公开(公告)号：US20030037415A1

公开(公告)日：2003-02-27

申请号：US10188113

申请日：2002-07-03

申请人： DEGUSSA AG

发明人： Hans Christian Alt ,  Andreas Geisselmann ,  Natalia Hinrichs ,  Hermanus Gerhardus Jozef Lansink Rotgerink

IPC分类号： B01J035/08

CPC分类号： F27B15/00 ,  B01J2/16 ,  B01J8/388 ,  B01J19/26 ,  B01J21/06 ,  B01J21/063 ,  B01J21/08 ,  B01J37/0045 ,  B01J2208/00371 ,  C01B13/145 ,  C01B33/12 ,  C01F7/025 ,  C01P2004/50 ,  C01P2004/51 ,  C01P2004/61 ,  C09C1/3009 ,  C09C1/3036 ,  C09C1/3615 ,  C09C1/3638

摘要： A continuous process and apparatus for the production of at least approximately spherical, substantially solid particles, in which the particles are granulated in a circulating fluidized bed. This can be achieved by spraying a suspension or a solution of the solid which forms the particles into a chamber. A drying gas is passed through the chamber at a velocity which is sufficient to effect pneumatic conveying of already partially dried or agglomerated particles. The particles conveyed by the drying gas stream are separated from the exhaust gas stream and returned, at least in part, to the chamber. Particles with a size within the desired particle size range are continuously discharged from the chamber, such that the mass present in the chamber remains constant.

摘要翻译： 用于生产至少近似球形的基本上固体颗粒的连续方法和装置，其中颗粒在循环流化床中造粒。 这可以通过将形成颗粒的固体的悬浮液或溶液喷射到室中来实现。 干燥气体以足以实现已部分干燥或附聚颗粒的气动输送的速度通过室。 由干燥气流输送的颗粒与废气流分离并至少部分地返回到室中。 尺寸在所需粒度范围内的颗粒从腔室连续排出，使得存在于腔室中的质量保持恒定。

公开(公告)号：US20010011060A1

公开(公告)日：2001-08-02

申请号：US08878681

申请日：1997-06-19

发明人： MARIO SACCHETTI ,  ILLARO CUFFIANI ,  GIANNI PENNINI

IPC分类号： B01J035/08

CPC分类号： C08F10/00 ,  C08F4/6543

摘要： The present invention relates to spherical solid catalyst components for the polymerization of olefins, comprising a titanium compound, supported on a magnesium halide, containing more than one Ti-halogen link and optionally containing groups different from halogen in an amount lower than 0.5 mole per mole of Ti. Spherical solid compounds of the invention are characterized by having a surface area, measured by the BET method, of lower than 70 m2/g, a total porosity, measured by the mercurium method, higher than 0.5 cm3/g and a pore radius such that at least 50% have values higher than 800 null.

摘要翻译： 本发明涉及用于烯烃聚合的球形固体催化剂组分，其包含负载在卤化镁上的钛化合物，其含有多于一个的Ti-卤素连接并且任选地含有少于0.5摩尔/摩尔量的不同于卤素的基团 的Ti。 本发明的球形固体化合物的特征在于具有通过BET法测量的表面积低于70m 2 / g，通过汞法测量的总孔隙率高于0.5cm 3 / g，孔半径使得 至少有50％的值高于800？

公开(公告)号：US20040251569A1

公开(公告)日：2004-12-16

申请号：US10864593

申请日：2004-06-10

申请人： ASAHI GLASS COMPANY, LIMITED

发明人： Toshiya Matsubara ,  Masaharu Tanaka ,  Kenji Yamada ,  Hajime Katayama

IPC分类号： B01J035/08 ,  B29B009/00

CPC分类号： B01J2/08 ,  B01F3/0807 ,  B01F5/0475 ,  B01F13/0059 ,  B01F2215/0431 ,  B01F2215/045 ,  B01J13/046

摘要： A process for producing inorganic spheres, which comprises injecting an aqueous liquid containing an inorganic compound into a laminar flow of an organic liquid which runs at a flow rate of from 0.001 to 2 m/s in a flow path compartmentalized by a partition wall through a plurality of inlet holes formed in one partition wall to form a W/O type emulsion containing the organic liquid as a dispersion medium and the aqueous liquid containing the inorganic compound as a dispersed phase, and solidifying the aqueous liquid containing an inorganic compound in the W/O type emulsion, wherein the partition wall having a plurality of inlet holes is made of a metal sheet having a surface subjected to water repellent treatment.

摘要翻译： 一种无机球体的制造方法，其特征在于，将含有无机化合物的水性液体注入到通过分隔壁分隔的流路中以0.001〜2m / s的流量流过的有机液体的层流 多个入口孔形成在一个分隔壁中，以形成含有有机液体作为分散介质的W / O型乳液和含有无机化合物作为分散相的含水液体，并将含有无机化合物的水性液体固化在W / O型乳液，其中具有多个入口孔的分隔壁由具有防水处理表面的金属片制成。

公开(公告)号：US20010018401A1

公开(公告)日：2001-08-30

申请号：US09343832

申请日：1999-06-30

发明人： PATRICIA RAE BLUM ,  LARRY MICHAEL CIRJAK ,  MARC ANTHONY PEPERA ,  CHRISTOS PAPARIZOS ,  GEORGE FREDERICK SALEM ,  MICHAEL JAMES BAKER

IPC分类号： C07C027/12 ,  C07C027/14 ,  B01J035/08 ,  B01J021/08

CPC分类号： B01J37/0045 ,  B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

摘要： A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a metal salt of Pd and M, wherein M comprises Ba, Cd, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 105 microns.

摘要翻译： 一种制备流化床乙酸乙烯酯（VAM）催化剂的方法，包括将包含基本上惰性的微球形颗粒的混合物的载体浸渍到包含Pd和M的金属盐的溶液中，其中M包括Ba，Cd，Au，La， Nb，Ce，Zn，Pb，Ca，Sr，Sb或其混合物，还原金属盐以在载体表面上形成Pd和M的沉积物，并用至少一种碱金属盐浸渍载体。 用于微球支持体的至少50％的颗粒具有低于105微米的粒度。

公开(公告)号：US20040049091A1

公开(公告)日：2004-03-11

申请号：US10235279

申请日：2002-09-05

申请人： Fina Technology, Inc.

发明人： James R. Butler

IPC分类号： C07C002/64 ,  B01J035/08

CPC分类号： C07C5/3332 ,  B01J23/78 ,  C07C2523/745 ,  C07C15/46

摘要： Disclosed is a method for extending the life of dehydrogenation catalysts used to prepare vinyl aromatic hydrocarbons. The catalysts, which typically include both iron oxide and potassium containing catalysis promoter, are exposed to additional potassium delivered using a potassium carboxylate. The potassium carboxylates are desirably free of halogens and other catalysts poisons or groups that could result in the undesirable properties in vinyl aromatic hydrocarbons produced therewith. The present invention is particularly useful with the production of styrene and methyl styrene.

摘要翻译： 公开了延长用于制备乙烯基芳烃的脱氢催化剂的寿命的方法。 通常包括氧化铁和含有催化剂催化剂的催化剂暴露于使用羧酸钾递送的另外的钾。 羧酸钾不需要卤素和其它催化剂毒物或基团，这些毒素或基团可能导致在其中产生的乙烯基芳烃中的不良性质。 本发明特别适用于生产苯乙烯和甲基苯乙烯。

公开(公告)号：US20020173599A1

公开(公告)日：2002-11-21

申请号：US09735811

申请日：2000-12-13

发明人： Mark Gregory Goode ,  Clark Curtis Williams ,  Timothy Roger Lynn ,  Robert Converse Brady III ,  Jody Michael Moffett

IPC分类号： C08F002/34 ,  B01J035/08 ,  C08F002/00 ,  C08G085/00 ,  B01J031/00 ,  C08F004/44

CPC分类号： C08F10/00 ,  B01J8/004 ,  B01J8/1827 ,  B01J19/26 ,  B01J2208/00017 ,  B01J2208/00539 ,  B01J2208/00752 ,  C08F4/65912 ,  C08F4/6592 ,  C08F10/02 ,  C08F210/06 ,  C08F210/16 ,  Y10S526/901 ,  Y10S526/943 ,  C08F2/34 ,  C08F4/65927 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/15 ,  C08F210/14

摘要： The present invention teaches the use of particular soluble metallocene catalysts to produce stereoregular polymers in gas phase polymerizations wherein the catalysts are fed into a particle lean zone in the reactor. The metallocenes catalysts are bridged bis-(substituted indenyl) compounds.

摘要翻译： 本发明教导了使用特定的可溶性茂金属催化剂在气相聚合中产生立体规则聚合物，其中将催化剂进料到反应器中的贫灰区。 金属茂催化剂是桥连双（取代茚基）化合物。

公开(公告)号：US20020111262A1

公开(公告)日：2002-08-15

申请号：US09952761

申请日：2001-09-14

发明人： Joe D. Allison

IPC分类号： B01J035/08

CPC分类号： C10G2/33 ,  B01J35/08 ,  B01J37/0072 ,  B01J37/06

摘要： A method for producing small spherical particles that are especially useful as catalysts and catalyst supports employed in chemical processes is disclosed. According to some embodiments, the method includes impregnating a porous support with a metal or metal oxide and dissolving the support to release spherical particles. In certain embodiments the support that is employed in the method comprises a number of spherical voids which determine the size of the spherical particles, and preferably have micrometer range diameters. One embodiment of an attrition resistant Fischer-Tropsch catalyst comprises a plurality of micrometer size spherical metal and/or metal oxide particles that are prepared according to the above-described method.

摘要翻译： 公开了一种用于生产特别用作化学方法中使用的催化剂和催化剂载体的小球形颗粒的方法。 根据一些实施方案，该方法包括用金属或金属氧化物浸渍多孔载体并溶解载体以释放球形颗粒。 在某些实施方案中，该方法中使用的载体包括多个球形空隙，其确定球形颗粒的尺寸，并且优选具有微米范围直径。 耐磨耗费 - 托催化剂的一个实施方案包括根据上述方法制备的多个微米尺寸的球形金属和/或金属氧化物颗粒。

公开(公告)号：US20010012816A1

公开(公告)日：2001-08-09

申请号：US09828920

申请日：2001-04-10

发明人： Toshio Yamaguchi ,  Kikoo Uekusa

IPC分类号： B01J035/08 ,  B01J021/02

CPC分类号： B01J21/04 ,  B01J35/08 ,  B01J37/0072

摘要： The present invention provides a process for producing spherical catalyst carrier of silica, silica-alumina composition, zirconia-alumina composition, titania-alumina composition, boria-alumina composition, or boria-silica-alumina composition which has almost the same pore characteristics as alumina hydrate gel, silica-alumina hydrate gel, zirconia-alumina hydrate gel, or titania-alumina hydrate gel (or alumina hydrate paste, boria-alumina hydrate paste, or boria-silica-alumina hydrate paste) as the major raw material, has uniform sphericity and smooth surface and homogeneity, and has a macropore volume that can be controlled. The process comprises adding a polysaccharide solution to any of alumina, silica-alumina, zirconia-alumina, or titania-alumina in the form of hydrate gel, or alumina, boria-alumina, or boria-silica-alumina in the form of hydrate paste, mixing them to form a slurry with a controlled concentration, dropping the slurry into a solution containing multivalent metal ions, thereby forming spherical hydrogel, and performing the additional steps of aging, washing, drying, and calcining.

摘要翻译： 本发明提供一种二氧化硅球形催化剂载体，氧化硅 - 氧化铝组合物，氧化锆 - 氧化铝组合物，二氧化钛 - 氧化铝组合物，氧化硼 - 氧化铝组合物或氧化硼 - 氧化铝 - 氧化铝组合物的制备方法，其具有与氧化铝几乎相同的孔隙特性 水合物凝胶，二氧化硅 - 水合氧化铝凝胶，氧化锆 - 水合氧化铝凝胶或二氧化钛 - 水合氧化铝凝胶（或氧化铝水合物糊，氧化硼 - 氧化铝水合物糊，或氧化硼 - 氧化铝 - 水合氧化铝浆）为主要原料，均匀 球形和光滑的表面和均匀性，并具有可以控制的大孔体积。 该方法包括将多糖溶液以水合物凝胶形式的氧化铝，二氧化硅 - 氧化铝，氧化锆 - 氧化铝或二氧化钛 - 氧化铝，或氧化铝，氧化硼 - 氧化铝，氧化硼 - 氧化铝 - 水合物糊状物 将其混合形成具有受控浓度的浆料，将浆料滴入含有多价金属离子的溶液中，从而形成球形水凝胶，并进行老化，洗涤，干燥和煅烧的附加步骤。