公开(公告)号：US4353815A

公开(公告)日：1982-10-12

申请号：US203017

申请日：1980-11-03

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/656 ,  C10G35/09 ,  B01J23/58

CPC分类号： B01J23/6567 ,  C10G35/09

摘要： Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at hydrocarbon dehydrogenation conditions, with a novel attenuated superactive multimetallic catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component maintained in the elemental metallic state, and of a manganese component. An example of the attenuated superactive nonacidic multimetallic catalytic composite disclosed herein is a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of an alkali or alkaline earth component, a manganese component, and of a platinum group component which is maintained in the elemental metallic state during the incorporation of a rhenium carbonyl component.

摘要翻译： 可脱氢烃通过在烃脱氢条件下与新型减毒超活性多金属催化复合材料接触来脱氢，该催化复合材料包含催化有效量的热解铼羰基组分与多孔载体材料的组合，所述多孔载体材料含有催化有效量的 保持元素金属状态的铂族组分和锰组分。 本文公开的减毒超活性非酸性多金属催化复合物的实例是催化有效量的热解的铼羰基组分与多孔载体材料的组合，所述多孔载体材料含有催化有效量的碱金属或碱土金属组分的均匀分散体，锰组分 ，以及在引入羰基铼组分期间维持在元素金属状态的铂族组分。

公开(公告)号：US4328385A

公开(公告)日：1982-05-04

申请号：US212490

申请日：1980-12-03

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/656 ,  C07C5/22 ,  C07C5/25 ,  C10G35/09 ,  C07C5/23

CPC分类号： C10G35/09 ,  B01J23/6567 ,  C07C5/226 ,  C07C5/2556 ,  C07C2521/04 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/656 ,  C07C2527/126 ,  Y02P20/582

摘要： Isomerizable hydrocarbons are isomerized using a catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component, which is maintained in the elemental metallic state during the incorporation and pyrolysis of the rhenium carbonyl component, of a tin component, and of a halogen component.

摘要翻译： 使用包含催化有效量的热解铼羰基组分与多孔载体材料的组合的催化复合物异构化异构化，该多孔载体材料含有催化有效量的铂族组分的均匀分散体，其在 钌羰基组分，锡组分和卤素组分的引入和热解。

公开(公告)号：US4298504A

公开(公告)日：1981-11-03

申请号：US166214

申请日：1980-06-18

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/644 ,  B01J23/656 ,  C10G35/09 ,  B01J27/08 ,  B01J23/64 ,  B01J27/10

CPC分类号： B01J23/6567 ,  C10G35/09 ,  B01J23/6447

摘要： A novel attenuated superactive multimetallic catalytic composite especially useful for converting hydrocarbons comprises a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component, which is maintained in the elemental metallic state during the incorporation of the rhenium carbonyl component, and of a bismuth component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component, bismuth component and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium, about 0.01 to about 5 wt. % bismuth about 0.1 to about 3.5 wt. % halogen. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a uniform dispersion of a bismuth component and of a platinum group metal maintained in the elemental state, whereby the interaction of the rhenium moiety with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligands associated with the rhenium reagent.

摘要翻译： 特别适用于转化烃类的新型减毒超活性多金属催化复合物包括催化有效量的热解铼羰基组分与含有催化有效量的铂族组分的均匀分散体的多孔载体材料的组合，其保持在 在掺入铼羰基组分和铋组分期间的元素金属状态。 在一个非常优选的实施方案中，该新型催化复合材料还含有催化有效量的卤素组分。 铂族组分，热解铼羰基组分，铋组分和任选的卤素组分优选以基于元素计算的量存在于多金属催化复合物中，相当于约0.01至约2重量％ ％铂族金属，约0.01至约5wt。 ％铼，约0.01至约5wt。 铋约0.1至约3.5wt。 ％卤素。 与本发明催化复合材料的制备相关联的关键特征是羰基钌合物与含有均匀分散的铋组分和保持在元素状态的铂族金属的多孔载体材料的反应，由此铼的相互作用 与铂族部分的部分由于与铼试剂相关的一氧化碳配体的铂嗜性（即铂寻求）倾向而最大化。

公开(公告)号：US4295960A

公开(公告)日：1981-10-20

申请号：US203018

申请日：1980-11-03

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/656 ,  C07C5/41 ,  C10G35/09 ,  C07C15/08 ,  B01J27/08

CPC分类号： C10G35/09 ,  B01J23/6567 ,  C07C5/417 ,  Y02P20/52

摘要： Dehydrocyclizable hydrocarbons are converted to aromatics by contacting them at hydrocarbon dehydrocyclization conditions with an attenuated superactive acidic multimetallic catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing catalytically effective amounts of a halogen component, a cadmium component and a uniform dispersion of a catalytically effective amount of a platinum group component which is maintained in the elemental metallic state. The platinum group, pyrolyzed rhenium carbonyl, cadmium and halogen components are present in the multimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium, about 0.01 to about 5 wt. % cadmium and about 0.1 to about 3.5 wt. % halogen. A specific example of a dehydrocyclization method disclosed herein is a method for converting a feed mixture of n-hexane and n-heptane to a product mixture of benzene and toluene which involves contacting the feed mixture and a hydrogen stream with the attenuated superactive acidic multimetallic catalyst disclosed herein at hydrocarbon dehydrocyclization conditions.

摘要翻译： 可脱氢可环化烃通过在烃脱氢环化条件下与减压的超活性酸性多金属催化复合物接触而转化成芳族化合物，所述衰减的超活性酸性多金属催化复合材料包含催化有效量的热解的铼羰基组分与含有催化有效量的卤素组分的多孔载体材料的组合， 镉组分和维持在元素金属状态的催化有效量的铂族组分的均匀分散体。 铂族，热解的铼羰基，镉和卤素组分分别以基于元素计算的量存在于多金属催化剂中，相当于约0.01至约2wt。 ％铂族金属，约0.01至约5wt。 ％铼，约0.01至约5wt。 ％镉和约0.1至约3.5wt。 ％卤素。 本文公开的脱氢环化方法的具体实例是将正己烷和正庚烷的进料混合物转化为苯和甲苯的产物混合物的方法，其包括将进料混合物和氢气流与减压的超活性酸性多金属催化剂 在烃脱氢环化条件下公开。

公开(公告)号：US4290921A

公开(公告)日：1981-09-22

申请号：US130655

申请日：1980-03-17

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/656 ,  C10G35/09 ,  B01J27/08 ,  B01J23/64 ,  B01J27/10

CPC分类号： B01J23/6567 ,  C10G35/09

摘要： A novel attenuated superactive multimetallic catalytic composite especially useful for converting hydrocarbons comprises a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component, which is maintained in the elemental metallic state during the incorporation of the rhenium carbonyl component, and of a zirconium component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component, zirconium component and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium, about 0.01 to about 5 wt. % zirconium and about 0.1 to about 3.5 wt. % halogen. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a uniform dispersion of a zirconium component and of a platinum group metal maintained in the elemental state, whereby the interaction of the rhenium moiety with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligands associated with the rhenium reagent.

摘要翻译： 特别适用于转化烃类的新型减毒超活性多金属催化复合物包括催化有效量的热解铼羰基组分与含有催化有效量的铂族组分的均匀分散体的多孔载体材料的组合，其保持在 在加入铼羰基组分和锆组分期间的元素金属状态。 在一个非常优选的实施方案中，该新型催化复合材料还含有催化有效量的卤素组分。 铂族组分，热解的铼羰基组分，锆组分和任选的卤素组分优选以基于元素计算的量存在于多金属催化复合材料中，对应于约0.01至约2重量％ ％铂族金属，约0.01至约5wt。 ％铼，约0.01至约5wt。 ％锆和约0.1至约3.5重量％ ％卤素。 与本发明催化复合材料的制备相关联的关键特征是羰基铑合金与含有均匀分散的锆组分和维持在元素状态的铂族金属的多孔载体材料的反应，由此铼的相互作用 与铂族部分的部分由于与铼试剂相关的一氧化碳配体的铂嗜性（即铂寻求）倾向而最大化。

公开(公告)号：US4280930A

公开(公告)日：1981-07-28

申请号：US135585

申请日：1980-03-31

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/89 ,  C07C5/32 ,  C07C5/333 ,  C07C5/367 ,  B01J23/58 ,  B01J23/60

CPC分类号： C07C5/3337 ,  B01J23/8953 ,  C07C5/325 ,  C07C5/367 ,  C07C2521/04 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/06 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/75 ,  C07C2523/89 ,  Y02P20/52

摘要： A nonacidic catalytic composite especially useful for dehydrogenating dehydrogenatable hydrocarbons comprises a combination of a platinum group component, a cobalt component, a zinc component, and an alkali or alkaline earth component with a porous carrier material in amounts sufficient to result in a composite containing about 0.01 to about 2 wt. % platinum group metal, about 0.05 to about 5 wt. % cobalt, about 0.01 to about 5 wt. % zinc and about 0.1 to about 5 wt. % alkali metal or alkaline earth metal.

摘要翻译： 特别可用于脱氢可脱氢烃的非酸催化复合物包括铂组分，钴组分，锌组分和碱金属或碱土金属组分与多孔载体材料的组合，其量足以导致含有约0.01 至约2重量％ ％铂族金属，约0.05至约5wt。 ％钴，约0.01至约5wt。 ％锌和约0.1至约5wt。 ％碱金属或碱土金属。

公开(公告)号：US4268707A

公开(公告)日：1981-05-19

申请号：US148117

申请日：1980-05-09

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/89 ,  C07C5/333 ,  C07C5/367 ,  C07C5/41

CPC分类号： C07C5/3337 ,  B01J23/8946 ,  C07C5/367 ,  C07C2521/04 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/42 ,  C07C2523/75 ,  C07C2523/89 ,  Y02P20/52

摘要： Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at dehydrogenation conditions, with a nonacidic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a cobalt component, a lanthanide series component and an alkali or alkaline earth component with a porous carrier material in amounts sufficient to result in a composite containing about 0.01 to about 2 wt. % platinum group metal, about 0.05 to about 5 wt. % cobalt, about 0.01 to about 5 wt. % lanthanide series metal and about 0.1 to about 5 wt. % alkali metal or alkaline earth metal.

摘要翻译： 可脱氢烃通过在脱氢条件下与含有催化有效量的铂族组分，钴组分，镧系元素组分和碱金属或碱土金属组分与多孔载体材料的组合的非酸催化复合物接触而脱氢 其量足以导致含有约0.01至约2wt。 ％铂族金属，约0.05至约5wt。 ％钴，约0.01至约5wt。 ％镧系金属和约0.1至约5wt。 ％碱金属或碱土金属。

公开(公告)号：US4256608A

公开(公告)日：1981-03-17

申请号：US80639

申请日：1979-10-01

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/656 ,  C10G35/09 ,  B01J27/08 ,  B01J23/89 ,  B01J27/10

CPC分类号： B01J23/6567 ,  C10G35/09

摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a novel attenuated superactive multimetallic catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of a catalytically effective amount of a platinum group component, which is maintained in the elemental metallic state during the incorporation and pyrolysis of the rhenium carbonyl component, and of an iron component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component, iron component and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium, about 0.005 to about 5 wt. % iron and about 0.1 to about 3.5 wt. % halogen. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a uniform dispersion of an iron component and of a platinum group component maintained in the elemental state, whereby the interaction of the rhenium moiety with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligands associated with the rhenium reagent. A specific example of the type of hydrocarbon conversion process disclosed herein is a process for the catalytic reforming of a low octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the attenuated superactive multimetallic catalytic composite at reforming conditions.

摘要翻译： 通过在碳氢化合物转化条件下使它们与新型减弱的超活性多金属催化复合材料接触来转化碳氢化合物，该催化复合材料包含催化有效量的热解的铼羰基组分与含有催化有效量的铂的均匀分散体的多孔载体材料的组合 组分，其在羰基铼组分和铁组分的引入和热解期间保持在元素金属状态。 在一个非常优选的实施方案中，该新型催化复合材料还含有催化有效量的卤素组分。 铂族组分，热解的铼羰基组分，铁组分和任选的卤素组分优选以基于元素计算的量存在于多金属催化复合物中，相当于约0.01至约2重量％ ％铂族金属，约0.01至约5wt。 ％铼，约0.005至约5wt。 ％铁和约0.1至约3.5wt。 ％卤素。 与制备本发明的催化复合材料相关的一个关键特征是羰基钌络合物与保持在元素状态的铁组分和铂族组分的均匀分散体的多孔载体材料的反应，由此铼的相互作用 与铂族部分的部分由于与铼试剂相关的一氧化碳配体的铂嗜性（即铂寻求）倾向而最大化。 本文公开的烃转化方法的具体实例是低辛烷值汽油馏分的催化重整方法，其中汽油馏分和氢气流在重整条件下与减弱的超活性多金属催化复合材料接触。

公开(公告)号：US4229319A

公开(公告)日：1980-10-21

申请号：US48957

申请日：1979-06-15

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/68 ,  B01J27/08 ,  B01J23/66 ,  B01J27/10

CPC分类号： B01J23/688

摘要： An attenuated superactive multimetallic catalytic composite especially useful for converting hydrocarbons comprises a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of a catalytically effective amount of a platinum group component, which is maintained in the elemental metallic state, and of a silver component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component, silver component and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium, about 0.01 to about 5 wt. % silver and about 0.1 to about 3.5 wt. % halogen. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a uniform dispersion of a silver component and of a platinum group component maintained in the elemental state, whereby the interaction of the rhenium moiety with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligands associated with the rhenium reagent.

摘要翻译： 特别可用于转化烃的减毒超活性多金属催化复合物包括催化有效量的热解的铼羰基组分与含有催化有效量的铂族组分的均匀分散体的多孔载体材料的组合，其保持在 元素金属状态和银组分。 在一个非常优选的实施方案中，该新型催化复合材料还含有催化有效量的卤素组分。 铂族组分，热解的铼羰基组分，银组分和任选的卤素组分优选以基于元素计算的量存在于多金属催化复合物中，相当于约0.01至约2重量％ ％铂族金属，约0.01至约5wt。 ％铼，约0.01至约5wt。 ％银和约0.1至约3.5重量％ ％卤素。 与本发明催化复合材料的制备相关的主要特征是羰基铑合金与含有均匀分散的银组分和维持在元素状态的铂族组分的多孔载体材料的反应，由此铼的相互作用 与铂族部分的部分由于与铼试剂相关的一氧化碳配体的铂嗜性（即铂寻求）倾向而最大化。

公开(公告)号：US4220558A

公开(公告)日：1980-09-02

申请号：US29507

申请日：1979-04-12

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/62 ,  B01J23/656 ,  B01J27/08 ,  B01J23/64 ,  B01J27/10

CPC分类号： B01J23/62 ,  B01J23/6567

摘要： A novel attenuated superactive multimetallic catalytic composite, especially useful for the conversion of hydrocarbons, comprises a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component, which is maintained in the elemental metallic state, and of an indium component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component, indium component and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium, about 0.01 to about 5% indium and about 0.1 to about 3.5 wt. % halogen. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a uniform dispersion of an indium component and of a platinum group metal maintained in the elemental state, whereby the interaction of the rhenium moiety with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligand used in the rhenium reagent.

摘要翻译： 特别可用于烃转化的新颖的减毒超活性多金属催化复合材料包括催化有效量的热解铼羰基组分与含有催化有效量的铂族组分的均匀分散体的多孔载体材料的组合，其中 保持在元素金属状态和铟组分。 在一个非常优选的实施方案中，该新型催化复合材料还含有催化有效量的卤素组分。 铂族组分，热解的铼羰基组分，铟组分和任选的卤素组分优选以基于元素计算的量存在于多金属催化复合物中，相当于约0.01至约2重量％ ％铂族金属，约0.01至约5wt。 ％铼，约0.01至约5％的铟和约0.1至约3.5wt。 ％卤素。 与本发明的催化复合材料的制备相关的关键特征是羰基钌络合物与保持在元素状态的铟组分和铂族金属的均匀分散体的多孔载体材料的反应，由此铼的相互作用 由于在铼试剂中使用的一氧化碳配体的铂嗜性（即铂寻求）倾向，铂基团部分被最大化。