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91.发明授权公开(公告)号：US07223710B1
公开(公告)日：2007-05-29
申请号：US10624220
申请日：2003-07-22
申请人： Paul A. Sechrist
发明人： Paul A. Sechrist
IPC分类号： B01J20/34
摘要： A process in which halogen is recovered from a cyclic operation for regenerating hydrocarbon conversion catalysts is disclosed. The process uses an arrangement of beds of adsorbent and a circulating stream to return the halogen-containing materials to a regeneration circuit.
摘要翻译： 公开了从用于再生烃转化催化剂的循环操作中回收卤素的方法。 该方法使用吸附剂床和循环流的排列来将含卤素材料返回到再生回路。
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公开(公告)号：US06784132B1
公开(公告)日：2004-08-31
申请号：US10010564
申请日：2001-11-05
申请人： Paul A. Sechrist
发明人： Paul A. Sechrist
IPC分类号： B01J3844
摘要： A method of recovering halogen-containing materials from the cyclic catalyst regeneration operation of a catalytic hydrocarbon conversion process is disclosed. The method uses an arrangement of beds of adsorbent to maintain the halogen-containing materials within a circulating regeneration circuit.
摘要翻译： 公开了一种从催化烃转化方法的循环催化剂再生操作中回收含卤物质的方法。 该方法使用吸附剂床的布置来将含卤物质维持在循环再生回路中。
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公开(公告)号：US06703479B1
公开(公告)日：2004-03-09
申请号：US10011334
申请日：2001-12-03
IPC分类号： C08F600
CPC分类号： B01J8/087 , B01J2208/00212 , B01J2219/00006 , C08G63/80
摘要： A process and apparatus is disclosed for heating or cooling polymer solids in a dispensing section of a solid-state polycondensation reactor. Gas is delivered to the dispensing section of the reactor in which it cools polymer solids in the dispensing section by direct heat exchange. Part of the gas is withdrawn at a point proximate to the dispensing section of the reactor and is cooled. The rest of the gas ascends through a reactive section of the reactor and purges polymer solids of impurities. The gas withdrawn from the reactive section of the reactor is oxidized of impurities and dried and then combined with the gas withdrawn proximate to the dispensing section of the reactor. To achieve uniform heating or cooling of the polymer solids in the dispensing section, a preferred ratio of mass flow rate of gas to the mass flow rate of solids is recommended.
摘要翻译： 公开了用于在固态缩聚反应器的分配部分中加热或冷却聚合物固体的方法和装置。 气体被输送到反应器的分配部分，其中通过直接热交换在分配部分中冷却聚合物固体。 气体的一部分在靠近反应器的分配部分的位置被抽出，并被冷却。 气体的其余部分通过反应器的反应部分上升并清除杂质的聚合物固体。 从反应器的反应部分抽出的气体被杂质氧化并干燥，然后与在反应器的分配部分附近排出的气体组合。 为了实现均匀加热或冷却分配部分中的聚合物固体，推荐气体的质量流量与固体的质量流量的优选比例。
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94.发明授权Cyclic catalytic hydrocarbon conversion process with reduced chloride emissions 失效循环催化烃转化过程，减少氯化物排放
公开(公告)号：US5965473A
公开(公告)日：1999-10-12
申请号：US764868
申请日：1996-12-13
CPC分类号： B01D53/685 , B01J38/10 , B01J38/42 , B01J38/44 , C10G35/06 , B01D2259/40
摘要： A method is disclosed for recovering chlorine-containing species from the outlet gas of a hydrocarbon conversion process with a cyclic regeneration operation. The outlet gas from an off-stream catalyst bed in which regeneration is occurring is passed to another off-stream catalyst bed which contains spent catalyst and which is maintained at sorption conditions. The spent catalyst particles sorb the chlorine-containing species from the outlet gas. This method captures and retains within the hydrocarbon conversion process chlorine-containing species that would otherwise be scrubbed and lost from the process and that would need to be replaced by the injection of make-up chlorine-containing species. This method results in significant savings in operating costs of a cyclic regeneration process. This method is adaptable to many processes for the catalytic conversion of hydrocarbons in which deactivated catalyst are regenerated by a cyclic regeneration operation.
摘要翻译： 公开了一种利用循环再生操作从烃转化过程的出口气中回收含氯物质的方法。 来自再生发生的离岸催化剂床的出口气体被传递到另一个含有废催化剂并且保持在吸附条件下的脱氢催化剂床。 废催化剂颗粒从出口气体中吸附含氯物质。 该方法捕获并保留了碳氢化合物转化过程中含氯物质，否则该物质将被洗涤并从该方法中流失，并且需要通过注入含氯含量物质代替。 这种方法可以显着节省循环再生过程的运行成本。 该方法适用于催化转化烃的许多方法，其中通过循环再生操作再生失活的催化剂。
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公开(公告)号：US5840176A
公开(公告)日：1998-11-24
申请号：US695473
申请日：1996-08-12
摘要： A method for replacing particles in a process that transfers particles is disclosed. This invention employs a seal zone which is in communication with two zones of the process and in which particles that are being added to the process are purged. This invention allows particles to be replaced without reducing the normal rate of particle transfer through the process, which results in a savings in downtime costs. This invention is adaptable to a multitude of processes for the catalytic conversion of hydrocarbons in which deactivated catalyst particles are regenerated.
摘要翻译： 公开了一种在转移颗粒的工艺中替代颗粒的方法。 本发明采用与该工艺的两个区域连通的密封区域，并且其中被添加到该工艺中的颗粒被清除。 本发明允许在不降低通过该过程的颗粒转移的正常速率的情况下更换颗粒，这导致宕机成本的节省。 本发明适用于催化转化烃的多种方法，其中失活的催化剂颗粒被再生。
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公开(公告)号：US5552120A
公开(公告)日：1996-09-03
申请号：US395142
申请日：1995-02-27
申请人： Paul A. Sechrist , David A. Lomas , Edward C. Haun
发明人： Paul A. Sechrist , David A. Lomas , Edward C. Haun
CPC分类号： C10G11/18
摘要： An FCC apparatus uses a highly efficient separation device to remove product from the catalyst so that the reactor vessel receives a low volume of feed hydrocarbons and riser by-products. The separation device encloses an upwardly directed outlet end of a ballistic separation device in low volume disengaging vessel that collects disengaged catalyst from the riser in a dense bed. Immediate contact of the dense bed with a stripping fluid minimizes the amount of hydrocarbons that are carried out of the disengaging vessel into the open volume of the reactor vessel.
摘要翻译： FCC装置使用高效分离装置从催化剂中除去产物，使得反应器容器接收少量的进料烃和立管副产物。 分离装置包围在低容量分离容器中的弹道分离装置的向上指向的出口端，其在致密床中从提升管收集脱离的催化剂。 致密床与剥离流体的立即接触将从分离容器进入的反应器容器的开放体积中的烃的量最小化。
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97.发明授权
公开(公告)号：US5545382A
公开(公告)日：1996-08-13
申请号：US345058
申请日：1994-11-25
申请人： Paul A. Sechrist
发明人： Paul A. Sechrist
CPC分类号： B01J8/06 , B01J8/005 , B01J8/008 , B01J8/12 , B01J2208/00212
摘要： A reactor arrangement and process for contacting a fluid reactant with a particulate catalyst in a plurality of flow channels and discharging converted reactant fluid and particles from the flow channels. The particles are discharged axially from the bottom of the flow channels into an unconfined bed of particles. Reactants are discharged in a transverse direction through the sides of the flow channels and across screen openings located a short distance above the channel outlets. A plurality of chambers regulate fluid flow through sections of the screens and prevent excessive fluid velocity in any section from holding up particle flow through the flow channels. The reactor arrangement and process of this invention is particularly useful for arrangements that may be used to operate a reactor under isothermal or other controlled temperature controlled conditions where a heat transfer fluid surrounds a plurality of tubular conduits or multiple flow channels that confine the particles and reactants.
摘要翻译： 一种用于使流体反应物与多个流动通道中的颗粒催化剂接触并从流动通道排出转化的反应物流体和颗粒的反应器装置和方法。 颗粒从流动通道的底部轴向排出到无约束的颗粒床中。 反应物沿横向方向通过流动通道的侧面排出，并穿过位于通道出口上方短距离的筛网孔。 多个室调节通过筛网部分的流体流动，并且防止任何部分中的过量流体速度阻止颗粒流过流动通道。 本发明的反应器装置和方法对于可用于在等温或其它受控温度控制条件下操作反应器的装置特别有用，其中传热流体包围多个管状管道或限制颗粒和反应物的多个流动通道 。
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公开(公告)号：US5498756A
公开(公告)日：1996-03-12
申请号：US367542
申请日：1995-01-03
摘要： A regeneration process and apparatus eliminates the need for an external chlorination recycle loop. The method and apparatus uses two-pass internal mixing of a chlorine compound input stream and drying gas to both mix and heat the chlorination gas before entering the chlorination zone. The only heat required for the process is a small amount for vaporizing the chlorine containing input stream to prevent the formation of chloride droplets. All other heat for the chlorination zone is supplied internally in the regeneration vessel.
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公开(公告)号：US5397458A
公开(公告)日：1995-03-14
申请号：US173237
申请日：1993-12-27
IPC分类号： B01J8/12 , B01J38/44 , C10G35/12 , C10G35/085
摘要： A regeneration process and apparatus eliminates the need for an external chlorination recycle loop. The method and apparatus uses two-pass internal mixing of a chlorine compound input stream and drying gas to both mix and heat the chlorination gas before entering the chlorination zone. The only heat required for the process is a small amount for vaporizing the chlorine containing input stream to prevent the formation of chloride droplets. All other heat for the chlorination zone is supplied internally in the regeneration vessel.
摘要翻译： 再生方法和装置消除了对外部氯化循环回路的需要。 该方法和装置使用氯化合物输入流和干燥气体的双程内部混合，以在进入氯化区之前混合和加热氯化气体。 该方法所需的唯一热量是用于蒸发含氯输入流的少量以防止形成氯化物液滴。 用于氯化区的所有其他热量在再生容器内部供应。
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公开(公告)号：US5376607A
公开(公告)日：1994-12-27
申请号：US16211
申请日：1993-02-11
申请人： Paul A. Sechrist
发明人： Paul A. Sechrist
IPC分类号： A61K31/43 , B01J8/12 , B01J23/90 , B01J23/96 , B01J38/20 , C10G35/12 , B01J38/24 , B01J38/44
摘要： A semi-continuous process for combusting coke from catalyst particles in a fixed bed is improved by rejecting from the combustion process a high moisture content flue gas stream which is produced by the combustion of a relatively large proportion of the hydrogen in the coke that enters the combustion section during an early stage of combustion. By operating the early stage of combustion at conditions to increase the rate of combustion of the hydrogen in the coke relative to that of the carbon in the coke, the overall equilibrium level of water in a flue gas/recycle gas that circulates through the process is lowered. The high moisture content flue gas stream from the early stage of combustion is rejected separately from the process. Subdivision of the bed and separation of the flue gas streams can be easily accomplished in a vertically arranged catalyst particle bed by adding baffles to the recycle gas distribution space that subdivide the distribution space into separate chambers and by adding baffles to the flue gas collection space that subdivide the collection space into separate chambers. The amount of high moisture content flue gas withdrawn from the process can be equal to the amount of the make-up gas streams entering the flue gas/recycle gas loop.
摘要翻译： 通过从燃烧过程中排除高含水量的烟道气流，可以改善在固定床中从催化剂颗粒燃烧焦炭的半连续方法，该高含水量的烟道气流是通过进入焦炭中的相当大比例的焦炭中的氢的燃烧产生的 燃烧段在燃烧的早期阶段。 通过在提高焦炭中氢的燃烧速率相对于焦炭中的碳的燃烧速率的条件下操作燃烧的早期阶段，通过该过程循环的烟道气/循环气体中的水的总平衡水平为 降低 来自燃烧早期的高含水量烟气流与该方法分开拒绝。 床的细分和烟道气流的分离可以在垂直布置的催化剂颗粒床中容易地实现，通过向循环气体分配空间添加挡板，将分配空间细分成分离的室，并且通过向烟道气收集空间添加挡板， 将收集空间细分为不同的房间。 从该方法抽出的高含水量烟道气的量可以等于进入烟道气/循环气回路的补充气流的量。
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