公开(公告)号：US20040089587A1

公开(公告)日：2004-05-13

申请号：US10632535

申请日：2003-08-01

发明人： Avelino Corma Canos ,  Teresa Navarro Villalba ,  Susana Valencia Valencia ,  Fernando Rey Garcia

IPC分类号： C10G047/02 ,  C10G011/05 ,  C07C005/23 ,  C07C005/27 ,  C07C002/58 ,  C07C002/66 ,  C01B039/48

CPC分类号： C10G11/05 ,  B01J29/04 ,  C01B37/005 ,  C01B39/023 ,  C01B39/08 ,  C10G47/16 ,  Y10S423/27

摘要： The invention relates to a method for synthesizing a family of zeolite materials, grouped together under the name ITQ-16, in an OHnull medium and in the absence of fluorides and to the catalytic applications thereof. The zeolite ITQ-16 family of materials is characterized by having different proportions of distinct polymorphs A, B and C described as possible intergrowths in the Beta zeolite and, therefore, the X-ray diffraction patterns of said family are different from that described for the Beta zeolite. In its calcinated form, zeolite ITQ-16 has the following empirical formula: x(MXO2):tTO2:gGeO2:(1nullg)SiO2, wherein T is one or more elements having null4 oxidation status and different from Ge and Si; X is one or more elements having null3 oxidation status; and M can be Hnull or one or more inorganic cations with a nulln charge.

摘要翻译： 本发明涉及一种用于合成沸石材料族的方法，该组合物以名称ITQ-16在OH-介质中并且在不存在氟化物的情况下分组在一起，并用于催化应用。 沸石ITQ-16系列材料的特征在于具有不同比例的不同的多晶型物A，B和C作为β沸石中可能的共生生长而被描述，因此，所述族的X射线衍射图不同于对于 β沸石。 沸石ITQ-16具有以下经验公式：x（MXO2）：tTO2：gGeO2：（1-g）SiO2，其中T是具有+4氧化态且不同于Ge和Si的一种或多种元素; X是具有+3氧化状态的一种或多种元素; 并且M可以是H +或一个或多个具有+ n电荷的无机阳离子。

公开(公告)号：US20030092949A1

公开(公告)日：2003-05-15

申请号：US10319161

申请日：2002-12-13

发明人： Ajit B. Dandekar ,  Michael Hryniszak ,  David Lawrence Stern

IPC分类号： C07C015/00 ,  C07C002/66

CPC分类号： C07C15/085 ,  C07C2/66 ,  C07C6/126 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/70 ,  Y02P20/52

摘要： A process for producing cumene is provided which comprises the step of contacting benzene and propylene under at least partial liquid phase alkylating conditions with a particulate molecular sieve alkylation catalyst, wherein the particles of said alkylation catalyst have a surface to volume ratio of about 80 to less than 200 inchnull1.

公开(公告)号：US20010020118A1

公开(公告)日：2001-09-06

申请号：US09817399

申请日：2001-03-26

申请人： Sud-Chemie, Inc. (formerly United Catalysts, Inc.)

发明人： David L. Williams ,  Yuji Mishima ,  Andrzej Rokicki

IPC分类号： C07C002/66 ,  C07C002/72

CPC分类号： C07C5/325 ,  B01J23/894 ,  B01J23/8946 ,  B01J23/8993 ,  C07C5/3337 ,  C07C2521/06 ,  C07C2523/10 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/89 ,  C07C2527/232 ,  C07C15/40 ,  C07C15/46

摘要： A catalyst for the production of alkenylaromatics from alkylaromatics, wherein the catalyst is predominantly iron oxide, an alkali metal compound and a small amount of a source for palladium or platinum. Additional components of the catalyst may include compounds based on cerium, molybdenum, tungsten and other such promoters. Also a process for the production of alkenylaromatics from alkylaromatics using this catalyst.

摘要翻译： 用于从烷基芳族化合物生产链烯基芳族化合物的催化剂，其中催化剂主要是氧化铁，碱金属化合物和少量钯或铂的来源。 催化剂的另外的组分可以包括基于铈，钼，钨和其它这样的促进剂的化合物。 也是使用该催化剂从烷基芳族化合物生产链烯基芳烃的方法。

公开(公告)号：US20030166984A1

公开(公告)日：2003-09-04

申请号：US10376322

申请日：2003-03-03

申请人： KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY

发明人： Sang-Eon Park ,  Jong-San Chang ,  Min Seok Park

IPC分类号： C07C002/64 ,  C07C002/66

CPC分类号： C07C5/3332 ,  C07C2523/22 ,  C07C2523/26 ,  C07C2523/745 ,  C07C15/46 ,  C07C15/44

摘要： The present invention relates to a method for catalytic dehydrogenation of alkylaromatic hydrocarbons and more particularly, to a method for catalytic dehydrogenation of alkylaromatic hydrocarbons using carbon dioxide as a soft oxidant in the presence of a heterogeneous catalyst comprising both vanadium and iron, which allows operation at a lower reaction temperature due to improved thermodynamic equilibrium and provides an enhanced conversion of hydrocarbons and energy saving.

摘要翻译： 本发明涉及一种烷基芳族烃的催化脱氢方法，更具体地说，涉及一种在包含钒和铁的多相催化剂存在下使用二氧化碳作为软氧化剂催化脱氢烷基芳烃的方法，其允许在 由于改善了热力学平衡，反应温度较低，提供了碳氢化合物的转化和节能。

公开(公告)号：US20030149320A1

公开(公告)日：2003-08-07

申请号：US10287873

申请日：2002-11-04

发明人： Gregory J. Gajda ,  James F. McGehee

IPC分类号： C07C002/66

CPC分类号： C07C15/073 ,  C07C2/66 ,  C07C6/126 ,  C07C2529/70

摘要： A process for the alkylation of aromatics with olefins using a solid catalyst is disclosed, wherein the olefin ratio and/or the maximum olefin concentration in the alkylation catalyst bed is maintained less than an upper limit. Such operation can decrease the catalyst deactivation rate and the formation of diphenylalkanes. This invention is applicable to processes for the production of a wide variety of commercially important alkylated aromatics, including ethylbenzene and cumene.

摘要翻译： 公开了使用固体催化剂用烯烃烷基化芳族化合物的方法，其中烷基化催化剂床中的烯烃比率和/或最大烯烃浓度保持小于上限。 这种操作可以降低催化剂失活速率和二苯基烷烃的形成。 本发明适用于生产各种商业上重要的烷基化芳族化合物的方法，包括乙苯和枯烯。

公开(公告)号：US20030127360A1

公开(公告)日：2003-07-10

申请号：US10315353

申请日：2002-12-10

发明人： Jannetje Maatje van den Berge ,  Gary David Mohr

IPC分类号： B01J029/06 ,  C10G011/02 ,  C07C005/22 ,  C10G035/06 ,  C07C004/02 ,  C07C001/20 ,  C07C002/66 ,  C10G047/02

CPC分类号： C01B39/026 ,  B01J29/40 ,  B01J37/0009 ,  B01J2229/42 ,  Y10S423/22

摘要： This invention relates to a process for producing zeolite-bound high silica zeolites and the use of the zeolite-bound high silica zeolite produced by the process for hydrocarbon conversion. The process is carried out by forming an extrudable paste comprising a mixture of high silica zeolite in the hydrogen form, water, silica, and optionally an extrusion aid, extruding the extrudable paste to form silica-bound high silica zeolite extrudates, and then converting the silica of the binder to a zeolite binder. The zeolite-bound high silica zeolite produced by the process comprises high silica zeolite crystals that are bound together by zeolite binder crystals. The zeolite-bound high silica zeolite finds particular application in hydrocarbon conversion processes, e.g., catalytic cracking, alkylation, disproportionation of toluene, isomerization, and transalkylation reactions.

公开(公告)号：US20030125592A1

公开(公告)日：2003-07-03

申请号：US10318882

申请日：2002-12-13

发明人： Ajit B. Dandekar ,  Thomas Francis Degnan ,  John P. McWilliams ,  Chaya R. Venkat

IPC分类号： C07C002/66

CPC分类号： C07C2/66 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/50 ,  C07C2529/65 ,  C07C2529/70 ,  Y02P20/584 ,  C07C15/073

摘要： 1. A process for alkylating aromatics comprises: i) contacting a feed containing alkylatable aromatic, e.g., benzene, under liquid phase alkylating conditions with an alkylating agent, e.g., ethylene, in the presence of an alkylation catalyst comprising a porous crystalline material, e.g., MCM-22, to provide an alkylated aromatic product during which contacting said catalyst becomes at least partially deactivated by sorbing catalyst poisons present in said feed; ii) treating said at least partially deactivated catalyst in situ by contacting with at least one polar compound, e.g., water or acetic acid, having a dipole moment of at least 0.05 Debyes under conditions of temperature and pressure employed in said liquid phase alkylating conditions which are sufficient to at least partially desorb said catalyst poison from said catalyst; and iii) collecting said alkylated aromatic product.

摘要翻译： 1.芳族化合物烷基化方法包括：i）在液相烷基化条件下，在包含多孔结晶材料的烷基化催化剂的存在下，使烷基化芳族化合物（例如苯）与烷基化试剂例如乙烯接触，例如 MCM-22，以提供烷基化芳族产物，在此期间，通过吸附所述进料中存在的催化剂毒物使所述催化剂接触至少部分失活; ii）在所述液相烷基化条件下使用的温度和压力条件下，通过与至少一种极性化合物（例如水或乙酸）接触，处理所述至少部分失活的催化剂，所述极性化合物例如水或乙酸具有至少0.05Debyes的偶极矩， 足以使所述催化剂毒物至少部分地解吸所述催化剂毒物; 和iii）收集所述烷基化芳族产物。

公开(公告)号：US20040167368A1

公开(公告)日：2004-08-26

申请号：US10789115

申请日：2004-02-27

发明人： Laurent Alain Michel Fenouil ,  Brendan Dermot Murray ,  Paul Marie Ayoub

IPC分类号： C07C002/66 ,  C07C004/00 ,  C07C005/32

CPC分类号： C10G45/00 ,  C10G65/043 ,  C10G69/123 ,  C10G2300/1085 ,  C10G2300/1096 ,  C10G2400/22 ,  C10G2400/30

摘要： A process for preparing branched alkyl aromatic hydrocarbons, which process comprises contacting branched olefins with an aromatic hydrocarbon under alkylating conditions, which branched olefins have been obtained by a process which comprises dehydrogenating an isoparaffinic composition over a suitable catalyst which isoparaffinic composition has been obtained by hydrocracking and hydroisomerization of a paraffinic wax and which isoparaffinic composition comprises paraffins having a carbon number in the range of from 7 to 35, of which paraffins at least a portion of the molecules is branched, the average number of branches per paraffin molecule being at least 0.5 and the branching comprising methyl and optionally ethyl branches; a process for preparing (branched-alkyl)arylsulfonates, comprising sulfonating branched alkyl aromatic hydrocarbons which branched alkyl aromatic hydrocarbons have been prepared by the said process for preparing branched alkyl aromatic hydrocarbons; and branched alkyl aromatic hydrocarbon compositions and (branched-alkyl)arylsulfonate compositions which are obtainable by the processes so defined.

摘要翻译： 一种制备支链烷基芳烃的方法，该方法包括在烷基化条件下使支链烯烃与芳族烃接触，该支链烯烃已经通过包括使异链烷烃组合物在合适的催化剂上脱氢的方法获得，该催化剂已经通过加氢裂化获得了异链烷烃组合物 和链烷烃蜡的加氢异构化，并且所述异链烷烃组合物包含碳数为7至35的链烷烃，其中至少部分分子的链烷烃是支链的，每个链烷烃分子的平均支链数为至少0.5 并且支链包含甲基和任选的乙基支链; 一种制备（支链 - 烷基）芳基磺酸盐的方法，包括磺化支化烷基芳烃，其中支链烷基芳烃是通过所述制备支链烷基芳烃的方法制备的; 和支链烷基芳烃组合物和（支链 - 烷基）芳基磺酸盐组合物，其可通过如此定义的方法获得。

公开(公告)号：US20030176750A1

公开(公告)日：2003-09-18

申请号：US10024537

申请日：2001-12-21

发明人： Chitta Ranjan Patra ,  Rajiv Kumar

IPC分类号： C07C002/66

CPC分类号： C07C2/66 ,  C07C2529/08 ,  C07C2529/70 ,  C07C15/02

摘要： The present invention relates to a process for the preparation of dimethylcumenes comprising alkylating a substrate comprising of one or more xylene isomers with an alkylating agent in the presence of a solid acid zeolite catalyst selected from ultrastable zeolite Y (Si/Alnull5 to 50) and Beta (Si/Alnull10-120), and separating the products formed in vapour phase.

摘要翻译： 本发明涉及一种制备二甲基枯烯的方法，包括在选自超稳沸石Y（Si / Al = 5〜50）的固体酸沸石催化剂存在下，用烷基化剂将含有一种或多种二甲苯异构体的底物烷基化， 和β（Si / Al = 10-120），并分离蒸气形成的产物。

公开(公告)号：US20020198424A1

公开(公告)日：2002-12-26

申请号：US10193792

申请日：2002-07-12

发明人： James T. Merrill ,  James R. Butler

IPC分类号： C07C002/66

CPC分类号： B01J29/7007 ,  B01J2229/42 ,  C07C2/66 ,  C07C2521/08 ,  C07C2529/70 ,  Y02P20/544 ,  Y02P20/584 ,  C07C15/073

摘要： The alkylation of benzene-containing feedstock over a zeolite beta alkylation catalyst which is formulated with a silica binder and has an average regeneration coefficient of at least 95% for at least three regenerations. The alkylation reaction is carried out in the liquid phase or supercritical region with a C2-C4 alkylating agent, specifically ethylene. The catalyst exhibits a regeneration coefficient of at least 95% after ethylation of the benzene with ethylene at a benzene/ethylene mole ratio of less than 10. The ethylation of benzene occurs at an initial designated primary activity. The operation of the reaction zone is continued until the activity of the catalyst for the ethylation of benzene decreases by a value of at least 0. 1% and not more 1% from the initial designated primary activity. The operation of the reaction for alkylation is terminated and a regeneration procedure is instituted in which the catalyst is regenerated in an oxidizing environment at an average temperature of no more than 500null C. At the conclusion of the regeneration procedure, the operation of the alkylation zone is reinstituted with the reaction zone again operated under conditions as described above followed by regeneration.

摘要翻译： 在沸石β烷基化催化剂上的含苯原料的烷基化，其用二氧化硅粘合剂配制，并且对至少三次再生具有至少95％的平均再生系数。 烷基化反应在液相或超临界区域用C2-C4烷基化剂，特别是乙烯进行。 苯与乙烯在苯/乙烯摩尔比小于10的乙醚化后，催化剂表现出至少95％的再生系数。苯的乙基化发生在初始指定的主要活性。 反应区的操作继续进行，直到乙基化乙基化催化剂的活性从初始指定的主要活性降低至少0.1％而不是1％以上的值。 终止烷基化反应的操作，并且在不超过500℃的平均温度下在氧化环境中再生催化剂的再生方法。在再生过程结束时，烷基化操作 区域被重新配置，反应区域再次在如上所述的条件下操作，随后再生。