公开(公告)号：US20080193835A1

公开(公告)日：2008-08-14

申请号：US12106079

申请日：2008-04-18

Applicant: Yuriy V. Mikhaylik

Inventor： Yuriy V. Mikhaylik

IPC: H01M10/40

CPC classification number: H01M10/0567 ,  H01M4/13 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/38 ,  H01M4/382 ,  H01M4/5815 ,  H01M4/60 ,  H01M6/164 ,  H01M6/166 ,  H01M6/168 ,  H01M10/052 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2220/30 ,  H01M2300/0028 ,  Y02E60/122

Abstract: Disclosed is an additive for an electrochemical cell wherein the additive includes an N—O bond. The additive is most preferably included in a nonaqueous electrolyte of the cell. Also disclosed are cells and batteries including the additive, and methods of charging the batteries and cells. An electrochemical cell including the additive preferably has an anode that includes lithium and a cathode including an electroactive sulfur-containing material.

Abstract translation: 公开了一种用于电化学电池的添加剂，其中添加剂包括N-O键。 添加剂最优选包含在电池的非水电解质中。 还公开了包括添加剂的电池和电池，以及对电池和电池充电的方法。 包括添加剂的电化学电池优选具有包括锂和包括电活性含硫材料的阴极的阳极。

公开(公告)号：US20080171265A1

公开(公告)日：2008-07-17

申请号：US11883607

申请日：2006-01-19

Applicant: Jiro Iriyama ,  Kentaro Nakahara ,  Shigeyuki Iwasa ,  Masahiro Suguro ,  Masaharu Satoh

Inventor： Jiro Iriyama ,  Kentaro Nakahara ,  Shigeyuki Iwasa ,  Masahiro Suguro ,  Masaharu Satoh

IPC: H01M4/58 ,  B05D5/12

CPC classification number: H01M4/60 ,  H01M4/137 ,  H01M4/1399 ,  H01M4/625 ,  H01M10/0525 ,  H01M2004/028

Abstract: In order to provide a positive electrode for a secondary battery having a low electric resistance and a large mechanical strength, and a secondary battery capable of charge and discharge using a large current and having a large capacity and excellent in storage characteristics, there is used a positive electrode for a secondary battery comprising an active material layer at least comprising a radical compound and a carbon fiber in which a graphite structure has an average value of interlayer distances d002 in the range of not less than 0.335 nm and not more than 0.340 nm. Such a carbon fiber having the interlayer distance has a modulus of elongation in the range of not less than 200 GPa and not more than 800 GPa. Particularly the carbon fiber preferably has a volume resistivity in the range of not less than 200μΩ·cm and not more than 2000μΩ·cm. The carbon fiber is preferably a vapor-grown carbon fiber or a graphitized carbon fiber derived from a mesophase pitch as a precursor.

Abstract translation: 为了提供具有低电阻和大机械强度的二次电池用正极，以及能够使用大电流进行充放电且容量大，储存特性优异的二次电池， 二次电池用正极，其包含至少包含自由基化合物和碳纤维的活性物质层，其中石墨结构的层间距离d 002的平均值在不小于0.335的范围内 nm且不大于0.340nm。 具有层间距离的这种碳纤维的伸长模量在200GPa以上且800GPa以下的范围。 特别地，碳纤维的体积电阻率优选为200μm以上且2000μm以下的体积电阻率。 碳纤维优选为气相生长碳纤维或由中间相沥青衍生的石墨化碳纤维作为前体。

公开(公告)号：US20080160406A1

公开(公告)日：2008-07-03

申请号：US11768485

申请日：2007-06-26

Applicant: Yoshikazu Kato ,  Kenichi Kawase

Inventor： Yoshikazu Kato ,  Kenichi Kawase

IPC: H01M4/60

CPC classification number: H01M4/60 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/604 ,  H01M4/621 ,  H01M4/622 ,  H01M10/052 ,  H01M10/0525 ,  Y02E60/122

Abstract: A battery capable of improving the safety when the battery is broken while securing the cycle characteristics is provided. The battery includes a cathode, an anode, and an electrolyte. The anode includes an anode active material layer that has a resin containing sulfur (S). Compared to a case not having the resin containing resin, a sufficient discharge capacity can be obtained even when charge and discharge is repeated, and smoking and ignition are not easily generated when the battery is broken. Thereby, the cycle characteristics are secured, and the safety when the battery is broken is improved.

Abstract translation: 提供一种能够在确保循环特性的同时在电池破损时提高安全性的电池。 电池包括阴极，阳极和电解质。 阳极包括具有含硫（S）的树脂的负极活性物质层。 与不含树脂的树脂相比，即使重复进行充放电也能够获得充分的放电容量，并且在电池破损时不容易产生吸烟和点火。 由此，确保了循环特性，提高了电池破损时的安全性。

公开(公告)号：US07378194B2

公开(公告)日：2008-05-27

申请号：US10954487

申请日：2004-10-01

Applicant: Christophe Michot ,  Michel Armand ,  Michel Gauthier ,  Nathalie Ravet

Inventor： Christophe Michot ,  Michel Armand ,  Michel Gauthier ,  Nathalie Ravet

IPC: H01M10/36 ,  H01M10/40 ,  C01B25/00 ,  C07F9/02 ,  C07C23/00

CPC classification number: C07C211/63 ,  C07C45/46 ,  C07C45/72 ,  C07C211/64 ,  C07C317/04 ,  C07C317/12 ,  C07C381/00 ,  C07D213/20 ,  C07D213/74 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08 ,  C07D311/82 ,  C07D339/06 ,  C07F9/54 ,  H01G9/038 ,  H01G9/20 ,  H01G9/2004 ,  H01G11/62 ,  H01M4/13 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M4/5825 ,  H01M4/587 ,  H01M4/60 ,  H01M4/602 ,  H01M4/624 ,  H01M6/164 ,  H01M6/166 ,  H01M6/168 ,  H01M6/181 ,  H01M8/1048 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0566 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/36 ,  H01M2300/0022 ,  H01M2300/0082 ,  Y02E10/542 ,  Y02E60/122 ,  Y02E60/13

Abstract: The invention concerns novel ionic compounds with low melting point whereof the onium type cation having at least a heteroatom such as N, O, S or P bearing the positive charge and whereof the anion includes, wholly or partially, at least an ion imidide such as (FX1O)N−(OX2F) wherein X1 and X2 are identical or different and comprise SO or PF, and their use as solvent in electrochemical devices. Said composition comprises a salt wherein the anionic charge is delocalised, and can be used, inter alia, as electrolyte.

Abstract translation: 本发明涉及具有低熔点的新型离子化合物，其中具有至少具有正电荷的N，O，S或P的杂原子的鎓型阳离子及其阴离子全部或部分至少包含一个离子酰亚胺，例如 （FX 1 O）N - （OX 2 F）其中X 1和X 2， / SUP>相同或不同，包含SO或PF，以及它们在电化学装置中作为溶剂的用途。 所述组合物包含盐，其中阴离子电荷是离域的，并且可以特别地用作电解质。

公开(公告)号：US20080102369A1

公开(公告)日：2008-05-01

申请号：US11976566

申请日：2007-10-25

Applicant: Hideo Sakata ,  Fusaji Kita ,  Kumiko Ishizuka

Inventor： Hideo Sakata ,  Fusaji Kita ,  Kumiko Ishizuka

IPC: H01M10/02 ,  H01M4/48

CPC classification number: H01M4/505 ,  H01M4/13 ,  H01M4/131 ,  H01M4/133 ,  H01M4/364 ,  H01M4/485 ,  H01M4/525 ,  H01M4/587 ,  H01M4/60 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  H01M10/4235 ,  H01M2004/021 ,  Y02E60/122 ,  Y02T10/7011

Abstract: A nonaqueous secondary battery having a positive electrode having a positive electrode mixture layer, a negative electrode, and a nonaqueous electrolyte, in which the positive electrode contains, as an active material, a lithium-containing transition metal oxide containing a metal element selected from the group consisting of Mg, Ti, Zr, Ge, Nb, Al and Sn, the positive electrode mixture layer has a density of 3.5 g/cm3 or larger, and the nonaqueous electrolyte contains a compound having two or more nitrile groups in the molecule

Abstract translation: 一种具有正极的非水系二次电池，其具有正极合剂层，负极和非水电解质，其中正极含有含有金属元素的含锂过渡金属氧化物作为活性物质，所述含锂过渡金属氧化物含有选自 由Mg，Ti，Zr，Ge，Nb，Al和Sn组成的正极合剂层的密度为3.5g / cm 3以上，非水电解液含有具有2个 或更多的腈基

公开(公告)号：US07318981B2

公开(公告)日：2008-01-15

申请号：US10519933

申请日：2004-03-01

Applicant: Shigeyuki Iwasa ,  Hiroyuki Nishide

Inventor： Shigeyuki Iwasa ,  Hiroyuki Nishide

IPC: H01M4/60

CPC classification number: H01M4/60 ,  H01M4/137 ,  H01M4/602 ,  H01M10/052 ,  H01M2004/028

Abstract: A secondary battery, that has an excellent charge and discharge cycle characteristics, with a larger capacity, is provided. The secondary battery having a positive electrode, negative electrode and electrolyte, includes a polymer having a repeating unit represented by a formula (1) as an active material of at least one of positive electrode and negative electrode. According to formula (1), R1, R2, R3 and R4 each independently represents hydrogen atom, substituted or unsubstituted alkyl group, substituted or unsubstituted aromatic hydrocarbons, substituted or unsubstituted hetroaromatic groups, halogen atom, or alkylene group that may be coupled to the ring form either one or both of R1 and R3, R2 and R4.

Abstract translation: 提供具有较大容量的具有优异的充放电循环特性的二次电池。 具有正极，负极和电解质的二次电池包括具有由式（1）表示的重复单元作为正极和负极中的至少一种的活性材料的聚合物。 根据式（1），R 1，R 2，R 3和R 4各自独立地表示氢原子，取代或未取代的烷基，取代或未取代的芳族烃，取代或未取代的杂芳族基团，卤素原子或可与 环形成R 1和R 3，R 2和R 4中的一个或两个。

公开(公告)号：US20070281210A1

公开(公告)日：2007-12-06

申请号：US11806982

申请日：2007-06-05

Applicant: Vladimir Kolosnitsyn ,  Elena Karaseva

Inventor： Vladimir Kolosnitsyn ,  Elena Karaseva

IPC: H01M4/58 ,  H01M4/60 ,  H01M4/40 ,  H01M4/62

CPC classification number: H01M4/58 ,  H01M4/136 ,  H01M4/40 ,  H01M4/60 ,  H01M4/621 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569

Abstract: A rechargeable cell for operation at temperatures above from −40° C. to +120° C. which has a positive electrode comprising sulfur and/or organic and/or non-organic compounds (including polymer compounds) of sulfur as an electrode active material, and a negative electrode made of metal lithium or lithium alloys, and an electrolyte comprising a solution of one or more salts in one or more solvents.

Abstract translation: 一种用于在高于-40℃至+ 120℃的温度下操作的可再充电电池，其具有包含硫和/或硫作为电极活性材料的硫和/或有机和/或非有机化合物（包括聚合物化合物）的正极 以及由金属锂或锂合金制成的负极以及包含在一种或多种溶剂中的一种或多种盐的溶液的电解质。

公开(公告)号：US07270797B2

公开(公告)日：2007-09-18

申请号：US11128198

申请日：2005-05-13

Applicant: Manabu Suhara ,  Naoshi Saito ,  Kazushige Horichi ,  Koji Tatsumi

Inventor： Manabu Suhara ,  Naoshi Saito ,  Kazushige Horichi ,  Koji Tatsumi

IPC: C01D1/02 ,  C01B13/14 ,  H01M4/58

CPC classification number: H01M4/0471 ,  C01G51/42 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2004/50 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/02 ,  H01M4/364 ,  H01M4/525 ,  H01M4/582 ,  H01M4/60 ,  H01M4/62 ,  H01M6/164 ,  H01M10/052 ,  H01M2004/021 ,  H01M2004/028

Abstract: To provide a process for producing a lithium-cobalt composite oxide for a positive electrode of a lithium secondary battery excellent in volume capacity density, safety, charge and discharge cyclic durability, press density and productivity, by using in expensive cobalt hydroxide and lithium carbonate. A mixture having a cobalt hydroxide powder and a lithium carbonate powder mixed so that the atomic ratio of lithium/cobalt would be from 0.98 to 1.01, is fired in an oxygen-containing atmosphere at from 250 to 700° C., and the fired product is further fired in an oxygen-containing atmosphere at from 850 to 1,050° C., or such a mixture is heated at a temperature-raising rate of at most 4° C./min in a range from 250 to 600° C. and fired in an oxygen-containing atmosphere at from 850 to 1,050° C.

Abstract translation: 为了提供一种生产锂二次电池用正极中的锂钴复合氧化物的方法，该锂二次电池的正极通过在昂贵的氢氧化钴和碳酸锂中的使用而具有优异的体积容量密度，安全性，充放电循环耐久性，压力密度和生产率。 将混合物以氢氧化钴粉末和碳酸锂粉末混合，使得锂/钴的原子比为0.98〜1.01，在250〜700℃的含氧气氛中烧成，烧成品 在850〜1050℃的含氧气氛中进一步烧成，或将这种混合物以250℃〜600℃的升温速度加热至4℃/分钟以上， 在含氧气氛中在850〜1050℃下烧成。

公开(公告)号：US20070172731A1

公开(公告)日：2007-07-26

申请号：US11624579

申请日：2007-01-18

Applicant: Tomoki NOBUTA ,  Takashi MIZUKOSHI ,  Naoki TAKAHASHI ,  Tetsuya YOSHINARI ,  Toshihiko NISHIYAMA

Inventor： Tomoki NOBUTA ,  Takashi MIZUKOSHI ,  Naoki TAKAHASHI ,  Tetsuya YOSHINARI ,  Toshihiko NISHIYAMA

IPC: H01M4/60 ,  H01M6/04

CPC classification number: H01M4/60 ,  H01G9/155 ,  H01G11/48 ,  H01M4/606 ,  H01M6/04 ,  H01M10/36 ,  H01M2300/0011 ,  Y02E60/13

Abstract: An objective of this invention is to provide a proton-conducting polymer battery comprising an electrode containing a proton-conducting conductive compound as an active material and an aqueous electrolytic solution, which exhibits good battery properties and higher safety and higher reliability after reflow processing. There is provided a proton-conducting polymer battery in which protons are exclusively involved in charge/discharge, comprising a cathode, an anode, a separator and an electrolytic solution; wherein: the cathode and the anode are disposed facing each other via the separator in the electrolytic solution; electrode active materials in the cathode and/or the anode are selected from π-conjugated polymers and hydroxyl-containing polymers; and the electrolytic solution is an aqueous solution comprising sulfuric acid as an electrolyte and at least one of phosphoric acid and diphosphoric acid, wherein the concentration of the contained water is 65 wt % or less, and the concentration of the sulfuric acid is 3 wt % to 35 wt %.

Abstract translation: 本发明的目的是提供一种质子传导性聚合物电池，其包含含有质子传导性导电化合物作为活性物质的电极和电解质水溶液，其在回流处理后表现出良好的电池性能和更高的安全性和更高的可靠性。 提供质子传导聚合物电池，其中质子仅涉及充电/放电，包括阴极，阳极，隔膜和电解液; 其中：所述阴极和所述阳极经由所述电解液中的隔膜彼此相对配置; 阴极和/或阳极中的电极活性材料选自π共轭聚合物和含羟基聚合物; 所述电解液是含有作为电解质的硫酸和磷酸和二磷酸中的至少一种的水溶液，其中所含水的浓度为65重量％以下，硫酸的浓度为3重量％ 至35重量％。

公开(公告)号：US07226695B2

公开(公告)日：2007-06-05

申请号：US10479486

申请日：2002-06-11

Applicant: Masataka Takeuchi ,  Hiroshi Yasuda ,  Junko Mizuguchi

Inventor： Masataka Takeuchi ,  Hiroshi Yasuda ,  Junko Mizuguchi

IPC: H01M4/02

CPC classification number: H01M4/137 ,  C08G61/122 ,  C08G73/0694 ,  H01G11/56 ,  H01M4/60 ,  H01M4/606 ,  H01M4/608 ,  H01M4/625 ,  H01M10/36 ,  H01M2300/0011 ,  H01M2300/0065 ,  H01M2300/0082 ,  Y02E60/13

Abstract: The present invention relates to a method for producing a polymer/conductive carbon composite electrode comprising dehydration condensation polymerization of a tetramine derivative and a tetracarbonyl compound in the presence of an electrically conductive carbon material. The synthetized polymer comprises quinoxaline structural units such as polyphenyl quinoxaline (PPQ) and serves as an active material having proton conductivity. The composite material for electrode obtained by the method has a large capacity of inserting/releasing a proton and excellent in durability. An electrode comprising the composite material and a secondary battery comprising the electrode is excellent in safety and reliability high-speed current characteristics, has a longer life and a larger gravimetric energy density (Wh/kg).

Abstract translation: 本发明涉及一种聚合物/导电性碳复合电极的制造方法，其特征在于，在导电性碳材料的存在下，包括四胺衍生物和四羰基化合物的脱水缩聚。 合成的聚合物包括喹喔啉结构单元如聚苯基喹喔啉（PPQ），并且用作具有质子传导性的活性材料。 通过该方法获得的电极用复合材料具有大的插入/释放质子的能力，并且耐久性优异。 包含复合材料的电极和包含电极的二次电池具有优异的安全性和可靠性的高速电流特性，具有更长的寿命和更大的重量能量密度（Wh / kg）。