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    Catalyst for vinyl compounds and process for production of vinyl polymers
    92.
    发明申请
    Catalyst for vinyl compounds and process for production of vinyl polymers 失效
    乙烯基化合物的催化剂和乙烯基聚合物的生产方法

    公开(公告)号：US20030027716A1

    公开(公告)日：2003-02-06

    申请号：US10204262

    申请日：2002-08-20

    Inventor： Haruhito Sato ,  Masami Watanabe ,  Masahiko Kuramoto

    IPC: B01J031/00 ,  C08F004/44

    CPC classification number: C07C2/32 ,  C07C2/04 ,  C07C2521/16 ,  C07C2531/14 ,  C07C2531/16 ,  C08F10/00 ,  Y10S526/943 ,  C08F4/7042 ,  C08F4/7006

    Abstract: The catalyst for polymerizing vinyl compounds according to the present invention comprises (A) a complex of Group 4 to 10 transition metal of the Periodic Table, (B) a clay, clay mineral or ion-exchangeable layered compound, and (C) at least one aluminoxy compound represented by Formula (1): 1 wherein a plurality of R groups are each independently C1-10 hydrocarbon group and at least one of the R groups is a hydrocarbon group having 2 or more carbon atoms; and x is an integer of 2 or more. By using the Group 4 to 10 transition metal complex and the clay, clay mineral or ion-exchangeable layered compound in combination with the specific aluminoxy compound, vinyl polymers are produced at a high efficiency. Also, the catalyst for producing null-olefins according to the present invention comprises (Anull) a complex of Group 8 to 10 transition metal of the Periodic Table, (Bnull) an organic compound-modified clay, clay mineral or ion-exchangeable layered compound, and (Cnull) at least one aluminoxy compound represented by Formula (2): 2 wherein a plurality of R groups are each independently C1-10 hydrocarbon group and at least one of the R groups is a hydrocarbon group having 2 or more carbon atoms; and y is an integer of 2 to 4. Since the organic compound-modified clay, clay mineral or ion-exchangeable layered compound absorbs other catalyst components between layers thereof, the elution of the catalyst components into liquid phase is effectively prevented, thereby facilitating the separation of the catalyst from a reaction product.

    Abstract translation: 根据本发明的用于聚合乙烯基化合物的催化剂包含（A）元素周期表第4至10族过渡金属的络合物，（B）粘土，粘土矿物或可离子交换层状化合物，和（C）至少 一种由式（1）表示的铝氧化合物：其中多个R基团各自独立地为C 1-10烃基，并且至少一个R基团为具有2个或更多个碳原子的烃基; x为2以上的整数。 通过使用4至10族过渡金属络合物和粘土，粘土矿物或可离子交换的层状化合物与特定的铝氧化合物的组合，以高效率生产乙烯基聚合物。 此外，根据本发明的用于制备α-烯烃的催化剂包含（A'）元素周期表第8-10族过渡金属的络合物，（B'）有机化合物改性的粘土，粘土矿物或可离子交换的 层状化合物和（C'）至少一种由式（2）表示的铝氧化合物：其中多个R基团各自独立地为C1-10烃基，并且至少一个R基团为具有2个或更多个的烃基 碳原子 y为2〜4的整数。由于有机化合物改性粘土，粘土矿物或离子交换性层状化合物在其层之间吸收其他催化剂成分，因此有效地防止了催化剂成分向液相的溶出， 催化剂与反应产物的分离。

    Hydrogen response Ziegler-Natta catalyst for narrowing MWD of polyolefin, method of making, method of using, and polyolefins made therewith
    93.
    发明申请
    Hydrogen response Ziegler-Natta catalyst for narrowing MWD of polyolefin, method of making, method of using, and polyolefins made therewith 审中-公开
    用于使聚烯烃的MWD变窄的齐格勒 - 纳塔催化剂，制造方法，使用方法和由此制成的聚烯烃

    公开(公告)号：US20030018143A1

    公开(公告)日：2003-01-23

    申请号：US10210834

    申请日：2002-08-01

    Inventor： Steven D. Gray ,  Tim J. Coffy

    IPC: C08F004/44 ,  B01J031/00

    CPC classification number: C08F10/00 ,  C08F4/6567 ,  C08F4/6557

    Abstract: A Ziegler-Natta type catalyst having an improved hydrogen response provides for narrowing of the MWD of resulting polyolefins polymerized using such catalyst, with such catalyst generally made by a) contacting a soluble magnesium dialkoxide compound of the general formula Mg(ORnull)2 with a halogenating agent capable of exchanging one halogen for one alkoxide to form a reaction product A, where Rnull is a hydrocarbyl or substituted hydrocarbyl having from 1 to 20 carbon atoms; b) contacting reaction product A with a first halogenating/titanating agent to form reaction product B; and c) contacting reaction product B with a second halogenating/titanating agent to form a catalyst component; wherein in at least one of steps b) and c), the halogenating/titanating agent is a blend of Ti(OPr)4 and TiCl4. Catalyst components, catalysts, catalyst sytems, polyolefin polymers, and methods of forming each are disclosed.

    Abstract translation: 具有改善的氢响应的齐格勒 - 纳塔型催化剂使得使用这种催化剂聚合的所得聚烯烃的MWD变窄，这种催化剂通常通过以下步骤制备：a）使通式Mg（OR'）2的可溶性二烷氧基镁化合物与 能够将一个卤素换成一个醇盐形成反应产物A的卤化剂，其中R'是具有1至20个碳原子的烃基或取代的烃基; b）使反应产物A与第一卤化/钛化剂接触以形成反应产物B; 和c）使反应产物B与第二卤化/钛化剂接触以形成催化剂组分; 其中在步骤b）和c）中的至少一个中，卤化/钛化剂是Ti（OPr）4和TiCl 4的共混物。 公开了催化剂组分，催化剂，催化剂体系，聚烯烃聚合物和形成方法。

    CATALYST SYSTEM AND ITS USE IN A POLYMERIZATION PROCESS
    94.
    发明申请
    CATALYST SYSTEM AND ITS USE IN A POLYMERIZATION PROCESS 有权
    催化剂体系及其在聚合过程中的应用

    公开(公告)号：US20030008985A1

    公开(公告)日：2003-01-09

    申请号：US09882906

    申请日：2001-06-18

    Inventor： Matthew W. Holtcamp ,  Tan H. Pham

    IPC: C08F004/44 ,  B01J031/00

    CPC classification number: C08F10/00 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/16 ,  C08F4/603 ,  C08F4/61908 ,  C08F210/14

    Abstract: Disclosed are polymerization catalyst activator complexes prepared from the reaction of a carbenium salt and Lewis base containing an aromatic group. Also disclosed are polymerization catalyst activator complexes prepared via the reaction of a Group 13 element containing salt including a Lewis base containing an aromatic group and a tritylhalide compound. Also disclosed are polymerization catalyst systems including the activator complex of the invention, and processes for polymerizing olefin(s) utilizing same.

    Abstract translation: 公开了由碳鎓盐与含芳族基团的路易斯碱的反应制备的聚合催化剂活化剂配合物。 还公开了通过含有含有芳族基团的路易斯碱和三苯甲基卤化合物的含13族元素盐的反应制备的聚合催化剂活化剂配合物。 还公开了包括本发明的活化剂配合物的聚合催化剂体系，以及利用它们聚合烯烃的方法。

    Novel catalyst system and the use thereof
    95.
    发明申请
    Novel catalyst system and the use thereof 失效
    新型催化剂体系及其用途

    公开(公告)号：US20030008984A1

    公开(公告)日：2003-01-09

    申请号：US10168646

    申请日：2002-06-24

    Inventor： Roland Kratzer ,  Cornelia Fritze ,  Jorg Schottek

    IPC: C08F004/60 ,  B01J031/00

    CPC classification number: B01J31/1608 ,  B01J31/0237 ,  B01J31/14 ,  B01J31/1616 ,  B01J31/2295 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/00 ,  C08F4/65916

    Abstract: The invention relates to a catalyst system, containing at least one metallocene, at least one co-catalyst, at least one supporting material and optionally additional organometallic compounds. The catalyst system can be used advantageously for polymerising olefins, as it obviates the use of aluminoxanes, such as methylaluminoxane (MAO), which is conventionally used in excess quantities as a co-catalyst, whilst at the same time producing strong catalyst activity and excellent polymer morphology.

    Abstract translation: 本发明涉及一种含有至少一种茂金属，至少一种助催化剂，至少一种载体材料和任选的其它有机金属化合物的催化剂体系。 催化剂体系可以有利地用于聚合烯烃，因为它消除了铝氧烷的使用，例如甲基铝氧烷（MAO），其通常以过量的量作为助催化剂使用，同时产生强的催化剂活性和优异的 聚合物形态。

    Method and catalyst system for producing aromatic carbonates
    97.
    发明申请
    Method and catalyst system for producing aromatic carbonates 有权

    公开(公告)号：US20030004053A1

    公开(公告)日：2003-01-02

    申请号：US10191019

    申请日：2002-07-08

    Inventor： Grigorii Lev Soloveichik ,  Kirill Vladimirovich Shalyaev ,  Marsha Mottel Grade ,  Bruce Fletcher Johnson

    IPC: B01J031/00

    CPC classification number: B01J23/8926 ,  C07C68/005 ,  C07C69/96

    Abstract: A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes an effective amount of a Group VIII B metal source; an effective amount of a bromide composition; an effective amount of an activating organic solvent; an effective amount of a combination of inorganic co-catalysts comprising a lead source and a copper source; and an effective amount of a base.

    Supported olefin polymerization catalysts
    98.
    发明申请
    Supported olefin polymerization catalysts 失效
    负载型烯烃聚合催化剂

    公开(公告)号：US20020187892A1

    公开(公告)日：2002-12-12

    申请号：US10108938

    申请日：2002-03-27

    Inventor： Peter Preishuber-Pfluegl

    IPC: B01J031/00

    CPC classification number: C08F110/02 ,  C08F10/00 ,  C08F4/025 ,  C08F4/7006 ,  C08F4/7042

    Abstract: A method for forming supported late transition metal olefin polymerization catalysts is described in which an already formed transition metal complex, usually containing a reactive functional group, is placed on a support containing a complementary reactive functional group. Also described are novel polymerization catalyst components containing late transition metal complexes of neutral tridentate ligands.

    Abstract translation: 描述了形成负载型后过渡金属烯烃聚合催化剂的方法，其中已经形成的通常含有反应性官能团的过渡金属络合物放置在含有互补反应性官能团的载体上。 还描述了含有中性三齿配体的后过渡金属络合物的新型聚合催化剂组分。

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