Abstract:
Reinforcement in concrete is cathodically protected by galvanically connecting a sacrificial anode, such as a zinc or zinc alloy anode, to the reinforcement, and contacting the anode with an electrolyte solution having a pH which is maintained sufficiently high for corrosion of the anode to occur, and for passive film formation on the anode to be avoided. The pH of the electrolyte is preferably at least 0.2 units, and preferably from 0.5 units to more than 1.0 units, above the pH value at which passivity of the anode would occur. The electrolyte may be for example sodium hydroxide or potassium hydroxide but is preferably lithium hydroxide which also acts as an alkali-silica reaction inhibitor.
Abstract:
An image is reproduced and transferred onto a substrate by (a) providing a positive electrode having a continuous passivated surface moving at constant speed; (b) forming on the positive electrode surface dots of colored, coagulated colloid representative of a desired image, by electrocoagulation of a colloid present in an electrocoagulation printing ink; and (c) bringing a substrate into contact with the dots of colloid to cause transfer of same onto the substrate. Step (b) is carried out by providing a series of negative electrodes having passivated surfaces spaced from the positive electrode surface by a constant gap; coating the positive electrode surface with an olefin; filling the electrode gap with the ink; applying to the negative electrodes a pulsed bias voltage; and applying to selected ones of the negative electrodes a trigger voltage sufficient to cause point-by-point selective coagulation and adherence of the colloid onto the olefin-coated positive electrode surface.
Abstract:
An electrolytic restoration of concrete includes an anode positioned at a surface of the concrete to be restored and the communication of a current from the anode to the reinforcing bars in the concrete as a cathode. The anode is in the presence of or carries an electrolyte so that sufficient current is provided temporarily over a sufficient period of time so that ions from the concrete are carried through the concrete and expelled into the electrolyte for extraction. The anode is provided by layer of conductive material which is particulate or fibrous so that it is an amorphous layer which can therefore follow the surface of the concrete. In a horizontal arrangement, the layer can be applied directly onto a felt mat for carrying electrolyte. In a vertical orientation an initial layer of chopped cellulose is wetted and applied onto the vertical surface followed by the same layer carrying carbon powder so that the layer is conductive and forms the anode when connected to metal connector plates buried in the anode layer.
Abstract:
For cathodic protection against corrosion of steel reinforcements in reinforced steel constructions, a prefabricated anode is provided which has a core of titanium expanded metal provided with an activation layer and with a cement-containing ion-conductive jacket; the prefabricated anode is immovably secured to the reinforced concrete construction in an ion-conductive bond; after that, the reinforcement of the concrete construction and the core of the anode are connected to the poles of a direct voltage source.
Abstract:
An electrochemical cell (50) for deionizsation utilizes electrochemical ion-exchange to remove ions from a feed solution. Under the influence of an electric field, ions are adsorbed into, are scored within and pass through a permeable layer (54, 64) of particulate ion-absorbing material and binder, the sheet being several millimeters thick. Water from the feed solution also permeates through the layer (54, 64), so a concentrated solution of the ions emerges from the rear (58) of the layer. The cell does not require separate sources of feed and eluant solutions and can be operated substantially continuously. In a modified cell (70) the flow path for the feed solution passes through a highly porous ion exchanger structure (77), which may be located between two such microporous layers (54, 64). Absorption in such a cell may be effective in the absence of an electric field, elution requiring the periodic application of the electric field.
Abstract:
A process for adjusting the steel-to-concrete bond strength in a hardened concrete structure having embedded steel elements. A source of DC voltage, preferably in the range of 5-40 volts, is connected at its negative side to the embedded steel and at its positive side to an external distributed electrode formed on the surface of the concrete structure. The external electrode may, for example, be a self-adherent electrolytic mass of moist pulp fiber, a conductive coating, or the like. Application of voltage to the structure and the resulting current flow between embedded steel and the external electrode, initially results in a progressive reduction in the steel-to-concrete bond strength. This can be particularly useful in connection with pre-tensioned or post-tensioned structures. Continued application of the voltage results in a progressive increase in bond strength, ultimately reaching a maximum strength significantly above initial values. This is useful in reinforced concrete structures, to improve the bond between the concrete and the reinforcing steel. By reference to pre-established database values, the process may be easily controlled to realize targeted modifications in bond strength. Significant improvement can also be achieved in the sealing of the interface between steel and concrete, to prevent seepage of contaminating liquids or gases along the interface.
Abstract:
A catalytically-coated valve metal reference electrode is used to measure the potential of reinforcing members in concrete in a system to cathodically protect the same.
Abstract:
Cathodic protection to prevent corrosion of embedded steel, e.g. reinforcing rods in concrete, is obtained by applying a graphite-alkyl methacrylate composition to the exterior of the concrete.
Abstract:
A method of installing a coated valve metal electrode as impressed-current anode in a cathodic protection system for a steel-reinforced concrete structure comprises providing a roll of coated valve metal mesh, unrolling the mesh and installing it in conformity with the structure, fixing the mesh to the structure and embedding the mesh in an ion-conductive overlay. The mesh is a highly expanded valve metal sheet providing multiple current paths and therefore enhanced redundancy. Current distributor strips can be welded to the mesh after unrolling.
Abstract:
A catalytic polymer electrode compries a current conducting polymer body forming an electrode base which is provided with catalytic valve metal particles fixed to its surface. A current conducting body of carbon filled thermoplastic polymer is heated to soften its outer surface, and the catalytic valve metal particles are pressed onto its softened surface and thereby attached to the surface of the polymer body. Such a catalytic polymer electrode used as an anode in an impressed-current cathodic protection system comprises a catalyst to provide a reduced oxygen potential. Such catalytic polymer anodes may be applied in systems for impressed current cathodic protection of reinforced concrete structures, such as bridge decks, support members, parking garages, or of buried or submerged steel structrues such as gas and oil pipelines, offshore production platforms, fuel storage tanks, well casings.