摘要:
The present invention relates to a continuous process for preparing para-alkyl-substituted cyclohexylmethanols, especially 4-isopropylcyclohexylmethanol, by catalytically hydrogenating the corresponding aldehydes or ketones in the presence of hydrogen and in the presence of a catalyst which comprises, as an active metal, ruthenium applied to a support, the support comprising Al2O3 and/or SiO2, and the catalyst being used in the form of a fixed bed catalyst in a hydrogenation reactor or in a plurality of hydrogenation reactors connected in series.
摘要翻译:本发明涉及通过在氢存在下催化氢化相应的醛或酮并且在催化剂存在下,在作为活性金属的催化剂存在下,制备对 - 烷基取代的环己基甲醇,特别是4-异丙基环己基甲醇的连续方法, 钌施加到载体上,载体包含Al 2 O 3和/或SiO 2,催化剂以氢化反应器或串联连接的多个氢化反应器中的固定床催化剂的形式使用。
摘要:
Process for regenerating a ruthenium-containing supported hydrogenation catalyst. wherein the catalyst is treated with steam and then dried. Integrated process for hydrogenating benzene to cyclohexane in the presence of a ruthenium-containing supported catalyst, comprising, as well as the hydrogenation step. the catalyst regeneration steps.
摘要:
The present invention relates to a process for preparing fatty alcohols, in which a stream comprising at least one fatty acid triglyceride is provided and this stream is subjected to a hydrogenation in the presence of a heterogeneous copper catalyst.
摘要:
The present invention relates to an eggshell catalyst comprising an active metal selected from the group consisting of ruthenium, rhodium, palladium, platinum and mixtures thereof, applied to a support material comprising silicon dioxide, wherein the pore volume of the support material is 0.6 to 1.0 ml/g, determined by Hg porosimetry, the BET surface area is 280 to 500 m2/g, and at least 90% of the pores present have a diameter of 6 to 12 nm, to a process for preparing this eggshell catalyst, to a process for hydrogenating an organic compound which comprises at least one hydrogenatable group using the eggshell catalyst, and to the use of the eggshell catalyst for hydrogenating an organic compound.
摘要翻译:本发明涉及包含选自钌,铑,钯,铂及其混合物的活性金属的蛋壳催化剂,其应用于包含二氧化硅的载体材料,其中载体材料的孔体积为0.6至1.0 ml / g,通过Hg孔隙率法测定,BET表面积为280-500m2 / g,并且至少90%的孔存在的直径为6至12nm,制备该蛋壳催化剂的方法为 使用蛋壳催化剂氢化含有至少一个可氢化基团的有机化合物的方法,以及使用蛋壳催化剂氢化有机化合物。
摘要:
The present invention relates to a method of regenerating a ruthenium catalyst suitable for hydrogenation, which comprises flushing the catalyst with inert gas in a regeneration step until the original activity or part of the original activity has been attained. The method is particularly useful for ruthenium catalysts which are used for the hydrogenation of aromatics.
摘要:
The present invention relates to a continuous process for preparing para-alkyl-substituted cyclohexylmethanols, especially 4-isopropylcyclohexylmethanol, by catalytically hydrogenating the corresponding aldehydes or ketones in the presence of hydrogen and in the presence of a catalyst which comprises, as an active metal, ruthenium applied to a support, the support comprising Al2O3 and/or SiO2, and the catalyst being used in the form of a fixed bed catalyst in a hydrogenation reactor or in a plurality of hydrogenation reactors connected in series.
摘要翻译:本发明涉及通过在氢存在下催化氢化相应的醛或酮并且在催化剂存在下,在作为活性金属的催化剂存在下,制备对 - 烷基取代的环己基甲醇,特别是4-异丙基环己基甲醇的连续方法, 钌施加到载体上,载体包含Al 2 O 3和/或SiO 2,催化剂以氢化反应器或串联连接的多个氢化反应器中的固定床催化剂的形式使用。
摘要:
The present invention relates to a process for preparing fatty alcohols, in which a stream comprising at least one fatty acid triglyceride is provided and this stream is subjected to a hydrogenation in the presence of a heterogeneous copper catalyst.
摘要:
The present invention relates to an eggshell catalyst comprising an active metal selected from the group consisting of ruthenium, rhodium, palladium, platinum and mixtures thereof, applied to a support material comprising silicon dioxide, wherein the pore volume of the support material is 0.6 to 1.0 ml/g, determined by Hg porosimetry, the BET surface area is 280 to 500 m2/g, and at least 90% of the pores present have a diameter of 6 to 12 nm, to a process for preparing this eggshell catalyst, to a process for hydrogenating an organic compound which comprises at least one hydrogenatable group using the eggshell catalyst, and to the use of the eggshell catalyst for hydrogenating an organic compound.
摘要翻译:本发明涉及包含选自钌,铑,钯,铂及其混合物的活性金属的蛋壳催化剂,其应用于包含二氧化硅的载体材料,其中载体材料的孔体积为0.6至1.0 ml / g,通过Hg孔隙率法测定,BET表面积为280-500m2 / g,并且至少90%的孔存在的直径为6至12nm,制备该蛋壳催化剂的方法为 使用蛋壳催化剂氢化含有至少一个可氢化基团的有机化合物的方法,以及使用蛋壳催化剂氢化有机化合物。
摘要:
The present invention relates to a process for preparing cyclohexyl-substituted phosphines. The invention further relates to a process for preparing cyclohexyl-substituted phosphine oxides which can be used as intermediates in the preparation of cyclohexyl-substituted phosphines.