公开(公告)号：US07820781B2

公开(公告)日：2010-10-26

申请号：US10599403

申请日：2005-03-30

Applicant: Anthony Jarvis ,  Mark Frost ,  Mark Rule

Inventor： Anthony Jarvis ,  Mark Frost ,  Mark Rule

IPC: C08K3/22 ,  C08J3/20 ,  C08L67/00 ,  B29C49/00

CPC classification number: C08L67/02 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/14033 ,  B29B2911/1404 ,  B29B2911/14106 ,  B29B2911/14133 ,  B29C49/0005 ,  B29C49/06 ,  B29C51/002 ,  B29C2035/0822 ,  B29K2025/00 ,  B29K2033/08 ,  B29K2067/00 ,  B29K2069/00 ,  B29K2077/00 ,  B29K2105/16 ,  C08K3/01 ,  Y10T428/1321 ,  C08L2666/54

Abstract: A polymer additive for improving the reheat characteristics of a polymer or polymeric composition comprises an inorganic material which is such that a 2.5 mm thick polyethylene terephthalate plaque incorporating the inorganic material has, when tested, an absorption ratio of less than 0.9, wherein the absorption ratio is either the ratio of A1/A2 or the ratio A1/A3, wherein: A1 is the maximum absorption between 400 nm and 550 nm; A2 is the maximum absorption between 700 to 1100 nm; A3 is the maximum absorption between 700 to 1600 nm. Preferred inorganic materials are titanium nitride, indium tin oxide and lanthanum hexaboride.

Abstract translation: 用于改善聚合物或聚合物组合物的再热特性的聚合物添加剂包括无机材料，其使得当测试时，包含无机材料的2.5mm厚的聚对苯二甲酸乙二醇酯板具有小于0.9的吸收比，其中吸收比 是A1 / A2的比例或A1 / A3比，其中：A1是400nm和550nm之间的最大吸收; A2是700至1100nm之间的最大吸收; A3是700至1600nm之间的最大吸收。 优选的无机材料是氮化钛，氧化铟锡和六硼化镧。

公开(公告)号：US20070020422A1

公开(公告)日：2007-01-25

申请号：US11527005

申请日：2006-09-26

Applicant: Mark Rule

Inventor： Mark Rule

IPC: B65D1/02

CPC classification number: C08K5/0091 ,  C08K5/5317 ,  C08L67/02 ,  C09K15/32 ,  Y10T428/1397

Abstract: Methods to decrease aldehyde content of a polymer are provided. An effective amount of an additive that contains a P—H functionality is incorporated into the polymer in the presence of an acidic of basic catalyst compositions are also provided.

公开(公告)号：US06911523B2

公开(公告)日：2005-06-28

申请号：US10621636

申请日：2003-07-17

Applicant: Mark Rule

Inventor： Mark Rule

IPC: C08G63/183 ,  C08K3/22 ,  C08F6/00

CPC classification number: C08K3/22 ,  C08G63/183 ,  Y10S220/906 ,  Y10T428/1352

Abstract: A method to decrease an aldehyde content of a polyester. The method comprises incorporating an effective amount of an additive that is capable of catalyzing a hydride-transfer reaction between an organic donor molecule and an aldehyde in the polyester.

Abstract translation: 降低聚酯醛含量的方法。 该方法包括加入有效量的能够在聚酯中催化有机供体分子和醛之间的氢化物转移反应的添加剂。

公开(公告)号：US20050118371A1

公开(公告)日：2005-06-02

申请号：US10967803

申请日：2004-10-18

Applicant: Yu Shi ,  Mark Rule ,  Christopher Kjorlaug ,  Linda Anthony ,  Thomas Milton

Inventor： Yu Shi ,  Mark Rule ,  Christopher Kjorlaug ,  Linda Anthony ,  Thomas Milton

IPC: B29C49/00 ,  B29C49/06 ,  B65D1/02 ,  C08G63/183 ,  C08G63/672 ,  B65D1/00

CPC classification number: B65D1/0207 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/14033 ,  B29B2911/1404 ,  B29B2911/14106 ,  B29B2911/14133 ,  B29B2911/14593 ,  B29B2911/14653 ,  B29B2911/14713 ,  B29B2911/14906 ,  B29B2911/1498 ,  B29B2911/14986 ,  B29C49/0005 ,  B29C49/06 ,  B29K2067/00 ,  B29K2105/253 ,  B29K2667/00 ,  B29K2995/0017 ,  B29K2995/004 ,  B29K2995/0041 ,  B29K2995/0067 ,  B29K2995/0077 ,  B29L2031/565 ,  B29L2031/7158 ,  C08G63/183 ,  C08G63/672 ,  Y10T428/1352

Abstract: A container is made from a preform comprising a PET Copolymer comprising a diol component having repeat units from ethylene glycol and a non-ethylene glycol diol component and a diacid component having repeat units from terephthalic acid and a non-terephthalic acid diacid component. The total amount of non-ethylene glycol diol component and non-terephthalic acid diacid component is present in the poly(ethylene terephthalate) copolymer in an amount from about 0.2 mole percent to less than 2.2 mole percent. The container is useful in packaging beverages and corresponding methods are disclosed.

Abstract translation: 容器由包含PET共聚物的PET共聚物制成，所述PET共聚物包含具有来自乙二醇和非乙二醇二醇组分的重复单元的二醇组分和具有来自对苯二甲酸和非对苯二甲酸二酸组分的重复单元的二酸组分。 聚对苯二甲酸乙二醇酯共聚物中非乙二醇二醇组分和非对苯二甲酸二酸组分的总量以约0.2摩尔％至小于2.2摩尔％的量存在。 该容器在包装饮料中是有用的，并且公开了相应的方法。

公开(公告)号：US06811826B2

公开(公告)日：2004-11-02

申请号：US10664187

申请日：2003-09-17

Applicant: Mark Rule ,  Yu Shi ,  Horst Ehrich

Inventor： Mark Rule ,  Yu Shi ,  Horst Ehrich

IPC: B05D136

CPC classification number: C08J7/045 ,  B65D1/0215 ,  Y10T428/1352 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/139 ,  Y10T428/1393 ,  Y10T428/31678

Abstract: The coated multilayer structure comprising a polymeric base layer, a zero valent material barrier layer, and a top coat on the zero valent material barrier layer, the top coat comprising a soluble compound capable of reducing the permeability of the multilayer structure to gas or vapor. The zero valent material barrier layer can also enhance barrier to UV light. A method for enhancing the gas or vapor barrier properties or the UV light barrier properties of a multilayer polymeric/inorganic structure is also disclosed. According to one embodiment, Si coated polyethylene terephthalate containers are coated with a gas or vapor barrier enhancing top coat. A method for recycling containers coated with a zero valent material barrier layer is also disclosed.

公开(公告)号：US06762275B1

公开(公告)日：2004-07-13

申请号：US10446094

申请日：2003-05-27

Applicant: Mark Rule ,  Yu Shi

Inventor： Mark Rule ,  Yu Shi

IPC: C08G6302

CPC classification number: C08K5/21 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/14033 ,  B29B2911/1404 ,  B29B2911/14106 ,  B29B2911/14133 ,  B29B2911/1498 ,  B29C49/0005 ,  B29C49/06 ,  B29K2105/0002 ,  B29K2105/253 ,  B29L2031/7158 ,  Y10T428/1321 ,  Y10T428/1352 ,  Y10T428/1397 ,  C08L67/02

Abstract: A method for decreasing acetaldehyde content of melt processed polyester comprising combining with polyester an organic additive compound that scavenges acetaldehyde from polyester. The organic additive compound comprises at least two component molecular fragments, each component molecular fragment comprising at least two hydrogen substituted heteroatoms bonded to carbons of the respective component molecular fragment. Each component molecular fragment is reactive with acetaldehyde in the polyester to form water and a resulting organic compound comprising an unbridged five or six member ring including the at least two heteroatoms. The reduced acetaldehyde content polyester is particularly useful for making containers such as for packaging beverages.

Abstract translation: 一种降低熔融加工聚酯的乙醛含量的方法，包括与聚酯结合从聚酯中清除乙醛的有机添加剂化合物。 有机添加剂化合物包含至少两个组分分子片段，每个组分分子片段包含与相应组分分子片段的碳键合的至少两个氢取代的杂原子。 每个组分分子片段与聚酯中的乙醛反应以形成水，并且所得的有机化合物包含包含至少两个杂原子的未桥连的五或六元环。 还原的乙醛含量的聚酯对于制造用于包装饮料的容器特别有用。

公开(公告)号：US06569479B2

公开(公告)日：2003-05-27

申请号：US10106503

申请日：2002-03-27

Applicant: Mark Rule

Inventor： Mark Rule

IPC: B65B2500

CPC classification number: C08K5/0091 ,  Y10T428/1397 ,  C08L67/00

Abstract: A process for reducing acetaldehyde concentration in beverages contained in polyester-based packaging, wherein oxygen permeation into the container is reduced or eliminated. The polyester contains an oxidation catalyst active for the oxidation of acetaldehyde to acetic acid. A composition comprising a polyester and said oxidation catalyst. A polyester-based container comprising said oxidation catalyst, and a bottled beverage having a polyester-based container comprising an oxidation catalyst active for the oxidation of acetaldehyde to acetic acid.

公开(公告)号：US06548123B1

公开(公告)日：2003-04-15

申请号：US09735313

申请日：2000-12-12

Applicant: George Plester ,  Horst Ehrich ,  Mark Rule

Inventor： George Plester ,  Horst Ehrich ,  Mark Rule

IPC: C23C1640

CPC classification number: C23C14/10 ,  B29B17/0026 ,  B29K2709/08 ,  B29K2995/0067 ,  B29L2031/7158 ,  Y02W30/62

Abstract: A method, composition and system for coating an external surface of containers and in particular, plastic containers, provides for low permeability to gases and vapors. The coating applied to the external surface of the containers is very thin and is comprised of one or several inorganic substances or layers of substances. For example, the coating can include silica which is bonded to the external surface of the container. This coating will be flexible and can be applied regardless of the container's internal pressure or lack thereof. The coating will firmly adhere to the container and possess an enhanced gas barrier effect after pressurization even when the coating is scratched, fractured, flexed and/or stretched. Moreover, this gas barrier enhancement will be substantially unaffected by filling of the container.

Abstract translation: 用于涂覆容器的外表面，特别是塑料容器的方法，组合物和系统提供对气体和蒸气的低渗透性。 施加到容器的外表面的涂层非常薄，并且由一种或多种无机物质或物质层组成。 例如，涂层可以包括结合到容器外表面的二氧化硅。 该涂层将是柔性的，并且可以施加，而不管容器的内部压力或其不足。 即使涂层被刮伤，断裂，弯曲和/或拉伸，涂层也将牢固地附着在容器上并且在加压之后具有增强的阻气效果。 此外，这种阻气增强将基本上不会通过填充容器而受到影响。

公开(公告)号：US06465066B1

公开(公告)日：2002-10-15

申请号：US09309813

申请日：1999-05-11

Applicant: Mark Rule ,  James Ellison Shepherd ,  Colin Beveridge ,  Homaira Naseem

Inventor： Mark Rule ,  James Ellison Shepherd ,  Colin Beveridge ,  Homaira Naseem

IPC: B65B300

CPC classification number: B65D41/0435 ,  Y10T428/1352

Abstract: A packaged potable liquid, such as bottled water, wherein the liquid has little or no plastic off-taste. The packaged liquid includes a closure wherein the closure shell or the liner within the closure comprises a plastic matrix and an organic slip agent dispersed in the plastic matrix, the slip agent being substantially fully ethylenically saturated and the closure or the liner being substantially free of an ethylenically unsaturated compound. The packaged liquid also includes a container which is desirably substantially free of an ethylenically unsaturated compound.

Abstract translation: 包装的饮用液体，例如瓶装水，其中液体几乎没有或没有塑料的异味。 包装的液体包括封闭件，其中封闭壳体或封闭件内的衬垫包括分散在塑料基质中的塑料基质和有机增滑剂，所述增滑剂基本上完全烯属饱和，并且封闭物或衬垫基本上不含 烯属不饱和化合物。 包装的液体还包括期望基本上不含烯属不饱和化合物的容器。

公开(公告)号：US06223683B1

公开(公告)日：2001-05-01

申请号：US08818342

申请日：1997-03-14

Applicant: George Plester ,  Horst Ehrich ,  Mark Rule

Inventor： George Plester ,  Horst Ehrich ,  Mark Rule

IPC: C23C1600

CPC classification number: C23C14/10 ,  B29B17/0026 ,  B29K2709/08 ,  B29K2995/0067 ,  B29L2031/7158 ,  Y02W30/62

Abstract: A method, composition and system for coating an external surface of containers and in particular, plastic containers, provides for low permeability to gases and vapors. The coating applied to the external surface of the containers is very thin and is comprised of one or several inorganic substances or layers of substances. For example, the coating can include silica which is bonded to the external surface of the container. This coating will be flexible and can be applied regardless of the container's internal pressure or lack thereof. The coating will firmly adhere to the container and possess an enhanced gas barrier effect after pressurization even when the coating is scratched, fractured, flexed and/or stretched. Moreover, this gas barrier enhancement will be substantially unaffected by filling of the container.

Abstract translation: 用于涂覆容器的外表面，特别是塑料容器的方法，组合物和系统提供对气体和蒸气的低渗透性。 施加到容器的外表面的涂层非常薄，并且由一种或多种无机物质或物质层组成。 例如，涂层可以包括结合到容器外表面的二氧化硅。 该涂层将是柔性的，并且可以施加，而不管容器的内部压力或其不足。 即使涂层被刮伤，断裂，弯曲和/或拉伸，涂层也将牢固地附着在容器上并且在加压之后具有增强的阻气效果。 此外，这种阻气增强将基本上不会通过填充容器而受到影响。