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    Blends of thermoplastic polymer with a multi-phase acrylic composite polymers
    11.
    发明授权
    Blends of thermoplastic polymer with a multi-phase acrylic composite polymers 失效
    热塑性聚合物与多相丙烯酸复合聚合物的共混物

    公开(公告)号：US4086296A

    公开(公告)日：1978-04-25

    申请号：US532350

    申请日：1974-12-13

    Applicant: Daniel T. Carty ,  James A. Oline

    Inventor： Daniel T. Carty ,  James A. Oline

    IPC: C08F265/04 ,  C08F285/00 ,  C08F291/00 ,  C08L51/00 ,  C08L101/00 ,  C08L77/00 ,  C08F15/00

    CPC classification number: C08F291/00 ,  C08F265/04 ,  C08F285/00 ,  C08L101/00 ,  C08L51/003

    Abstract: Blends of the thermoplastic polymers and a multiphase acrylic composite polymer comprising (A) a first non-crosslinked phase of molecular weight of about 7,500 to 50,000 polymerized from a first monomer emulsion or solution of at least 25 weight percent of at least one alkyl acrylate, wherein said alkyl group has 1 to 18 carbon atoms, 0 to 75 weight percent of another acrylic monomer and 0 to 75 weight percent of another copolymerizable ethylenically unsaturated monomer, and (B) a final rigid thermoplastic phase polymerized in the presence of the first phase from an emulsion or solution of about 35 to 100 weight percent of at least one monomer which is a methacrylate, acrylate, styrene or substituted styrene, 0 to 60 weight percent of another acrylic monomer, and 0 to 65 weight percent of another copolymerizable ethylenically unsaturated monomer, wherein the rigid thermoplastic phase has a molecular weight of from about 400,000 to about 5 .times. 10.sup.6. The polymer is useful as a processing aid and lubricant in a wide variety of plastics.

    Abstract translation: 所述热塑性聚合物和多相丙烯酸类复合聚合物的共混物包含（A）分子量为约7,500至50,000的第一非交联相，其由第一单体乳液或至少25重量％的至少一种丙烯酸烷基酯的溶液聚合， 其中所述烷基具有1至18个碳原子，0至75重量％的另一丙烯酸类单体和0至75重量％的另一个可共聚的烯属不饱和单体，和（B）在第一相存在下聚合的最终刚性热塑性相 从约35至100重量％的至少一种单体，即甲基丙烯酸酯，丙烯酸酯，苯乙烯或取代的苯乙烯，0至60重量％的另一丙烯酸单体和0至65重量％的另一种可共聚的烯属不饱和单体的乳液或溶液 单体，其中刚性热塑性相的分子量为约400,000至约5×10 6。聚合物可用作加工ai d和各种塑料中的润滑剂。

    Vinyl halide polymer impact modifiers
    12.
    发明授权
    Vinyl halide polymer impact modifiers 失效
    氯乙烯卤聚​​合物抗冲改性剂

    公开(公告)号：US3971835A

    公开(公告)日：1976-07-27

    申请号：US494810

    申请日：1974-08-05

    Applicant: Robert M. Myers ,  David L. Dunkelberger ,  Daniel T. Carty

    Inventor： Robert M. Myers ,  David L. Dunkelberger ,  Daniel T. Carty

    IPC: C08F257/02 ,  C08F285/00 ,  C08L27/06 ,  C08L51/00

    CPC classification number: C08F257/02 ,  C08F285/00 ,  C08L27/06 ,  C08L51/00

    Abstract: A three-stage, sequentially produced graft polymer comprises (A) a non-rubbery, hard first stage polymer formed by the sequential polmerization of a monomer charge of 50 to 100 weight percent of a vinylaromatic compound, 0 to 50 weight percent of a different monovinylidene monomer interpolymerizable therewith, and 0 to 10 weight percent of a polyfunctional crosslinking monomer based on the weight of the monomer charge; (B) a second stage rubbery polymer formed by sequentially polymerizing in the presence of the hard polymer Stage (A) a second monomer charge of 50 to 100 weight percent of butadiene, isoprene, chloroprene, an alkyl acrylate or mixtures thereof wherein the alkyl group of the alkyl acrylate has about 3 to 8 carbon atoms, 0 to 50 weight percent of a monovinylidene monomer interpolymerizable therewith, and 0 to 10 weight percent of a polyfunctional cross-linking agent; and (C) a third stage polymer formed by sequentially polymerizing in the presence of the Stage (A) and Stage (B) polymer product a monomer charge of 50 to 100 weight percent of an alkyl methacrylate wherein the alkyl group has about 1 to 4 carbon atoms, 0 to 50 weight percent of a vinylidene monomer interpolymerizable therewith, and 0 to 10 weight percent of a polyfunctional crosslinking monomer, and/or 0 to 1.0 weight percent of an alkyl mercaptan of 3 to 12 carbon atoms. Preferably the polymer is used as a modifier for vinyl halide polymers. When so used, the refractive index of the first two stages of the graft polymer is substantially equal to the refractive index of the vinyl halide polymer.

    Abstract translation: 三阶段顺序生产的接枝聚合物包括（A）通过顺序地将50至100重量百分比的乙烯基芳族化合物的单体电荷和0-50重量％的不同的单体电荷形成的非橡胶状硬质第一阶段聚合物 可与其共聚的单亚乙烯基单体和基于单体电荷重量的0至10重量％的多官能交联单体; （B）第二阶段橡胶质聚合物，其通过在硬质聚合物阶段（A）存在下依次聚合形成，所述第二阶段橡胶状聚合物是具有50至100重量％的丁二烯，异戊二烯，氯丁二烯，丙烯酸烷基酯或其混合物的第二单体进料，其中所述烷基 的丙烯酸烷基酯具有约3至8个碳原子，0至50重量％的可与其共聚的单亚乙烯基单体和0至10重量％的多官能交联剂; 和（C）通过在阶段（A）和阶段（B））聚合物产物的存在下依次聚合形成的第三阶段聚合物，其单体进料为50至100重量％的甲基丙烯酸烷基酯，其中烷基具有约1至4个 0〜50重量％的与其可共聚的亚乙烯基单体和0〜10重量％的多官能交联单体和/或0〜1.0重量％的3〜12个碳原子的烷基硫醇。 优选地，聚合物用作卤化乙烯聚合物的改性剂。 当这样使用时，接枝聚合物的前两个阶段的折射率基本上等于卤乙烯聚合物的折射率。

    Preparation and use of acrylic ionomer elastomers
    17.
    发明授权
    Preparation and use of acrylic ionomer elastomers 失效
    制备和使用丙烯酸离聚物弹性体

    公开(公告)号：US3976723A

    公开(公告)日：1976-08-24

    申请号：US561563

    申请日：1975-03-24

    Applicant: Alan D. Williams ,  John A. Powell ,  Daniel T. Carty ,  James A. Oline

    Inventor： Alan D. Williams ,  John A. Powell ,  Daniel T. Carty ,  James A. Oline

    IPC: C08F8/44 ,  C08L31/02

    CPC classification number: C08F8/44 ,  C08K3/22 ,  Y10S260/31

    Abstract: An alkyl acrylate polymer is cured by condensing carboxyl groups of the polymer with a polyvalent metal oxide to produce polymeric metallo-carboxylates characterized by a three dimensional cross-linked structure. Metallocarboxylates of improved characteristics are produced by neutralizing at least some of the carboxyl groups by reaction with a basic reagent prior to condensation with the polyvalent metal oxide. Preferably the basic reagent is a monovalent metal compound such as potassium hydroxide.

    Abstract translation: 通过将聚合物的羧基与多价金属氧化物缩合以产生以三维交联结构为特征的聚合金属羧酸盐来固化丙烯酸烷基酯聚合物。 通过在与多价金属氧化物缩合之前通过与碱性试剂反应来中和至少一些羧基来制备改进特性的金属羧酸盐。 碱性试剂优选为氢氧化钾等一价金属化合物。

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