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    GRAFT COPOLYMER IMPROVING ADHESION RESISTANCE AND IMPACT STRENGTH, METHOD OF PREPARING THE SAME, AND PVC COMPOSITION COMPRISING THE SAME
    11.
    发明申请
    GRAFT COPOLYMER IMPROVING ADHESION RESISTANCE AND IMPACT STRENGTH, METHOD OF PREPARING THE SAME, AND PVC COMPOSITION COMPRISING THE SAME 有权
    提高耐粘连性和抗冲击强度的共聚物，其制备方法和包含其的PVC组合物

    公开(公告)号：US20110244240A1

    公开(公告)日：2011-10-06

    申请号：US12870479

    申请日：2010-08-27

    Applicant: Yoon Ho Kim ,  Geon Soo Kim ,  Yeon Hwa Wi ,  Ki Hyun Yoo ,  Chan Hong Lee

    Inventor： Yoon Ho Kim ,  Geon Soo Kim ,  Yeon Hwa Wi ,  Ki Hyun Yoo ,  Chan Hong Lee

    IPC: B32B5/00 ,  C08L51/04

    CPC classification number: C08F279/02 ,  C08F285/00 ,  C08F290/062 ,  C08L27/06 ,  C08L51/04 ,  Y10T428/2998 ,  C08F212/08 ,  C08F220/18 ,  C08F220/28

    Abstract: Disclosed is a graft copolymer highly improving the adhesion resistance and impact strength, a method of preparing the same, and PVC composition containing the same, wherein the graft copolymer comprises i) 55 to 85 wt % of a conjugated diene-based rubber core; and ii) 15 to 45 wt % of a graft shell surrounding the rubber core, and formed by comprising a (meth)acrylate-based monomer, and at least one selected from the group consisting of a vinyl-based monomer having a polyalkylene oxide group represented by the following Formula 1; in which the graft copolymer includes 0.1 to 5 wt % of the vinyl-based monomer having the polyalkylene oxide group represented by the following Formula 1: wherein R is independently hydrogen, or C1 to C4 alkyl group, and n is independently 3 to 14.

    Abstract translation: 公开了一种高度改善耐粘连性和冲击强度的接枝共聚物，其制备方法和含有该组合物的PVC组合物，其中接枝共聚物包括i）55-85重量％的共轭二烯系橡胶核; 和ii）15至45重量％的围绕所述橡胶芯的接枝壳，并且通过包含（甲基）丙烯酸酯基单体和至少一种选自具有聚环氧烷基的乙烯基类单体形成的组 由下式1表示; 其中接枝共聚物包括0.1至5重量％的具有由下式1表示的聚环氧烷基的乙烯基类单体：其中R独立地为氢或C1至C4烷基，n独立地为3至14。

    GRAFT COPOLYMER FOR TRANSPARENT THERMOPLASTIC POLYURETHANE RESIN, PREPARATION METHOD THEREOF, AND POLYURETHANE RESIN COMPOSITION CONTAINING THE SAME
    14.
    发明申请
    GRAFT COPOLYMER FOR TRANSPARENT THERMOPLASTIC POLYURETHANE RESIN, PREPARATION METHOD THEREOF, AND POLYURETHANE RESIN COMPOSITION CONTAINING THE SAME 有权
    用于透明热塑性聚氨酯树脂的聚酰胺共聚物及其制备方法和含有它的聚氨酯树脂组合物

    公开(公告)号：US20100063199A1

    公开(公告)日：2010-03-11

    申请号：US12522021

    申请日：2008-01-04

    Applicant: Yoon-ho Kim ,  Geon-soo Kim ,  Chan-hong Lee ,  Hyung-jin Kim

    Inventor： Yoon-ho Kim ,  Geon-soo Kim ,  Chan-hong Lee ,  Hyung-jin Kim

    IPC: C08L9/10

    CPC classification number: C08F279/02

    Abstract: The present invention relates to a graft copolymer for transparent thermoplastic polyurethane resin, a preparing method thereof and a polyurethane resin composition comprising the same, more precisely a graft copolymer for transparent thermoplastic polyurethane resin prepared by graft copolymerization of (a) 50-85 weight % of rubber latex having multi-layered structure composed of an inner layer and an outer layer comprising a conjugated diene monomer and an ethylenically unsaturated aromatic compound in which the refraction index of the inner layer is greater than that of the outer layer; and (b) 15-50 weight % of a C2-C20 vinyl monomer. The present invention provides a thermoplastic polyurethane resin composition having excellent color properties, calendaring properties, low temperature impact strength and transparency.

    Abstract translation: 本发明涉及一种透明热塑性聚氨酯树脂的接枝共聚物及其制备方法和包含该共聚物的聚氨酯树脂组合物，更准确地说，涉及一种透明热塑性聚氨酯树脂的接枝共聚物，其通过（a）50-85重量％ 的具有多层结构的橡胶胶乳，所述多层结构由内层和包含共轭二烯单体和烯属不饱和芳族化合物的外层组成，其中内层的折射率大于外层的折射率; 和（b）15-50重量％的C 2 -C 20乙烯基单体。 本发明提供具有优异的着色性，压延性，低温冲击强度和透明性的热塑性聚氨酯树脂组合物。

    Method of preparing thermoplastic resin having superior gloss, impact strength and whiteness
    15.
    发明申请
    Method of preparing thermoplastic resin having superior gloss, impact strength and whiteness 有权
    制备具有优异光泽度，冲击强度和白度的热塑性树脂的方法

    公开(公告)号：US20090118393A1

    公开(公告)日：2009-05-07

    申请号：US12290924

    申请日：2008-11-05

    Applicant: Keun-hoon Yoo ,  Chan-hong Lee ,  Jin-hyoung Lee ,  Joo-byung Chai ,  Yu-sung Jung ,  Bong-keun Ahn ,  Won-deok Han

    Inventor： Keun-hoon Yoo ,  Chan-hong Lee ,  Jin-hyoung Lee ,  Joo-byung Chai ,  Yu-sung Jung ,  Bong-keun Ahn ,  Won-deok Han

    IPC: C08L9/10 ,  C08C3/00 ,  C08L51/04

    CPC classification number: C08F279/04 ,  C08F279/02 ,  C08L55/02 ,  C08L2666/02

    Abstract: Disclosed is a method for preparing a thermoplastic resin with superior impact resistance, chemical resistance and processability as well as excellent gloss and whiteness. The method includes emulsion-polymerizing a conjugated diene compound monomer to prepare a rubber latex having an average particle diameter of 1,800 Å to 5,000 Å, a polymerization conversion ratio of at least 90% and a swelling index of 12 to 40, an average gel content of 70 to 95%, emulsion-polymerizing 45 to 75 parts by weight of the rubber latex with 17 to 40 parts by weight of an aromatic vinyl compound and 4 to 20 parts by weight of a vinyl cyanide compound to prepare a graft copolymer latex, and coagulating the graft copolymer latex with a coagulant at 60 to 80° C., and aging the graft copolymer latex at 80 to 99° C. to obtain a graft copolymer powder.

    Abstract translation: 公开了一种制备具有优异的耐冲击性，耐化学性和加工性以及优异的光泽和白度的热塑性树脂的方法。 该方法包括使共轭二烯化合物单体乳液聚合，制备平均粒径为1800至5000的聚合转化率至少为90％，溶胀指数为12至40的橡胶胶乳，平均凝胶含量 70〜95％，乳液聚合45〜75重量份的橡胶胶乳和17〜40重量份的芳香族乙烯基化合物和4〜20重量份的乙烯基氰化合物，制备接枝共聚物胶乳， 并在60至80℃下用凝结剂凝结接枝共聚物胶乳，并在80至99℃下老化接枝共聚物胶乳，得到接枝共聚物粉末。

    METHOD FOR PREPARING GRAFT RUBBER LATEX HAVING LOW RESIDUAL MONOMER CONTENT
    17.
    发明申请
    METHOD FOR PREPARING GRAFT RUBBER LATEX HAVING LOW RESIDUAL MONOMER CONTENT 有权
    用于制备具有低残留单体含量的粗纱橡胶的方法

    公开(公告)号：US20070123657A1

    公开(公告)日：2007-05-31

    申请号：US11538205

    申请日：2006-10-03

    Applicant: Joo-byung CHAI ,  Chan-hong LEE ,  Keun-hoon YOO ,  Jin-hyoung LEE ,  Jae-hwan JUNG

    Inventor： Joo-byung CHAI ,  Chan-hong LEE ,  Keun-hoon YOO ,  Jin-hyoung LEE ,  Jae-hwan JUNG

    IPC: C08F297/02

    CPC classification number: C08F279/02

    Abstract: The present invention relates to a method for preparing a graft rubber latex having a low residual monomer content, and more precisely, a method for preparing a graft rubber latex having a high rubber content, which is characterized by graft-copolymerization of a mixture of a rubber latex having a gel content of at least 95% and an average particle diameter of 2,500˜5000 Å, a monomer mixture comprising one or more compounds selected from a group consisting of aromatic vinyl compound, vinyl cyan compound and acrylate compound, and small particle size latex produced by emulsion polymerization. The method of the present invention has the advantages of speedy processes with excellent latex stability and at the same time reducing residual monomer content in the latex upon completion of the polymerization, improving perceived quality of the product and increasing yield.

    Abstract translation: 本发明涉及一种制备具有低残留单体含量的接枝橡胶胶乳的方法，更确切地说，涉及一种制备橡胶含量高的接枝橡胶胶乳的方法，其特征在于接枝共聚 凝胶含量为至少95％，平均粒径为2,500〜5000的橡胶胶乳，包含一种或多种选自芳族乙烯基化合物，乙烯基氰化合物和丙烯酸酯化合物的化合物的单体混合物和小颗粒 通过乳液聚合生产的胶乳。 本发明的方法具有快速工艺的优点，其具有优异的胶乳稳定性，同时在聚合完成后减少胶乳中的残留单体含量，提高产品的感知质量和提高产率。

    Method of preparation for imide-substituted polymer
    18.
    发明申请
    Method of preparation for imide-substituted polymer 审中-公开
    酰亚胺取代聚合物的制备方法

    公开(公告)号：US20070093638A1

    公开(公告)日：2007-04-26

    申请号：US10559142

    申请日：2004-05-13

    Applicant: Moon-kyoon Chun ,  Chan-hong Lee ,  Joong-jin Han ,  Tae-hoon Kim

    Inventor： Moon-kyoon Chun ,  Chan-hong Lee ,  Joong-jin Han ,  Tae-hoon Kim

    IPC: C08G69/08

    CPC classification number: C08F8/32 ,  C08F8/48 ,  C08F222/08 ,  C08F212/08

    Abstract: The present invention provides a method for manufacturing the imide-substituted polymer comprising the following four consecutive steps of (i) the copolymerization step of copolymerizing aromatic vinyl monomers and unsaturated dicarboxylic anhydride monomers, (ii) the separation step of removing the unreacted monomers and solvents from the abovementioned copolymerized solution continuously supplied to the separator, (iii) the imide substitution step of reacting unsaturated dicarboxylic anhydride units in said copolymers with primary amines, and (iv) the devolatilization step of removing low-molecular-weight volatiles from the polymer solution. The imide-substituted polymer manufactured according to the methods in the present invention has greatly improved the heat resistance and the productivity as the content of aromatic vinyl homopolymers is reduced significantly and the reaction time is shortened extensively.

    Abstract translation: 本发明提供一种制备酰亚胺取代聚合物的方法，包括以下四个连续步骤：（i）共聚芳族乙烯基单体和不饱和二羧酸酐单体的共聚步骤，（ii）除去未反应的单体和溶剂的分离步骤 从上述连续供给到分离器的共聚溶液中，（iii）将所述共聚物中的不饱和二羧酸酐单元与伯胺反应的酰亚胺取代步骤，和（iv）从聚合物溶液中除去低分子量挥发物的脱挥发分步骤 。 根据本发明的方法制备的酰亚胺取代的聚合物随着芳族乙烯基均聚物的含量显着降低并且反应时间被广泛地缩短而大大提高了耐热性和生产率。

    Rubber latex and method for preparing the same
    19.
    发明申请
    Rubber latex and method for preparing the same 审中-公开
    橡胶胶乳及其制备方法

    公开(公告)号：US20070060710A1

    公开(公告)日：2007-03-15

    申请号：US10570714

    申请日：2004-10-29

    Applicant: Ok-yeol Jeong ,  Geon-soo Kim ,  Chan-hong Lee ,  Young-sim Kim

    Inventor： Ok-yeol Jeong ,  Geon-soo Kim ,  Chan-hong Lee ,  Young-sim Kim

    IPC: C08F297/02

    CPC classification number: C08F297/02 ,  C08C1/065 ,  C08F6/18 ,  C08F6/22 ,  C08F257/02 ,  C08F265/04 ,  C08F265/06 ,  C08F279/02 ,  C08F283/12 ,  C08F285/00 ,  C08L23/02 ,  C08L51/003 ,  C08L51/04 ,  C08L51/085 ,  C08L55/02 ,  C08L67/02 ,  C08L69/00 ,  C08L51/00 ,  C08L2666/18 ,  C08L2666/14 ,  C08L2666/02 ,  C08L2666/04 ,  C08L2666/24

    Abstract: Provided are a rubber latex used as a substrate for an impact modifier, a preparation method thereof, and an impact modifier prepared using the rubber latex. The rubber latex includes a rubber monomer as a main component and has a decreasing gel content from a core to a shell(s). The preparation method includes polymerizing a core followed by polymerization of a shell(s) has a lower gel content that the core. The impact modifier is prepared by common graft polymerization using the rubber latex as a substrate. The rubber latex has a high gel content core and a low gel content shell (s), and thus, is free from problems involved in low or high gel content rubber particles. The rubber latex can be used as a substrate for a high efficiency impact modifier with high rubber content and enhanced impact strength and processability.

    Abstract translation: 提供了用作抗冲改性剂的基材的橡胶胶乳，其制备方法和使用橡胶胶乳制备的抗冲改性剂。 橡胶胶乳包括橡胶单体作为主要成分，并且具有从芯到壳的凝胶含量降低。 制备方法包括聚合核心，随后聚合的壳体具有较低的凝胶含量的核心。 抗冲改性剂通过使用橡胶胶乳作为底物的常规接枝聚合制备。 橡胶胶乳具有高凝胶含量的芯和低凝胶含量的壳，因此，不含低或高凝胶含量橡胶颗粒的问题。 橡胶胶乳可以用作具有高橡胶含量和增强的冲击强度和加工性能的高效冲击改性剂的基材。

    Process for preparing thermoplastic resin having superior heat-stability
    20.
    发明授权
    Process for preparing thermoplastic resin having superior heat-stability 有权
    具有优异的热稳定性的制备热塑性树脂的方法

    公开(公告)号：US06774182B2

    公开(公告)日：2004-08-10

    申请号：US10069412

    申请日：2002-02-25

    Applicant: Keun-Hoon Yoo ,  Dong-Sung Kim ,  Chan-Hong Lee

    Inventor： Keun-Hoon Yoo ,  Dong-Sung Kim ,  Chan-Hong Lee

    IPC: C08L5100

    CPC classification number: C08F279/04 ,  C08L55/02 ,  C08L2666/04

    Abstract: The present invention relates to a process for preparing a heat-resistant thermoplastic resin, especially to a process for preparing a heat-resistant thermoplastic resin having superior heat-stability prepared by mixing a graft ABS polymer and a heat-resistant copolymer. The heat resistant thermoplastic resin prepared by the process of the present invention not only has superior heat-resistant properties, impact resistant properties, and workability, but also has superior heat-stability.

    Abstract translation: 本发明涉及一种制备耐热性热塑性树脂的方法，特别涉及通过混合接枝ABS聚合物和耐热共聚物制备的具有优良热稳定性的耐热性热塑性树脂的方法。 通过本发明的方法制备的耐热性热塑性树脂不仅具有优异的耐热性，耐冲击性和加工性，而且具有优异的热稳定性。

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