ULTRAVIOLET CURABLE SILICONE ADHESIVE COMPOSITION AND CURED PRODUCT OF SAME

    公开(公告)号:US20220017790A1

    公开(公告)日:2022-01-20

    申请号:US17299598

    申请日:2019-11-15

    IPC分类号: C09J7/38 C09J11/04

    摘要: An ultraviolet curable silicone adhesive composition which contains (A) an organopolysiloxane represented by formula (1) (wherein each R1 represents a polymerizable group or a monovalent hydrocarbon group having 1-20 carbon atoms, provided that at least one of the R1 moieties represents a polymerizable group; R2 represents an oxygen atom or an alkylene group having 1-20 carbon atoms; and m and n represent numbers satisfying m≥0, n≥1 and 1 (m+n)≥1,000), (B) an organopolysiloxane resin which is composed of (a) an R33SiO1/2 unit (wherein R3 represents a monovalent hydrocarbon group having 1-10 carbon atoms) and (b) an SiO4/2 unit, with the molar ratio of the unit (a) to the unit (b) being 0.6-1.2:1, (C) a fine silica powder and (D) a photopolymerization initiator, and which does not contain a (meth)acrylate compound that does not have a siloxane structure. This ultraviolet curable silicone adhesive composition enables the achievement of a cured product that has good shape retainability and little curing shrinkage, while exhibiting excellent adhesiveness if used as a provisional fixing material.

    ORGANOSILICON COMPOUND HAVING CYCLIC SILAZANE STRUCTURE, COMPOSITION CONTAINING THE SAME, AND METHOD FOR PRODUCING THE SAME

    公开(公告)号:US20220009949A1

    公开(公告)日:2022-01-13

    申请号:US17366963

    申请日:2021-07-02

    发明人: Takeshi NYUUGAKU

    IPC分类号: C07F7/10 C07F7/08

    摘要: To provide an organosilicon compound having a cyclic silazane structure, represented by the following general formula (1): wherein R1 represents a hydrogen atom, an oxy radical, a hydroxyl group, a substituted or unsubstituted alkoxy group having 1 to 10 carbon atoms, or a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms, R2 represents a substituted or unsubstituted alkylene group having 3 to 6 carbon atoms, R3 and R each independently represent a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms, and n represents an integer of 0 to 2.

    RESIST COMPOSITION AND PATTERNING PROCESS

    公开(公告)号:US20210405528A1

    公开(公告)日:2021-12-30

    申请号:US17342701

    申请日:2021-06-09

    发明人: Jun Hatakeyama

    摘要: A resist composition is provided comprising a base polymer and a quencher comprising a salt compound obtained from a nitrogen-containing compound having an iodine or bromine-substituted hydrocarbyl group (exclusive of iodine or bromine-substituted aromatic ring) bonded to the nitrogen atom via an ester bond-containing group and a compound having a 1,1,1,3,3,3-hexafluoro-2-propanol group. The resist composition has a high sensitivity and forms a pattern with improved LWR or CDU, independent of whether it is of positive or negative tone.

    PHOTOMASK BLANK, AND MANUFACTURING METHOD THEREOF

    公开(公告)号:US20210405520A1

    公开(公告)日:2021-12-30

    申请号:US17354180

    申请日:2021-06-22

    IPC分类号: G03F1/26

    摘要: In a photomask blank including a transparent substrate and a first inorganic film containing either or both of a transition metal and silicon, and optional a second inorganic film containing either or both of a transition metal and silicon, when an intensity of secondary ions is measured in the thickness direction of the transparent substrate and the inorganic films by TOF-SIMS with using a primary ion source of Bi and a sputtering ion source of Cs, an intensity of secondary ions containing carbon detected at the interface of the transparent substrate and the inorganic film or the inorganic films is higher than both intensities of the secondary ions containing carbon detected, respectively, at the sides remote from the interface.

    PRODUCTION METHOD OF ADDITION CONDENSATION PRODUCT

    公开(公告)号:US20210403611A1

    公开(公告)日:2021-12-30

    申请号:US17336805

    申请日:2021-06-02

    IPC分类号: C08F2/00 C08G16/02

    摘要: A production method of an addition condensation product includes a step at which an aromatic compound, a carbonyl compound, and a catalyst are mixed in a reaction solvent, and an addition condensation reaction of the aromatic compound and the carbonyl compound is conducted in the temperature range of 60 to 97° C., both inclusive, to obtain the addition condensation product of the aromatic compound and the carbonyl compound. At the step to obtain the addition condensation product, 1 mole of the aromatic compound is mixed with 0.1 to 0.999 mole, both inclusive, of the carbonyl compound as the mole ratio. A ratio of the aromatic compound dimer to the aromatic compound multimer is in the range of 1:75 to 1:1,000.

    Addition-curable silicone resin composition and a semiconductor device

    公开(公告)号:US11208532B2

    公开(公告)日:2021-12-28

    申请号:US16527444

    申请日:2019-07-31

    摘要: An addition-curable silicone resin composition which exhibits good adhesion to a substrate and has good compatibility with an inorganic filler, as well as a cured product thereof and a highly reliable semiconductor device encapsulated with the cured product, are provided. The addition-curable silicone resin composition includes (A) a linear or branched organopolysiloxane having at least one alkenyl group, said organopolysiloxane comprising at least one unit selected from R1R2SiO2/2 and R1R22SiO1/2 units, and at least one unit selected from R2′2SiO2/2, R2′3SiO1/2 and R2′SiO3/2 units, wherein a percentage of a total number of the R1R2SiO2/2 and R1R22SiO1/2 units, relative to a total number of all siloxane units, is from 0.001% to 50%, and wherein R1 is, independently at each occurrence, a hydroxy group or an alkoxy group of 1 to 30 carbon atoms; R2 is, independently at each occurrence, a group selected from a substituted or unsubstituted saturated hydrocarbon group of 1 to 12 carbon atoms, a substituted or unsubstituted aromatic hydrocarbon group of 6 to 12 carbon atoms, an alkenyl group of 2 to 10 carbon atoms, and the groups as defined for R1; and R2′ is a groups selected from the groups as defined for R2 other than those as defined for R1, with the proviso that at least one of R2 and R2′ is an alkenyl group; (B) an organohydrogenpolysiloxane having at least two hydrosilyl groups, in an amount such that the ratio of the number of hydrosilyl groups in component (B) to a total number of alkenyl groups in component (A) is from 0.1 to 4; and (C) a catalytic amount of a hydrosilylation catalyst.