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公开(公告)号:US12024681B2
公开(公告)日:2024-07-02
申请号:US17859917
申请日:2022-07-07
申请人: UOP LLC
IPC分类号: C10G35/06
CPC分类号: C10G35/06 , C10G2300/1037
摘要: A process increases the concentration of normal paraffins in a feed stream comprising separating a naphtha feed stream into a normal paraffin rich stream and a non-normal paraffin rich stream. A naphtha feed stream may be separated into a normal paraffin stream and a non-normal paraffin stream. An isomerization feed stream is taken from the non-normal paraffin stream and isomerized over an isomerization catalyst to convert non-normal paraffins to normal paraffins and produce an isomerization effluent stream. The isomerization effluent stream may be separated into a propane stream and a C4+ hydrocarbon stream optionally in a single column. The C4+ hydrocarbon stream may be recycled to the step of separating a naphtha feed stream.
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公开(公告)号:US20180223196A1
公开(公告)日:2018-08-09
申请号:US15947579
申请日:2018-04-06
申请人: UOP LLC
发明人: Bryan J. Egolf , Ian G. Horn , David A. Wegerer
IPC分类号: C10G59/02 , C10G35/085
CPC分类号: C10G59/02 , C10G35/04 , C10G35/06 , C10G35/085 , C10G35/12 , C10G2300/104 , C10G2300/1044 , C10G2300/305 , C10G2300/70 , C10G2400/02 , C10G2400/30
摘要: A reforming process is described. The reforming process includes introducing a hydrocarbon stream comprising hydrocarbons having 5 to 12 carbon atoms into a reforming zone containing reforming catalyst, the reforming zone comprising at least two reformers, each reformer having a set of reforming operating conditions, to produce a reformate effluent, wherein the last reformer contains less catalyst than the next to the last reformer.
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公开(公告)号:US20170327604A1
公开(公告)日:2017-11-16
申请号:US15526513
申请日:2015-12-12
发明人: Matthew W. HOLTCAMP , Gregory S. DAY , David F. SANDERS , David C. CALABRO , Quanchang LI , Machteld M.W. MERTENS
IPC分类号: C08F4/6592 , C08F210/02 , C08F4/02 , C08G77/60 , C07D251/30
CPC分类号: C08F4/6592 , B01D15/00 , B01D53/02 , B01D53/0462 , B01D53/047 , B01D67/0088 , B01D69/10 , B01D71/70 , B01D2253/20 , B01D2253/25 , B01D2256/245 , B01D2257/302 , B01D2257/304 , B01D2257/40 , B01D2257/504 , B01D2257/80 , B01J20/0229 , B01J20/0237 , B01J20/06 , B01J20/08 , B01J20/10 , B01J20/103 , B01J20/16 , B01J20/18 , B01J20/22 , B01J20/262 , B01J20/264 , B01J20/28011 , B01J20/28057 , B01J20/28061 , B01J20/28064 , B01J20/28066 , B01J20/28069 , B01J20/28071 , B01J20/28073 , B01J20/28076 , B01J20/28078 , B01J20/28083 , B01J20/286 , B01J20/3042 , B01J20/3204 , B01J20/3212 , B01J20/3236 , B01J20/3238 , B01J20/3272 , B01J23/44 , B01J31/0274 , B01J35/1019 , B01J35/1023 , B01J35/1028 , B01J35/1061 , B01J37/0213 , B01J37/0236 , B01J2220/86 , C01B37/00 , C07D251/30 , C07F7/0807 , C07F7/081 , C07F7/0818 , C08F4/02 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F210/02 , C08G77/26 , C08G77/60 , C10G25/003 , C10G31/09 , C10G35/06 , C10G45/00 , C10G45/04 , C10G45/34 , C10G45/44 , C10G45/46 , C10G45/52 , C10G45/60 , C10G45/64 , C10G47/02 , C10G50/00 , C10K1/32 , C10M101/02 , C23C16/56 , C08F4/027 , C08F210/14 , C08F4/64193 , C08F4/64189 , C08F4/64013 , C08F4/64158 , C08F4/64048 , C08F4/64148 , C08F4/64089 , C08F210/16
摘要: A catalyst system comprising a combination of: 1) an activator; 2) one or more metallocene catalyst compounds; 3) a support comprising an organosilica material, which is a mesoporous organosilica material. The organosilica material is a polymer of at least one monomer of Formula [Z1OZ2 SiCh2]3(i), where Z1 represents a hydrogen atom, a C1-C4 alkyl group, or a bond to a silic-on atom of another monomer and Z2 represents a hydroxyl group, a C1-C4alkoxy group, a C1-C6 salkyl group, or an oxygen atom bonded to a silicon atom of another monomer. This invention further relates to processes to polymerize olefins comprising contacting one or more olefins with the above catalyst system.
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公开(公告)号:US09694356B2
公开(公告)日:2017-07-04
申请号:US15081234
申请日:2016-03-25
发明人: Daqing Zhang , Gaoshan Zang , Yuhong Zhang , Jiaxin Wang , Tao Wang
IPC分类号: B01J20/34 , B01J38/44 , B01J27/32 , B01J38/10 , B01J38/60 , B01J38/04 , B01J38/14 , B01J38/18 , B01J38/62 , B01J27/13 , C10G35/09 , C10G35/06 , B01J37/20
CPC分类号: B01J38/44 , B01J27/13 , B01J27/32 , B01J37/20 , B01J38/04 , B01J38/10 , B01J38/14 , B01J38/18 , B01J38/60 , B01J38/62 , C10G35/06 , C10G35/09
摘要: This disclosure describes a method for regenerating a semi-regenerated reforming catalyst. The method comprises adjusting the reaction temperature to 250-480° C., introducing a sulfur-containing naphtha into the reforming reactor, or stopping introducing a feedstock into the reforming reactor, and introducing a sulfur-containing hydrogen into a recycle gas, until the sulfur content in the catalyst is 0.32-0.8 mass %, then the catalyst is subject to coke-burning, oxychlorination and reduction. Alternatively, the method first subjects the spent catalyst to coke-burning followed by introducing sulfate ions thereinto; and then performing oxychlorination and reduction. Disclosed is still another method for regenerating a platinum-rhenium reforming catalyst, which comprises coke-burning the spent catalyst; introducing sulfur and chlorine in the catalyst by impregnation; and then drying, calcinating and reducing.
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公开(公告)号:US09534177B2
公开(公告)日:2017-01-03
申请号:US13172149
申请日:2011-06-29
申请人: Scott Michael Babitz
发明人: Scott Michael Babitz
IPC分类号: B01J29/06 , B01J37/00 , C10G2/00 , B01D53/94 , B01J29/08 , C01B3/02 , C10G1/08 , C10G11/05 , C10G29/20 , C10G35/06 , C10G49/02 , B01J35/00
CPC分类号: C10G2/33 , B01D53/94 , B01J29/06 , B01J29/084 , B01J35/002 , B01J37/0045 , B01J2229/42 , C01B3/02 , C01B2203/1041 , C10G1/086 , C10G11/05 , C10G29/205 , C10G35/06 , C10G49/02
摘要: Process for the preparation of a catalyst comprising the steps of (a) preparing a slurry comprising clay, zeolite, and quasi-crystalline boehmite, provided that the slurry does not comprise peptized quasi-crystalline boehmite, (b) adding a monovalent acid to the slurry, (c) adding a silicon source to the slurry, and (d) shaping the slurry to form particles. This process leads to a catalyst with high accessibility and high attrition resistance.
摘要翻译: 制备催化剂的方法包括以下步骤:(a)制备包含粘土,沸石和准结晶勃姆石的浆料,条件是浆料不包含胶溶的准晶勃姆石,(b)向 浆料,(c)向浆料中加入硅源,和(d)使浆料成形以形成颗粒。 该方法导致具有高可接近性和高抗磨性的催化剂。
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公开(公告)号:US20160279626A1
公开(公告)日:2016-09-29
申请号:US15081234
申请日:2016-03-25
发明人: Daqing ZHANG , Gaoshan ZANG , Yuhong ZHANG , Jiaxin WANG , Tao WANG
CPC分类号: B01J38/44 , B01J27/13 , B01J27/32 , B01J37/20 , B01J38/04 , B01J38/10 , B01J38/14 , B01J38/18 , B01J38/60 , B01J38/62 , C10G35/06 , C10G35/09
摘要: A method for regenerating semi-regenerated reforming catalyst comprises adjusting the reaction temperature to 250-480° C.; introducing sulfur-containing naphtha into the reforming reactor, so that the sulfur content in the catalyst is 0.32-0.8 mass %; then stopping introducing the raw materials into the reforming reactor; subjecting the catalyst to coke-burning, oxychlorination and reduction. Another method for regenerating semi-regenerated reforming catalyst comprises coke-burning the spent catalyst; introducing sulfate ions thereinto; then performing oxychlorination and reduction. There is still another method for regenerating a platinum-rhenium reforming catalyst, comprising coke-burning the spent catalyst; introducing sulfur and chlorine by impregnation; then drying, calcinating and reducing. The catalysts regenerated by said methods can be used without presulfurization and have excellent regeneration performance.
摘要翻译: 再生再生重整催化剂的方法包括将反应温度调节至250-480℃; 将含硫的石脑油引入重整反应器中,使得催化剂中的硫含量为0.32-0.8质量%; 然后停止将原料引入重整反应器; 对催化剂进行焦烧,氧氯化和还原。 再生再生重整催化剂的另一种方法包括焦炭燃烧废催化剂; 向其中引入硫酸根离子; 然后进行氧氯化和还原。 还有另一种再生铂 - 铼重整催化剂的方法,包括焦炭燃烧废催化剂; 通过浸渍引入硫和氯; 然后干燥,煅烧和还原。 通过所述方法再生的催化剂可以在没有预硫化的情况下使用并且具有优异的再生性能。
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公开(公告)号:US20160167015A1
公开(公告)日:2016-06-16
申请号:US14966534
申请日:2015-12-11
CPC分类号: B01J20/262 , B01D15/00 , B01D53/02 , B01D53/0462 , B01D53/047 , B01D67/0088 , B01D69/10 , B01D71/70 , B01D2253/20 , B01D2253/25 , B01D2256/245 , B01D2257/302 , B01D2257/304 , B01D2257/40 , B01D2257/504 , B01D2257/80 , B01J20/0229 , B01J20/0237 , B01J20/06 , B01J20/08 , B01J20/10 , B01J20/103 , B01J20/16 , B01J20/18 , B01J20/22 , B01J20/264 , B01J20/28011 , B01J20/28057 , B01J20/28061 , B01J20/28064 , B01J20/28066 , B01J20/28069 , B01J20/28071 , B01J20/28073 , B01J20/28076 , B01J20/28078 , B01J20/28083 , B01J20/286 , B01J20/3042 , B01J20/3204 , B01J20/3212 , B01J20/3236 , B01J20/3238 , B01J20/3272 , B01J23/44 , B01J31/0274 , B01J35/1019 , B01J35/1023 , B01J35/1028 , B01J35/1061 , B01J37/0213 , B01J37/0236 , B01J2220/86 , C01B37/00 , C07F7/0807 , C07F7/081 , C07F7/0818 , C08G77/26 , C08G77/60 , C10G25/003 , C10G31/09 , C10G35/06 , C10G45/00 , C10G45/04 , C10G45/34 , C10G45/44 , C10G45/46 , C10G45/52 , C10G45/60 , C10G45/64 , C10G47/02 , C10G50/00 , C10K1/32 , C10M101/02 , C23C16/56
摘要: Adsorbent materials including a porous material support and about 0.5 wt. % to about 30 wt. % of a Group 8 metal ion are provide herein. Methods of making the adsorbent material and processes of using the adsorbent material, e.g., for heteroatom species separation, are also provided herein.
摘要翻译: 包括多孔材料载体的吸附材料和约0.5wt。 %至约30wt。 本文提供了8族金属离子的%。 制备吸附剂材料的方法和使用吸附材料的方法,例如用于杂原子物质分离的方法也在本文中提供。
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公开(公告)号:US09035118B2
公开(公告)日:2015-05-19
申请号:US13327185
申请日:2011-12-15
CPC分类号: C10G35/06 , C10G2400/30
摘要: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and partially processing each feedstream in separate reactors. The processing includes passing the light stream to a combination hydrogenation/dehydrogenation reactor. The process reduces the energy by reducing the endothermic properties of intermediate reformed process streams.
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公开(公告)号:US20150073190A1
公开(公告)日:2015-03-12
申请号:US14542856
申请日:2014-11-17
发明人: An-Hsiang Wu
CPC分类号: B01J29/90 , B01J29/62 , B01J29/74 , B01J38/12 , B01J38/42 , B01J38/44 , B01J38/46 , C07C5/367 , C07C5/412 , C07C5/417 , C07C2529/068 , C07C2529/74 , C10G35/06 , C10G35/095 , C10G45/70 , C10G2300/708
摘要: Methods for treating or rejuvenating a spent catalyst are disclosed. Such methods can employ a step of halogenating the spent catalyst, followed by decoking the halogenated spent catalyst. The halogenation step can utilize fluorine and chlorine together, or fluorine and chlorine can be applied sequentially.
摘要翻译: 公开了用于处理或再生废催化剂的方法。 这样的方法可以采用卤化废催化剂的步骤,然后除去卤化的废催化剂。 卤化步骤可以一起使用氟和氯,也可以依次施加氟和氯。
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公开(公告)号:US08912108B2
公开(公告)日:2014-12-16
申请号:US13758144
申请日:2013-02-04
发明人: An-Hsiang Wu
CPC分类号: B01J29/90 , B01J29/62 , B01J29/74 , B01J38/12 , B01J38/42 , B01J38/44 , B01J38/46 , C07C5/367 , C07C5/412 , C07C5/417 , C07C2529/068 , C07C2529/74 , C10G35/06 , C10G35/095 , C10G45/70 , C10G2300/708
摘要: Methods for treating or rejuvenating a spent catalyst are described. These methods can employ a step of halogenating the spent catalyst, followed by decoking the halogenated spent catalyst. The halogenation step can utilize fluorine and chlorine together, or fluorine and chlorine can be applied sequentially.
摘要翻译: 描述了用于处理或再生废废催化剂的方法。 这些方法可以采用将废催化剂卤化的步骤,然后除去卤化的废催化剂。 卤化步骤可以一起使用氟和氯,也可以依次施加氟和氯。
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