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91.发明授权Process for producing fatty alcohols by hydrogenation of fatty acid triglycerides on a copper-containing heterogeneous catalyst 有权通过在含铜非均相催化剂上氢化脂肪酸甘油三酯来生产脂肪醇的方法公开(公告)号：US08946490B2
公开(公告)日：2015-02-03
申请号：US13319830
申请日：2010-05-19
IPC分类号： C07C27/04 , C07C29/149 , C07C29/17
CPC分类号： C07C29/149 , C07C29/177 , C07C31/125
摘要： The present invention relates to a process for preparing fatty alcohols, in which a stream comprising at least one fatty acid triglyceride is provided and this stream is subjected to a hydrogenation in the presence of a heterogeneous copper catalyst.
摘要翻译： 本发明涉及制备脂肪醇的方法，其中提供包含至少一种脂肪酸甘油三酯的料流，并且在异质铜催化剂存在下使该料流进行氢化。
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92.发明授权Method of regenerating ruthenium catalysts for the ring hydrogenation of phthalates 有权再生用于邻苯二甲酸酯环加氢的钌催化剂的方法公开(公告)号：US08598060B2
公开(公告)日：2013-12-03
申请号：US12375598
申请日：2007-07-25
IPC分类号： B01J20/34
CPC分类号： B01J23/462 , B01J21/04 , B01J23/96 , B01J35/0053 , B01J35/008 , B01J35/08 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/1066 , B01J35/1071 , B01J35/1076 , B01J35/108 , B01J37/18 , B01J38/04 , C07C51/36 , C07C67/303 , C07C2601/14 , Y02P20/584 , C07C61/09 , C07C69/75
摘要： The present invention relates to a method of regenerating a ruthenium catalyst for the hydrogenation of phthalates, which comprises flushing the catalyst with inert gas in a regeneration step until the original activity or part of the original activity has been attained.
摘要翻译： 本发明涉及一种再生用于氢化邻苯二甲酸酯的钌催化剂的方法，其包括在再生步骤中用惰性气体冲洗催化剂，直到达到原始活性或部分原始活性。
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93.发明授权Method for producing 1,2-propandiol by hydrogenating glycerine in a two-step reactor cascade 有权通过在两步反应器级联中氢化甘油来生产1,2-丙二醇的方法公开(公告)号：US08252962B2
公开(公告)日：2012-08-28
申请号：US12675900
申请日：2008-08-29
申请人： Jochem Henkelmann , Roman Prochazka , Oliver Bey , Stephan Maurer , Jochen Steiner , Heiko Urtel , Gerhard Theis , Peter Wahl , Petra Maier , Georg Mehrl
发明人： Jochem Henkelmann , Roman Prochazka , Oliver Bey , Stephan Maurer , Jochen Steiner , Heiko Urtel , Gerhard Theis , Peter Wahl , Petra Maier , Georg Mehrl
IPC分类号： C07C29/60
CPC分类号： B01J23/83 , B01J23/002 , B01J35/0006 , B01J37/0203 , B01J37/18 , B01J2523/00 , C07C29/60 , C07C67/03 , Y02E50/13 , C07C31/205 , C07C69/24 , C07C69/52 , B01J2523/17 , B01J2523/31 , B01J2523/3706
摘要： The present invention relates to a process for preparing 1,2-propanediol, in which a glycerol-containing stream, especially a stream obtained on the industrial scale in the production of biodiesel, is subjected to a hydrogenation in a two-stage reactor cascade.
摘要翻译： 本发明涉及一种制备1,2-丙二醇的方法，其中含有甘油的料流，特别是在生产生物柴油的工业规模上获得的物流在两级反应器级联中进行氢化。
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公开(公告)号：US08212069B2
公开(公告)日：2012-07-03
申请号：US12446460
申请日：2007-10-18
申请人： Ralf Boehling , Sven Kueber , Stefan Maixner , Eckhard Stroefer , Jochem Henkelmann , Georg Krug , Werner Bolz
发明人： Ralf Boehling , Sven Kueber , Stefan Maixner , Eckhard Stroefer , Jochem Henkelmann , Georg Krug , Werner Bolz
IPC分类号： C07C263/00
CPC分类号： C07C263/10 , B01J2219/00038 , B01J2219/00869 , C07C2601/14 , C07C265/14
摘要： Process for preparing isocyanates by phosgenation of amines, wherein phosgene and amine are brought into contact in at least 2 mixing chambers connected in parallel.
摘要翻译： 通过胺的光气化制备异氰酸酯的方法，其中光气和胺在至少两个并联连接的混合室中接触。
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95.发明申请公开(公告)号：US20110196181A1
公开(公告)日：2011-08-11
申请号：US13088627
申请日：2011-04-18
申请人： Michael Becker , Axel Salden , Bianca Stäck , Jochem Henkelmann , Steffen Springmann , Frederik van Laar , Wilhelm Ruppel , Peter Resch , Michael Bender
发明人： Michael Becker , Axel Salden , Bianca Stäck , Jochem Henkelmann , Steffen Springmann , Frederik van Laar , Wilhelm Ruppel , Peter Resch , Michael Bender
CPC分类号： C07C13/18 , C07C5/10 , C07C7/1485 , C07C2521/04 , C07C2521/08 , C07C2523/46 , C10G65/08 , C10G67/02 , C10G2300/1096 , C10G2300/202 , Y02P20/125
摘要： Processes comprising: providing a starting material comprising one or more aromatic hydrocarbons, and having an aromatic sulfur compound content and a total sulfur content; reducing the aromatic sulfur compound content and the total sulfur content in the starting material; and hydrogenating the one or more aromatic hydrocarbons in the presence of a supported ruthenium catalyst and hydrogen.
摘要翻译： 方法包括：提供包含一种或多种芳族烃并具有芳族硫化合物含量和总硫含量的原料; 降低原料中芳香族硫化合物含量和总硫含量; 在负载的钌催化剂和氢气的存在下氢化一种或多种芳族烃。
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公开(公告)号：US07790937B2
公开(公告)日：2010-09-07
申请号：US12281406
申请日：2007-03-02
申请人： Jochem Henkelmann , Michael Becker , Jochen Buerkle , Peter Wahl , Gerhard Theis , Stephen Maurer
发明人： Jochem Henkelmann , Michael Becker , Jochen Buerkle , Peter Wahl , Gerhard Theis , Stephen Maurer
IPC分类号： C07C29/132
摘要： The present invention relates to a process for the preparation of 1,2-propanediol, in which a glycerol-containing stream, in particular a stream obtained on an industrial scale in the production of biodiesel, is subjected to a hydrogenation.
摘要翻译： 本发明涉及一种制备1,2-丙二醇的方法，其中含有甘油的料流，特别是在生产生物柴油的工业规模上获得的物流，经受氢化。
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97.发明申请CATALYST AND PROCESS FOR HYDROGENATING ORGANIC COMPOUNDS COMPRISING HYDROGENATABLE GROUPS 有权用于加氢可加工组合的有机化合物的催化剂和方法公开(公告)号：US20100152436A1
公开(公告)日：2010-06-17
申请号：US11993777
申请日：2006-06-20
CPC分类号： B01J23/462 , B01J21/08 , B01J35/1019 , B01J37/0205
摘要： The invention relates to a shell catalyst containing ruthenium as an active metal, alone or together with at least one other metal of the auxiliary group IB, VIIB or VIII of the periodical system of the elements (CAS version), and applied to a carrier containing silicon dioxide as a carrier material. The invention also relates to a method for producing said shell catalyst, and to a method for hydrogenating an organic compound containing hydrogenable groups, preferably for hydrogenating a carbocyclic aromatic group to form the corresponding carbocyclic aliphatic groups or for hydrogenating aldehydes to form the corresponding alcohols, using the inventive shell catalyst. The invention further relates to the use of the inventive shell catalyst for hydrogenating an organic compound containing hydrogenable groups, preferably for hydrogenating a carbocyclic aromatic group to form the corresponding carbocyclic aliphatic groups or for hydrogenating aldehydes to form the corresponding alcohols.
摘要翻译： 本发明涉及含有钌作为活性金属的壳催化剂，其单独或与元素周期性系统（CAS版）的辅助基团IB，VIIB或VIII的至少一种其它金属一起应用于含有 二氧化硅为载体材料。 本发明还涉及一种用于生产所述壳催化剂的方法，以及用于氢化含有可氢化基团的有机化合物的方法，优选用于氢化碳环芳族基团以形成相应的碳环脂族基团或用于氢化醛以形成相应的醇， 使用本发明的壳催化剂。 本发明还涉及本发明的壳催化剂用于氢化含有可氢化基团的有机化合物，优选用于氢化碳环芳族基团以形成相应的碳环脂族基团或用于氢化醛以形成相应的醇。
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公开(公告)号：US20090216050A1
公开(公告)日：2009-08-27
申请号：US12281406
申请日：2007-03-02
申请人： Jochem Henkelmann , Michael Becker , Jochen Bürkle , Peter Wahl , Gerhard Theis , Stephan Maurer
发明人： Jochem Henkelmann , Michael Becker , Jochen Bürkle , Peter Wahl , Gerhard Theis , Stephan Maurer
IPC分类号： C07C29/132
摘要： The present invention relates to a process for the preparation of 1,2-propanediol, in which a glycerol-containing stream, in particular a stream obtained on an industrial scale in the production of biodiesel, is subjected to a hydrogenation.
摘要翻译： 本发明涉及一种制备1,2-丙二醇的方法，其中含有甘油的料流，特别是在生产生物柴油的工业规模上获得的物流，进行氢化。
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公开(公告)号：US20070299282A1
公开(公告)日：2007-12-27
申请号：US11719983
申请日：2005-11-24
申请人： Thorsten Rohde , Jochem Henkelmann
发明人： Thorsten Rohde , Jochem Henkelmann
IPC分类号： C07C51/60
摘要： A process for preparing phthaloyl chloride by reacting phthalic anhydride with a chlorinating agent (I) selected from the group of thionyl chloride and phosgene in the presence of a catalyst at a temperature of from 80 to 200° C. and a pressure of from 0.01 to 10 MPa abs, in which the catalyst (II) used is triphenylphosphine, triphenylphosphine oxide or a mixture thereof.
摘要翻译： 一种通过邻苯二甲酸酐与选自亚硫酰氯和光气的氯化剂（I）在催化剂存在下，在80-200℃和0.01〜 10MPa abs，其中使用的催化剂（II）是三苯基膦，三苯基氧化膦或其混合物。
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公开(公告)号：US06956141B1
公开(公告)日：2005-10-18
申请号：US09913979
申请日：2000-02-22
申请人： Melanie Maas-Brunner , Jochem Henkelmann , Gerd Kaibel , Alois Kindler , Christian Knoll , Harald Rust , Christian Tragut , Manfred Stroezel , Udo Rheude , Rudolf Erich Lorenz , Juan Aiscar
发明人： Melanie Maas-Brunner , Jochem Henkelmann , Gerd Kaibel , Alois Kindler , Christian Knoll , Harald Rust , Christian Tragut , Manfred Stroezel , Udo Rheude , Rudolf Erich Lorenz , Juan Aiscar
IPC分类号： C07C29/17 , C07C29/42 , C07C33/042 , C07C33/04 , C07C33/044 , C07C33/046
CPC分类号： C07C29/42 , C07C29/172 , Y02P20/582 , C07C33/044 , C07C33/042 , C07C31/20
摘要： A process for preparing at least one unsaturated alcohol (B) comprises the steps (I) to (III) below: (I) reaction of at least one alkali metal hydroxide or alkaline earth metal hydroxide with at least one alcohol (A) in at least one organic solvent (L) to give a mixture (G-I) comprising at least the alcohol (A), the solvent (L) and an alkoxide (AL); (II) reaction of at least one carbonyl compound of the formula R—CO—R′ with at least one alkyne of the formula R″—C≡C—H and the mixture (G-I) obtained in step (I) to give a mixture (G-II) comprising at least the alcohol (A), the solvent (L) and an unsaturated alcohol (B); (III) distillation of the mixture (G-II) obtained in step (II) to give the alcohol or alcohols (B) and a mixture (G-III) comprising the solvent (L) and the alcohol (A), wherein the solvent (L) obtained in step (III) and the alcohol (A) obtained in step (III) are recycled as a mixture to step (I).
摘要翻译： 一种制备至少一种不饱和醇（B）的方法包括下列步骤（I）至（III）：（I）至少一种碱金属氢氧化物或碱土金属氢氧化物与至少一种醇（A）在 至少一种有机溶剂（L），得到至少包含醇（A），溶剂（L）和醇盐（AL）的混合物（GI） （II）至少一种式R-CO-R'的羰基化合物与至少一种式R'-C≡CH的炔和步骤（I）中获得的混合物（GI）的反应，得到混合物 至少包含醇（A），溶剂（L）和不饱和醇（B）的化合物（G-II）; （II）中获得的混合物（G-II）的蒸馏（III），得到醇或醇（B）和包含溶剂（L）和醇（A）的混合物（G-III），其中 将步骤（III）中获得的溶剂（L）和步骤（III）中获得的醇（A）作为步骤（I）的混合物再循环。
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