公开(公告)号：US11302881B2

公开(公告)日：2022-04-12

申请号：US13099716

申请日：2011-05-03

Applicant: Stephen R. Forrest ,  Noel C. Giebink

Inventor： Stephen R. Forrest ,  Noel C. Giebink

IPC: H01L31/00 ,  H01L51/00 ,  H01L51/42

Abstract: The present disclosure generally relates to organic photosensitive optoelectronic devices and polaron pair recombination dynamics to impact efficiency and open circuit voltages of organic solar cells. The present disclosure also relates, in part, to methods of making organic photosensitive optoelectronic devices comprising the same.

公开(公告)号：US09508940B2

公开(公告)日：2016-11-29

申请号：US13035051

申请日：2011-02-25

Applicant: Mark E. Thompson ,  Yujian You ,  Andrei Shoustikov ,  Scott Sibley ,  Paul E. Burrows ,  Stephen R. Forrest

Inventor： Mark E. Thompson ,  Yujian You ,  Andrei Shoustikov ,  Scott Sibley ,  Paul E. Burrows ,  Stephen R. Forrest

IPC: H01L51/54 ,  H01L51/00 ,  C07D487/22 ,  C09K11/06 ,  H01L51/50 ,  H01L51/52 ,  H05B33/14 ,  H05B33/28

CPC classification number: H01L51/0084 ,  C07D487/22 ,  C09K11/06 ,  C09K2211/10 ,  C09K2211/1003 ,  C09K2211/1007 ,  C09K2211/1018 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1074 ,  C09K2211/18 ,  C09K2211/185 ,  C09K2211/186 ,  H01L51/0053 ,  H01L51/0067 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0087 ,  H01L51/5016 ,  H01L51/5221 ,  H01L51/5234 ,  H01L2251/308 ,  H01L2251/5323 ,  H05B33/14 ,  H05B33/28 ,  Y10S428/917 ,  Y10T428/24942

Abstract: Organic light emitting devices are disclosed which are comprised of a heterostructure for producing electroluminescence wherein the heterostructure is comprised of an emissive layer containing a phosphorescent dopant compound. For example, the phosphorescent dopant compound may be comprised of platinum octaethylporphine (PtOEP), which is a compound having the chemical structure with the formula:

公开(公告)号：US09130170B2

公开(公告)日：2015-09-08

申请号：US13666664

申请日：2012-11-01

Applicant: Stephen R. Forrest ,  Xiaoran Tong ,  Jun Yeob Lee ,  Yong Joo Cho

Inventor： Stephen R. Forrest ,  Xiaoran Tong ,  Jun Yeob Lee ,  Yong Joo Cho

IPC: H01L51/44 ,  H01L51/00 ,  B82Y10/00 ,  H01L27/30 ,  H01L27/146 ,  H01L51/42

CPC classification number: H01L51/003 ,  B82Y10/00 ,  H01L27/14643 ,  H01L27/30 ,  H01L51/0046 ,  H01L51/0053 ,  H01L51/0077 ,  H01L51/0078 ,  H01L51/0097 ,  H01L51/424 ,  Y02E10/549

Abstract: There is disclosed a method for preparing the surface of a metal substrate. The present disclosure also relates to an organic photovoltaic device including a metal substrate made by such method. Also disclosed herein is an inverted photosensitive device including a stainless steel foil reflective electrode, an organic donor-acceptor heterojunction over the reflective electrode, and a transparent electrode over the donor-acceptor heterojunction.

Abstract translation: 公开了一种制备金属基材表面的方法。 本公开还涉及包括通过这种方法制造的金属衬底的有机光伏器件。 本文还公开了一种反转感光装置，其包括不锈钢箔反射电极，反射电极上的有机供体 - 受体异质结，以及供体 - 受体异质结上方的透明电极。

公开(公告)号：US08931431B2

公开(公告)日：2015-01-13

申请号：US12729448

申请日：2010-03-23

Applicant: Stephen R. Forrest ,  Gregory McGraw

Inventor： Stephen R. Forrest ,  Gregory McGraw

IPC: C23C16/44 ,  C23C16/52 ,  B41J2/005 ,  C23C14/04 ,  C23C14/12 ,  C23C14/22 ,  C23C16/22

CPC classification number: C23C14/12 ,  B41J2/005 ,  C23C14/04 ,  C23C14/228

Abstract: A first device is provided. The device includes a print head. The print head further includes a first nozzle hermetically sealed to a first source of gas. The first nozzle has an aperture having a smallest dimension of 0.5 to 500 microns in a direction perpendicular to a flow direction of the first nozzle. At a distance from the aperture into the first nozzle that is 5 times the smallest dimension of the aperture of the first nozzle, the smallest dimension perpendicular to the flow direction is at least twice the smallest dimension of the aperture of the first nozzle.

Abstract translation: 提供第一个设备。 该装置包括打印头。 打印头还包括密封到第一气体源的第一喷嘴。 第一喷嘴在垂直于第一喷嘴的流动方向的方向上具有最小尺寸为0.5至500微米的孔。 在与第一喷嘴的孔的最小尺寸的5倍的孔到第一喷嘴的距离处，垂直于流动方向的最小尺寸至少是第一喷嘴的孔的最小尺寸的两倍。

公开(公告)号：US08912036B2

公开(公告)日：2014-12-16

申请号：US12197195

申请日：2008-08-22

Applicant: Stephen R. Forrest ,  Richard R. Lunt

Inventor： Stephen R. Forrest ,  Richard R. Lunt

IPC: H01L21/00 ,  H01L31/00 ,  H01L51/00 ,  B82Y10/00 ,  H01L51/42

CPC classification number: H01L51/424 ,  B82Y10/00 ,  C23C14/12 ,  C23C14/228 ,  H01L51/0008 ,  H01L51/0013 ,  H01L51/0046 ,  H01L51/0053 ,  H01L51/0078 ,  Y02E10/549

Abstract: There is disclosed methods utilizing organic vapor phase deposition for growing bulk organic crystalline layers for organic photosensitive devices, heterojunctions and films made by such methods, and devices using such heterojunctions. There is also disclosed new methods for manufacturing heterojunctions and organic photosensitive devices, and the heterojunctions and devices manufactured thereby.

Abstract translation: 公开了利用有机气相沉积来生长有机光敏器件的本体有机结晶层的方法，通过这种方法制造的异质结和膜以及使用这种异质结的器件。 还公开了用于制造异质结和有机光敏器件的新方法，以及由此制造的异质结和器件。

公开(公告)号：US08574726B2

公开(公告)日：2013-11-05

申请号：US13009001

申请日：2011-01-19

Applicant: Mark E. Thompson ,  Peter Djurovich ,  Sergey Lamansky ,  Drew Murphy ,  Raymond Kwong ,  Feras Abdel-Razzaq ,  Stephen R. Forrest ,  Marc A. Baldo ,  Paul E. Burrows

Inventor： Mark E. Thompson ,  Peter Djurovich ,  Sergey Lamansky ,  Drew Murphy ,  Raymond Kwong ,  Feras Abdel-Razzaq ,  Stephen R. Forrest ,  Marc A. Baldo ,  Paul E. Burrows

IPC: H01L51/54

CPC classification number: H01L51/0085 ,  C07D209/86 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1037 ,  C09K2211/1092 ,  C09K2211/185 ,  C09K2211/186 ,  H01L51/0042 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0062 ,  H01L51/0065 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0087 ,  H01L51/0088 ,  H01L51/5016 ,  H01L51/5096 ,  H01L2251/308 ,  Y10S428/917

Abstract: Organic light emitting devices are described wherein the emissive layer comprises a host material containing an emissive molecule, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including cyclometallated platinum, iridium and osmium complexes. The organic light emitting devices optionally contain an exciton blocking layer. Furthermore, improved electroluminescent efficiency in organic light emitting devices is obtained with an emitter layer comprising organometallic complexes of transition metals of formula L2MX, wherein L and X are distinct bidentate ligands. Compounds of this formula can be synthesized more facilely than in previous approaches and synthetic options allow insertion of fluorescent molecules into a phosphorescent complex, ligands to fine tune the color of emission, and ligands to trap carriers.

公开(公告)号：US08557402B2

公开(公告)日：2013-10-15

申请号：US13205290

申请日：2011-08-08

Applicant: Mark E. Thompson ,  Peter Djurovich ,  Sergey Lamansky ,  Drew Murphy ,  Raymond Kwong ,  Feras Abdel-Razzaq ,  Stephen R. Forrest ,  Marc A. Baldo ,  Paul E. Burrows

Inventor： Mark E. Thompson ,  Peter Djurovich ,  Sergey Lamansky ,  Drew Murphy ,  Raymond Kwong ,  Feras Abdel-Razzaq ,  Stephen R. Forrest ,  Marc A. Baldo ,  Paul E. Burrows

IPC: H01L51/54 ,  C09K11/06

CPC classification number: H01L51/0085 ,  C07D209/86 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1037 ,  C09K2211/1092 ,  C09K2211/185 ,  C09K2211/186 ,  H01L51/0042 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0062 ,  H01L51/0065 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0087 ,  H01L51/0088 ,  H01L51/5016 ,  H01L51/5096 ,  H01L2251/308 ,  Y10S428/917

Abstract: Organic light emitting devices are described wherein the emissive layer comprises a host material containing an emissive molecule, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including cyclometallated platinum, iridium and osmium complexes. The organic light emitting devices optionally contain an exciton blocking layer. Furthermore, improved electroluminescent efficiency in organic light emitting devices is obtained with an emitter layer comprising organometallic complexes of transition metals of formula L2MX, wherein L and X are distinct bidentate ligands. Compounds of this formula can be synthesized more facilely than in previous approaches and synthetic options allow insertion of fluorescent molecules into a phosphorescent complex, ligands to fine tune the color of emission, and ligands to trap carriers.

公开(公告)号：US20130210189A1

公开(公告)日：2013-08-15

申请号：US13080759

申请日：2011-04-06

Applicant: Stephen R. Forrest ,  Mark E. Thompson ,  Guodan Wei ,  Siyi Wang

Inventor： Stephen R. Forrest ,  Mark E. Thompson ,  Guodan Wei ,  Siyi Wang

IPC: H01L51/42

CPC classification number: H01L51/4253 ,  H01L51/0028 ,  H01L51/4273 ,  Y02E10/549

Abstract: A method of preparing a bulk heterojunction organic photovoltaic cell through combinations of thermal and solvent vapor annealing are described. Bulk heterojunction films may prepared by known methods such as spin coating, and then exposed to one or more vaporized solvents and thermally annealed in an effort to enhance the crystalline nature of the photoactive materials.

Abstract translation: 描述了通过热和溶剂蒸汽退火的组合制备本体异质结有机光伏电池的方法。 本体异质结膜可以通过已知的方法例如旋涂来制备，然后暴露于一种或多种蒸发的溶剂并进行热退火，以增强光活性材料的结晶性质。

公开(公告)号：US20130153032A1

公开(公告)日：2013-06-20

申请号：US13112596

申请日：2011-05-20

Applicant: Stephen R. Forrest ,  Michael S. Arnold ,  Jeramy D. Zimmerman

Inventor： Stephen R. Forrest ,  Michael S. Arnold ,  Jeramy D. Zimmerman

IPC: H01L51/42

CPC classification number: H01L51/424 ,  B82Y10/00 ,  H01L51/0038 ,  H01L51/0046 ,  H01L51/0048 ,  H01L51/0053 ,  H01L51/4253 ,  Y02E10/549

Abstract: A photovoltaic device includes a photoactive region disposed between and electrically connected to two electrodes where the photoactive region includes photoactive polymer-wrapped carbon nanotubes that create excitons upon absorption of light in the range of about 400 nm to 1400 nm.

Abstract translation: 光伏器件包括设置在两个电极之间并电连接到两个电极的光活性区域，其中光活性区域包括光吸收聚合物包裹的碳纳米管，其在吸收约400nm至1400nm范围内的光时产生激子。

公开(公告)号：US08456081B2

公开(公告)日：2013-06-04

申请号：US13117926

申请日：2011-05-27

Applicant: Yifan Zhang ,  Stephen R. Forrest ,  Mark Thompson

Inventor： Yifan Zhang ,  Stephen R. Forrest ,  Mark Thompson

IPC: H01L51/50 ,  H01L51/56

CPC classification number: H01L51/5012 ,  H01L51/0081 ,  H01L2251/5384

Abstract: A first device is provided. The first device further comprises an organic light emitting device. The organic light emitting device further comprises an anode, a cathode, and an emissive layer disposed between the anode and the cathode. The emissive layer further comprises an organic host compound, an organic emitting compound capable of fluorescent emission at room temperature, and an organic dopant compound. The triplet energy of the dopant compound is lower than the triplet energy of the host compound. The dopant compound does not strongly absorb the fluorescent emission of the emitting compound.

Abstract translation: 提供第一个设备。 第一器件还包括有机发光器件。 有机发光器件还包括阳极，阴极和布置在阳极和阴极之间的发光层。 发光层还包含有机主体化合物，能够在室温下发荧光的有机发光化合物和有机掺杂剂化合物。 掺杂剂化合物的三重态能量低于主体化合物的三线态能量。 掺杂剂化合物不会强烈地吸收发光化合物的荧光发射。