摘要:
A new adsorbent CO2-ONE for removal of acidic gases such as carbon dioxide and hydrogen sulfide was developed from hydrothermal reaction of natural limestone with natural kaolin via sodium hydroxide. Several synthesis conditions were employed such as initial concentration of NaOH, weight ratio of limestone to kaolin, reaction temperature and pressure. The produced Ca—Na—SiO2—Al2O3 samples were characterized using XRD and EDS and showed that a mixture of Gehlenite Ca2Al(Al1.22Si0.78O6.78)OH0.22 and Stilbite Na5.76Ca4.96(Al15.68Si56.32O144) with percentage of 43 and 57 was successfully produced, respectively. Another produced sample showed the presence of Gehlenite Ca2Al(Al1.22Si0.78O6.78)OH0.22, Stilbite Na5.76Ca4.96(Al15.68Si56.32O144) and Lawsonite CaAl2Si2O7OH2(H2O) with percentage of 4.1 and 7.4 and 88, respectively.
摘要:
Provided are apparatus and systems having a poppet valve assembly and swing adsorption separation techniques related thereto. A poppet valve includes a valve body, a plurality of static valves fixedly secured to the valve body and a single dynamic poppet valve having a plurality of openings. The plurality of static valves align and mate with the plurality of openings. The single dynamic poppet valve reciprocates to selectively open and close the plurality of static valves.
摘要:
Disclosed herein is an apparatus and methods for decontaminating syngas generated in a fluidized-bed gasifier wherein metal contaminants, inter alia, alkali metals, halogens, particulates, and transition metals and sulfur containing contaminants are removed prior to the catalytic thermal cracking of tar and ammonia. Further disclosed is an apparatus and methods for removing ammonia from syngas.
摘要:
A process is proposed for reprocessing the exhaust gas from a plant for producing hydroxylamine or hydroxylammonium salts by catalytic reduction of nitrogen monoxide with hydrogen for the purpose of utilization of at least a part of the nitrogen monoxide and if appropriate hydrogen present in the exhaust gas for producing hydroxylamine or hydroxylammonium salts, which comprises, in a first separation stage, selectively separating off nitrogen monoxide from the exhaust gas of the plant for producing hydroxylamine or hydroxylammonium salts.
摘要:
Apparatus and methods for the production of a secure supply of breathable air are important under conditions where threats from chemical and biological weapons may be present. A method and a multi-stage CATOX system for producing a purified air flow from ambient air which may have nitrogen containing toxicants is provided. The multi-stage CATOX system has a first stage and second stage, at least one of the first or the second stage has a first catalytic heat exchanger with a cold side supporting a first catalyst and a hot side configured to transfer heat therefrom to the first catalyst.
摘要:
Apparatus and method for cleaning air. An air cleaner includes a housing that defines an airflow pathway and a catalytic reactor having a catalyst secured on a porous substrate that is disposed transverse to the airflow pathway. Preferably, the catalyst includes a light activated oxidizing photocatalyst or a thermally activated oxidizing catalyst. A photocatalytic reactor will include a light source directed at a light activated oxidizing photocatalyst, such as TiO2 particles or a binary oxide particle species, which is disposed on the porous substrate. Most preferably, a metal catalyst is disposed on the photocatalyst particles at a concentration or loading between about 0.01 wt % and about 5 wt %. The air cleaner may further comprise an adsorption matrix upstream of the catalytic reactor, optionally in combination with a heater. A particulate filter and/or an electrostatic precipitator may also be disposed upstream of the adsorption matrix and the catalytic reactor.
摘要:
Synthesis gas for FT synthesis is produced using a producing apparatus including an active carbon adsorbing vessel for adsorbing impurities in a natural gas, a hydro-desulfurizer for hydrogenating and desulfurizing sulfur content in the natural gas under a condition of a partial pressure of hydrogen of 100 to 200 kPa, a second hydrogen supplying line for supplying hydrogen to the natural gas between the hydro-desulfurizer and a reactor, the reactor for obtaining synthesis gas by reacting the natural gas, carbon dioxide and steam in the presence of a catalyst for reforming, and a heat recovering boiler for cooling the synthesis gas at a cooling rate of 2000 to 4000° C./second.
摘要:
The present invention generally relates to vacuum pressure swing adsorption (VPSA) processes and apparatus to recover carbon dioxide having a purity of approximately ≧90 mole % from streams containing at least carbon dioxide and hydrogen (e.g., syngas). The feed to the CO2 VPSA unit can be at super ambient pressure. The CO2 VPSA unit produces three streams, a H2-enriched stream, a H2-depleted stream and a CO2 product stream. When the CO2 VPSA unit is installed between an SMR/shift reactor and a H2 PSA unit, hydrogen recovery is expected to be increased by extracting CO2, thereby increasing hydrogen partial pressure in the H2 PSA feed. The stream from the CO2 VPSA unit, normally used as fuel, is recycled as feed to increase CO2 recovery. The recovered CO2 can be further upgraded, sequestered or used in applications such as enhanced oil recovery (EOR).
摘要:
An air supply system for a clean room with a critical machine. An intake duct connects the exterior of the clean room to a make-up air unit, and is configured to transport external air into the make-up air unit. A first air duct connects the make-up air unit to an air conditioning cabinet including a first chemical filter, and is configured to transport the air flowing through the make-up air unit into the air conditioning cabinet. The first chemical filter removes airborne molecular contamination from the air transported into the air conditioning cabinet. A second air duct connects the air conditioning cabinet to the critical machine, and is configured to transport the air flowing through the first chemical filter of the air conditioning cabinet into the critical machine. An exhaust duct connects the critical machine to the exterior of the clean room, discharging waste gas produced in the critical machine.
摘要:
An air supply system for a clean room with a critical machine. An intake duct connects the exterior of the clean room to a make-up air unit, and is configured to transport external air into the make-up air unit. A first air duct connects the make-up air unit to an air conditioning cabinet including a first chemical filter, and is configured to transport the air flowing through the make-up air unit into the air conditioning cabinet. The first chemical filter removes airborne molecular contamination from the air transported into the air conditioning cabinet. A second air duct connects the air conditioning cabinet to the critical machine, and is configured to transport the air flowing through the first chemical filter of the air conditioning cabinet into the critical machine. An exhaust duct connects the critical machine to the exterior of the clean room, discharging waste gas produced in the critical machine.