Organofunctional silanes and their mixtures
    93.
    发明授权
    Organofunctional silanes and their mixtures 有权
    有机官能硅烷及其混合物

    公开(公告)号:US07919650B2

    公开(公告)日:2011-04-05

    申请号:US11358550

    申请日:2006-02-21

    CPC classification number: C08G77/28 C07F7/1804

    Abstract: Organofunctional silanes, inclusive of dimers and oligomers, are provided in which individual silanes possess both free and blocked mercaptan functionality or particular mixtures of the organofunctional silanes possess both free and blocked mercaptan functionality. The organofunctional silanes and silane mixtures are useful, inter alia, as coupling agents for elastomeric compositions, e.g., rubber formulations employed in the manufacture of tires, where they exhibit a desirable balance of low scorch and good performance properties.

    Abstract translation: 提供有机官能硅烷,包括二聚体和低聚物,其中单独的硅烷具有游离和封端的硫醇官能团或有机官能硅烷的特定混合物具有游离和封端的硫醇官能团。 有机官能硅烷和硅烷混合物尤其可用作弹性体组合物的偶联剂,例如用于制造轮胎的橡胶制剂,其中它们具有低焦度和良好性能特性的理想平衡。

    Nanosized Copper Catalyst Precursors For The Direct Synthesis Of Trialkoxysilanes
    94.
    发明申请
    Nanosized Copper Catalyst Precursors For The Direct Synthesis Of Trialkoxysilanes 有权
    用于直接合成三烷氧基硅烷的纳米铜催化剂前体

    公开(公告)号:US20110065948A1

    公开(公告)日:2011-03-17

    申请号:US12950445

    申请日:2010-11-19

    CPC classification number: C07F7/025 B01J23/72

    Abstract: The present invention provides a process for using nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and mixtures thereof, as sources of catalytic copper in the Direct Synthesis of trialkoxysilanes of the formula HSi(OR)3 wherein R is an alkyl group containing from 1 to 6 carbon atoms inclusive. The nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and their mixtures of this invention have average particle sizes that are in the range from about 0.1 to about 60 nanometers, preferably from about 0.1 to about 30 nanometers, and most preferably from about 0.1 to about 15 nanometers. Nanosized sources of catalytic copper afford high dispersion of catalytic sites on silicon and contribute to high reaction rates, high selectivity and high silicon conversion. The nanosized copper catalyst precursors of the invention permit the use of substantially reduced levels of copper compared to conventional practice.

    Abstract translation: 本发明提供了在直接合成式HSi(OR)3的三烷氧基硅烷中使用纳米尺寸铜,纳米尺寸铜氧化物,纳米尺寸氯化铜,其它纳米铜盐及其混合物作为催化铜的来源的方法,其中R为 含有1〜6个碳原子的烷基。 本发明的纳米尺寸的铜,纳米尺寸的氧化铜,纳米尺寸的氯化铜,其他的纳米级铜盐及其混合物的平均粒度范围为约0.1至约60纳米,优选为约0.1至约30纳米, 最优选约0.1至约15纳米。 催化铜的纳米化来源提供了硅上催化位点的高分散性,有助于高反应速率,高选择性和高硅转化率。 与常规实践相比,本发明的纳米尺寸铜催化剂前体允许使用显着降低的铜含量。

    Rubber compositions comprising coupling agents for mineral-filled elastomer compositions
    95.
    发明授权
    Rubber compositions comprising coupling agents for mineral-filled elastomer compositions 有权
    包含矿物填充弹性体组合物的偶联剂的橡胶组合物

    公开(公告)号:US07902391B2

    公开(公告)日:2011-03-08

    申请号:US12384809

    申请日:2009-04-09

    CPC classification number: C08K5/548 C08K5/5419 C08K9/06 C08L21/00

    Abstract: A composition of matter is disclosed that comprises at least one silane coupling agent for coupling an elastomer and a filler wherein said silane comprises at least one hydrolysable group that, upon compounding said silane with said elastomer and filler, is released to yield a compound that improves downstream processability of the compounded composition or the properties of the final rubber product or both.

    Abstract translation: 公开了一种物质组合物,其包含用于偶联弹性体和填料的至少一种硅烷偶联剂,其中所述硅烷包含至少一种可水解基团,在将所述硅烷与所述弹性体和填料混合后,其可释放以产生改进的化合物 复合组合物的下游加工性或最终橡胶制品的性能或两者兼有。

    SELECTIVE HYDROSILYLATION METHOD AND PRODUCT
    98.
    发明申请
    SELECTIVE HYDROSILYLATION METHOD AND PRODUCT 审中-公开
    选择性氢化方法和产品

    公开(公告)号:US20110021460A1

    公开(公告)日:2011-01-27

    申请号:US12891886

    申请日:2010-09-28

    CPC classification number: C08G77/38 C08G77/46 Y10S424/10

    Abstract: An asymmetric siloxane is made by reacting a silicone having the formula MHDxM′H where MH is R1R2HSiO1/2, M′H is R4R5HSiO1/2 and x is an integer 0≦x≦10 under selective hydrosilylation conditions in the presence of a precious metal hydrosilylation catalyst, with a first olefinic compound and in a second step, a monohydridosiloxane produced in the first step is reacted under hydrosilylating conditions with another olefinic compound different from the first olefinic compound.

    Abstract translation: 通过在贵金属存在下,在选择性氢化硅烷化条件下使具有式MHDxM'H的硅酮,其中MH为R1R2HSiO1 / 2,M'H为R4R5HSiO1 / 2,x为0和n1E; x和n1E为10, 氢化硅烷化催化剂与第一烯属化合物反应,在第二步中,在氢化硅烷化条件下使第一步生产的单氢硅氧烷与另一种不同于第一种烯烃化合物的烯属化合物反应。

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