F1/461 ,  C02F1/26 ,  C08F14/08

CPC分类号： C08F6/003 ,  C02F1/26 ,  C02F1/461 ,  C02F2001/46138 ,  C02F2001/46147 ,  C08F2/10 ,  C08F2/20 ,  C08F14/08 ,  C08F14/18 ,  C08F2800/10 ,  Y02P20/582 ,  C08F2/24

摘要： Described herein is a composition comprising an aqueous polymerization reaction product of fluorinated monomers and wherein the polymerization is initiated (i) in the absence of a fluorinated emulsifier and whereby no fluorinated emulsifier is added during polymerization or (ii) in the presence of an fluorinated emulsifier selected from: [Rf—O-L-COO-]i Xi+ (I) wherein L represents a linear or branched, non-fluorinated, partially fluorinated, or fully fluorinated alkylene group, Rf represents a linear or branched partially or fully fluorinated aliphatic group or a linear or branched partially or fully fluorinated aliphatic group interrupted with at least one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; wherein the reaction product and/or the resulting aqueous phase are substantially free of di- and tri-alkylamines and substantially free of low molecular weight fluoroorganic compounds and methods thereof.

摘要翻译： 本文描述的是包含氟化单体的水性聚合反应产物的组合物，其中聚合反应开始于（i）在不存在氟化乳化剂的情况下，并且由此在聚合过程中不加入氟化乳化剂，或（ii）在氟化乳化剂存在下 选自：[Rf-OL-COO-] i Xi +（I）其中L表示直链或支链，非氟化，部分氟化或完全氟化的亚烷基，Rf表示直链或支链部分或完全氟化的脂族基团或 间隔有至少一个氧原子的直链或支链部分或完全氟化的脂肪族基团，X i +表示i为i且i为1,2或3的阳离子; 其中所述反应产物和/或所得水相基本上不含二烷基胺和三烷基胺，并且基本上不含低分子量氟代有机化合物及其方法。

公开(公告)号：US08541499B2

公开(公告)日：2013-09-24

申请号：US12682702

申请日：2008-10-10

申请人： Klaus Hintzer ,  Kai H. Lochhaas ,  Michael Jürgens ,  Harald Kaspar ,  Tilman C. Zipplies ,  André Streiter

发明人： Klaus Hintzer ,  Kai H. Lochhaas ,  Michael Jürgens ,  Harald Kaspar ,  Tilman C. Zipplies ,  André Streiter

IPC分类号： C08L27/18

CPC分类号： C08K5/19 ,  C08F2/24 ,  C08F14/18 ,  C08F214/18 ,  C08K5/095 ,  C08F2/16 ,  C08L27/12

摘要： There is provided a fluoroelastomer characterized by containing one type or more types of fluorinated emulsifiers represented by the formula: F—(CF2)t-[O(CF2)n]m-O—(CHF)o-(CF2)p-X where m=0 to 3; n=1 to 5; o=0 to 1; p=1 to 3; t=1 to 10; and where when t=2 than o≠0; and further where X is selected from a group consisting of a carboxyl acid group and a salt of a carboxylic acid group. A method for preparing fluoroelastomers by using such fluorinated emulsifiers in emulsion polymerization of fluoromonomers and articles containing such fluoroelastomers are also provided. A fluorinated elastomer dispersion including an aqueous mixture of a crosslinkable fluorinated elastomer and such fluorinated emulsifiers are also provided. The fluoroelastomers created with such fluorinated emulsifiers are essentially free of cations other than NH4+ and H+ and have a low glass transition temperature.

摘要翻译： 提供一种含氟弹性体，其特征在于含有一种或多种由式F-（CF 2）t- [O（CF 2）n] m O - （CHF）o - （CF 2）p X表示的氟化乳化剂，其中m = 0 到3; n = 1〜5; o = 0至1; p = 1〜3; t = 1〜10; 并且当t = 2时，o <0; 并且进一步其中X选自羧酸基团和羧酸基团的盐。 还提供了通过使用这种氟化乳化剂在含氟单体和含有这些含氟弹性体的制品的乳液聚合中制备含氟弹性体的方法。 还提供了包含可交联氟化弹性体和这种氟化乳化剂的水性混合物的含氟弹性体分散体。 用这种氟化乳化剂生产的含氟弹性体基本上不含NH 4+和H +以外的阳离子，并具有低的玻璃化转变温度。

公开(公告)号：US20130172477A1

公开(公告)日：2013-07-04

申请号：US13811783

申请日：2011-07-15

申请人： Klaus Hintzer ,  Harald Kaspar ,  Ludwig Mayer ,  Tilman C. Zipplies

发明人： Klaus Hintzer ,  Harald Kaspar ,  Ludwig Mayer ,  Tilman C. Zipplies

IPC分类号： C08F16/24

CPC分类号： C08F214/262 ,  C08F16/24 ,  C09D127/18 ,  C08F2/16

摘要： Provided are a tetrafluoroethylene copolymers having a melting point of at least 317° C., a melt flow index (MFI) at 372° C. and a 5 kg load (MFI 372/5) of from about 0.60 g/10 min up to about 15 g/10 min. Also provided are methods of forming a shaped article using the copolymers described above, shaped articles made with those copolymers and compositions containing such copolymers.

摘要翻译： 提供熔点为317℃，熔体流动指数（MFI）为372℃，5kg负荷（MFI 372/5）为约0.60g / 10min的四氟乙烯共聚物，直到 约15g / 10min。 还提供了使用上述共聚物形成成型制品的方法，用这些共聚物制成的成型制品和含有这种共聚物的组合物。

公开(公告)号：US20100305262A1

公开(公告)日：2010-12-02

申请号：US12682702

申请日：2008-10-10

申请人： Klaus Hintzer ,  Kai H. Lochhaas ,  Michael Jürgens ,  Harald Kaspar ,  Tilman C. Zipplies ,  André Streiter

发明人： Klaus Hintzer ,  Kai H. Lochhaas ,  Michael Jürgens ,  Harald Kaspar ,  Tilman C. Zipplies ,  André Streiter

IPC分类号： C08L27/18 ,  C08F16/24

CPC分类号： C08K5/19 ,  C08F2/24 ,  C08F14/18 ,  C08F214/18 ,  C08K5/095 ,  C08F2/16 ,  C08L27/12

摘要： There is provided a fluoroelastomer characterized by containing one type or more types of fluorinated emulsifiers represented by the formula: F—(CF2)t-[O(CF2)n]m-O—(CHF)o-(CF2)p-X where m=0 to 3; n=1 to 5; o=0 to 1; p=1 to 3; t=1 to 10; and where when t=2 than o≠0; and further where X is selected from a group consisting of a carboxyl acid group and a salt of a carboxylic acid group. A method for preparing fluoroelastomers by using such fluorinated emulsifiers in emulsion polymerization of fluoromonomers and articles containing such fluoroelastomers are also provided. A fluorinated elastomer dispersion including an aqueous mixture of a crosslinkable fluorinated elastomer and such fluorinated emulsifiers are also provided. The fluoroelastomers created with such fluorinated emulsifiers are essentially free of cations other than NH4+ and H+ and have a low glass transition temperature.

摘要翻译： 提供一种含氟弹性体，其特征在于含有一种或多种由式F-（CF 2）t- [O（CF 2）n] m O - （CHF）o - （CF 2）p X表示的氟化乳化剂，其中m = 0 到3; n = 1〜5; o = 0至1; p = 1〜3; t = 1〜10; 其中当t = 2时，o≠0; 并且进一步其中X选自羧酸基团和羧酸基团的盐。 还提供了通过使用这种氟化乳化剂在含氟单体和含有这些含氟弹性体的制品的乳液聚合中制备含氟弹性体的方法。 还提供了包含可交联氟化弹性体和这种氟化乳化剂的水性混合物的含氟弹性体分散体。 用这种氟化乳化剂生产的含氟弹性体基本上不含NH 4+和H +以外的阳离子，并具有低的玻璃化转变温度。