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    Polymers based on fluoranthene and their use
    113.
    发明授权
    Polymers based on fluoranthene and their use 有权
    基于荧蒽的聚合物及其用途

    公开(公告)号：US07737236B2

    公开(公告)日：2010-06-15

    申请号：US11077199

    申请日：2005-03-11

    Applicant: Reinhold Schwalm ,  Yvonne Heischkel ,  Horst Weiss

    Inventor： Reinhold Schwalm ,  Yvonne Heischkel ,  Horst Weiss

    IPC: C08F10/00 ,  C08F290/14 ,  C07J53/00 ,  C07D231/00

    CPC classification number: C09K11/06 ,  C07F5/025 ,  C08G61/02 ,  C09K2211/14 ,  C09K2211/1408 ,  C09K2211/1416 ,  C09K2211/1433 ,  H01L51/0035 ,  H01L51/0052 ,  H01L51/5012

    Abstract: Polymers comprising repeating units of the formula I where the variables are defined as follows: a is an integer from 0 to 3, R1, R2, R3 are identical or different and are selected independently from among hydrogen, C1-C20-alkyl, C1-C20-alkyl containing one or more Si, N, P, O or S atoms, C6-C30-aryl, preferably C6-C14-aryl, C4-C14-heteroaryl, —N(C6-C14-aryl)2, and Y1, where Y1 may be identical or different and are selected from among —CH═CH2, trans- or cis-CH═CH—C6H5, acryloyl, methacryloyl, methylstyryl, O—CH═CH2 and glycidyl, where Y2 is selected from among —CH═CH2, trans- or cis-CH═CH—C6H5, acryloyl, methacryloyl, methylstyryl, —O—CH═CH2 and glycidyl, and one or more groups Y1 or Y2 may be crosslinked to one another.

    Abstract translation: 包含式I重复单元的聚合物，其中变量定义如下：a是0-3的整数，R1，R2，R3相同或不同，独立地选自氢，C1-C20烷基，C1- 含有一个或多个Si，N，P，O或S原子的C 20 - 烷基，C 6 -C 30 - 芳基，优选C 6 -C 14 - 芳基，C 4 -C 14 - 杂芳基，-N（C 6 -C 14 - 芳基）2和Y 1 其中Y 1可以相同或不同，并且选自-CH 2 CH 2，反式或顺式-CH = CH-C 6 H 5，丙烯酰基，甲基丙烯酰基，甲基苯乙烯基，O-CH = CH 2和缩水甘油基，其中Y 2选自 - CH 2 CH 2，反式或顺式-CH = CH-C 6 H 5，丙烯酰基，甲基丙烯酰基，甲基苯乙烯基，-O-CH = CH 2和缩水甘油基，以及一个或多个Y 1或Y 2基团可彼此交联。

    Radiation-hardenable compounds
    115.
    发明授权
    Radiation-hardenable compounds 失效
    辐射可硬化的化合物

    公开(公告)号：US07576143B2

    公开(公告)日：2009-08-18

    申请号：US11817831

    申请日：2006-03-08

    Applicant: Reinhold Schwalm ,  Erich Beck ,  Klaus Menzel

    Inventor： Reinhold Schwalm ,  Erich Beck ,  Klaus Menzel

    IPC: C08F2/46 ,  C08G18/00 ,  C08G18/77

    CPC classification number: C08G18/725 ,  C08G18/672 ,  C09D175/16 ,  C08G18/48

    Abstract: A polyurethane acrylate (A), comprises, as synthesis components, (a) at least one polyisocyanate which comprises isocyanurate groups, based on 1-isocyanato-3,3,5-trimethyl-5-(isocyanatomethyl)cyclohexane, (b) at least one polyisocyanate which comprises isocyanurate groups, based on hexamethylene diisocyanate, (c) at least one aliphatic and/or cycloaliphatic diisocyanate, (d1) at least one polyetherdiol or polyesterdiol having a molecular weight ranging from 500 to 2000, (d2) optionally, at least one diol having a molecular weight of less than 220 g/mol, (e) at least one compound having at least one group reactive toward isocyanate and at least one unsaturated group capable of free radical polymerization, and (f) optionally, at least one compound having exactly one group reactive toward isocyanate.

    Abstract translation: 聚氨酯丙烯酸酯（A）作为合成成分包含（a）至少一种包含异氰脲酸酯基团的多异氰酸酯，基于1-异氰酸根合-3,3,5-三甲基-5-（异氰酸根合甲基）环己烷，（b）在 至少一种聚异氰酸酯，其包含基于六亚甲基二异氰酸酯的异氰脲酸酯基，（c）至少一种脂族和/或脂环族二异氰酸酯，（d1）至少一种分子量为500至2000的聚醚二醇或聚酯二醇，（d2） 至少一种分子量小于220g / mol的二醇，（e）至少一种具有至少一个对异氰酸酯反应的基团和至少一个能够进行自由基聚合的不饱和基团的化合物，和（f）任选地， 至少一种具有一个对异氰酸酯具有反应性的化合物。

    METHOD FOR PRODUCING MOLDED PARTS, ESPECIALLY FOR USE IN AUTOMOBILE MANUFACTURE, AND CORRESPONDING APPROPRIATE FILMS COMPRISING A COATING
    116.
    发明申请
    METHOD FOR PRODUCING MOLDED PARTS, ESPECIALLY FOR USE IN AUTOMOBILE MANUFACTURE, AND CORRESPONDING APPROPRIATE FILMS COMPRISING A COATING 有权
    生产模具的方法，特别适用于汽车制造，以及对应包装涂料的适当膜

    公开(公告)号：US20090061215A1

    公开(公告)日：2009-03-05

    申请号：US11718566

    申请日：2005-10-17

    Applicant: Hubert Baumgart ,  Horst Hintze-Bruning ,  Fatmir Raka ,  Gabriele Dlugosch ,  Frank Dietsche ,  Nick Gruber ,  Erich Beck ,  Reinhold Schwalm ,  Klaus Menzel ,  Yvonne Heischkel ,  Berthold Austrup

    Inventor： Hubert Baumgart ,  Horst Hintze-Bruning ,  Fatmir Raka ,  Gabriele Dlugosch ,  Frank Dietsche ,  Nick Gruber ,  Erich Beck ,  Reinhold Schwalm ,  Klaus Menzel ,  Yvonne Heischkel ,  Berthold Austrup

    IPC: B32B27/40

    CPC classification number: B29C37/0032 ,  B29C2037/0042 ,  C08G18/3212 ,  C08G18/672 ,  C08G18/722 ,  C09D175/16 ,  Y10T428/265

    Abstract: A process for producing moldings, in which a pigmented coating composition (P) and a free-radically crosslinkable coating composition (K), which after crosslinking to completion produces a transparent coating (KE) are applied to a support sheet a dried but as yet not completely crosslinked coating (KT) is produced from the coating composition (K), the coated support sheet is shaped and is injection backmolded or foam-backed with a liquid polymeric material, and the coating (KT)—if this has not already taken place—is cured or aftercured; the crosslinkable coating composition (K) comprising a free-radically crosslinkable component (KK) which contains hydrogen bond forming structural elements in an amount such that 1. a coating (MT) produced from the mixture (M) of component (KK) with additives, but as yet not crosslinked to completion, has a ratio of storage modulus G(MT)′ to loss modulus G(MT)″ of from 5 to 200, G(MT)′ and G(MT)″ having been determined at 20° C. by means of rheological oscillation measurements, and 2. a coating (ME) produced from the mixture (M) of component (KK) with additives and crosslinked to completion has a storage modulus E(ME)″ of from 1.0*107.0 to 8.0*107.0 Pa, E(ME)′ having been measured in the rubber-elastic range by dynamic mechanical thermal analysis.

    Abstract translation: 一种制造模制品的方法，其中在交联完成后产生透明涂层（KE）的着色涂料组合物（P）和可自由交联的涂料组合物（K）被施加到干燥但仍然 由涂料组合物（K）制备未完全交联的涂料（KT），涂覆的支撑片材成型并用液体聚合物材料注射回模塑或泡沫背衬，并且涂层（KT） - 如果尚未采用 地方治愈或后固化; 所述可交联涂料组合物（K）包含可自由基交联的组分（KK），其含有形成氢键的结构元素，其量使得1.由组分（KK）的混合物（M）与添加剂 ，但尚未交联完成，具有5至200，G（MT）'和G（MT）“的储能模量G（MT）'与损耗模量G（MT）”的比率已被确定 在20℃下，通过流变振动测量，和2.由组分（KK）与添加剂的混合物（M）产生并交联至完成的涂层（ME）具有的储能模量E（ME） 通过动态机械热分析在橡胶弹性范围内测量的1.0 * 107.0至8.0 * 107.0 Pa，E（ME）'。

    (Meth)acrylic ester of alkenylene glycols and the use thereof
    117.
    发明申请
    (Meth)acrylic ester of alkenylene glycols and the use thereof 失效
    （甲基）亚烷基二醇的丙烯酸酯及其用途

    公开(公告)号：US20060247377A1

    公开(公告)日：2006-11-02

    申请号：US10558996

    申请日：2004-06-04

    Applicant: Ulrich Riegel ,  Thomas Daniel ,  Matthias Weismantel ,  Mark Elliott ,  Rudiger Funk ,  Reinhold Schwalm

    Inventor： Ulrich Riegel ,  Thomas Daniel ,  Matthias Weismantel ,  Mark Elliott ,  Rudiger Funk ,  Reinhold Schwalm

    IPC: C08L67/02 ,  C07C67/26

    CPC classification number: C07C69/54 ,  C07C67/08

    Abstract: The present invention relates to novel (meth)acrylic esters of polyalkoxylated glycols of the formula where AO is independently at each instance is —O—CHR3-CHR4- or —CHR3-CHR4-O— where R3 and R4 are independently H, linear or branched C1-C8-alkyl, p1 is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, or 35, p2 is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, or 35, n is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 447, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90, 91, 92, 93, 94, 95, 96, 97, 98, 99, 100, R1 and R2 are independently H or CH3, wherein there is at least one AO in (AO)p1 and also at least one AO in (AO)p2 where R3 and R4 are not both H at one and the same time, a simplified process for preparing these esters and use of reaction mixtures thus obtainable.

    Abstract translation: 本发明涉及下式的聚烷氧基化二醇的（甲基）丙烯酸酯：其中AO各自独立地为-O-CHR 3 -CHR 4 - 或-CHR 3 -CHR 4 -O-，其中R 3和R 4独立地为H，直链或 支链C 1 -C 8 - 烷基，p 1为1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21 ，22,23,24,25,26,27,28,29,30,31,32,33,34或35中，p2分别为1,2,3,4,5,6,7,8,9,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34或35， 10，11，12，13，14，15，16，17，18，19，20，21，22，23，24，25，26，27，28，29，30，31，32，33，34， 或35，n为1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23 ，24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,447,48 ，49，50，51，52，53，54，55，56，57，58，59，60，61，62，63，64，65，66，67，68，69，70，，71，72，73 ，74，75，76，77，78，79，80，81，82，83，84，85，86，87，88，89，90，91，92，93，94，95，96，97，98 ，99,100，R 1和R 2独立地为H或CH 3，其中存在至少一个AO （AO）p 1和（AO）p2中的至少一个AO，其中R3和R4不同时为一个，制备这些酯的简化方法和使用由此获得的反应混合物。

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