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公开(公告)号：US5683585A
公开(公告)日：1997-11-04
申请号：US631911
申请日：1996-04-12
Applicant: Hanswilhelm Bach , Helmut Bahrmann , Jurgen Weber
Inventor： Hanswilhelm Bach , Helmut Bahrmann , Jurgen Weber
CPC classification number: C02F1/26
Abstract: Wastewaters resulting from preparation or use of paints comprising organic solvents are purified by extraction with higher monoalcohols, i.e. alcohols having at least 8 carbon atoms in the molecule.
Abstract translation: 由制备或使用包含有机溶剂的油漆产生的废水通过用分子中具有至少8个碳原子的高级一元醇萃取来纯化。
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公开(公告)号：US4879418A
公开(公告)日：1989-11-07
申请号：US226768
申请日：1988-08-01
Applicant: Hanswilhelm Bach , Helmut Bahrmann , Boy Cornils , Wilhelm Gick , Volker Heim , Werner Konkol , Ernst Wiebus
Inventor： Hanswilhelm Bach , Helmut Bahrmann , Boy Cornils , Wilhelm Gick , Volker Heim , Werner Konkol , Ernst Wiebus
CPC classification number: C07C45/50
Abstract: A process for the preparation of aldehydes including reacting olefins with carbon monoxide and hydrogen in an aqueous liquid phase in the presence of a rhodium catalyst and a specific class of water soluble aryl phosphines. These phosphines are preferably mixtures of alkali metal salts and quaternary ammonium salts of sulfonated aryl phosphines.
Abstract translation: 一种制备醛的方法，包括在铑催化剂和特定类型的水溶性芳基膦存在下，在含水液相中使烯烃与一氧化碳和氢气反应。 这些膦优选为磺化芳基膦的碱金属盐和季铵盐的混合物。
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公开(公告)号：US4808758A
公开(公告)日：1989-02-28
申请号：US125596
申请日：1987-11-25
Applicant: Hanswilhelm Bach , Boy Cornils , Wilhelm Gick , Heinz-Dieter Hahn , Werner Konkol , Ernst Wiebus
Inventor： Hanswilhelm Bach , Boy Cornils , Wilhelm Gick , Heinz-Dieter Hahn , Werner Konkol , Ernst Wiebus
CPC classification number: C07C45/50
Abstract: In a hydroformylation process for the preparation of aldehydes by reacting aliphatic olefins of 2 to 12 carbon atoms with carbon monoxide and hydrogen at temperatures of 20.degree. to 150.degree. C. and pressures of 0.1 to 20 mPa in the liquid phase and in the presence of an aqueous solution of a catalyst containing originally 50 to 800 wt. ppm of rhodium and 25 to 30 wt. % of complex-forming, sulfonated or carboxylated triarylphosphines, in each case based on the aqueous solution, the improvement comprising adding fresh phosphine solution to maintain the original phosphine concentration, until the total concentration of complex-forming phosphines and secondary and degradation products of the phosphines not capable of forming complexes amounts to about 35 to 45 wt. % based on the aqueous solution to selectively form n-aldehydes.
Abstract translation: 在通过使2至12个碳原子的脂族烯烃与一氧化碳和氢气在20至150℃的温度和0.1至20mPa的压力下在液相中以及在 含有最初为50〜800重量％的催化剂的水溶液。 ppm的铑和25〜30wt。 复合物形成，磺化或羧化的三芳基膦的百分比，在每种情况下基于水溶液，改进包括加入新鲜的磷化氢溶液以保持原始的磷化氢浓度，直到络合物形成膦的总浓度和二次和降解产物的总浓度 不能形成络合物的膦为约35〜45wt。 基于水溶液以选择性形成正醛。
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公开(公告)号：US4801754A
公开(公告)日：1989-01-31
申请号：US125595
申请日：1987-11-25
Applicant: Hanswilhelm Bach , Boy Cornils , Wilhelm Gick , Gehard Diekhaus , Werner Konkol , Ernest Wiebus
Inventor： Hanswilhelm Bach , Boy Cornils , Wilhelm Gick , Gehard Diekhaus , Werner Konkol , Ernest Wiebus
CPC classification number: C07C45/50
Abstract: In a hydroformylation process for the preparation of aldehydes by reacting aliphatic olefins of 2 to 12 carbon atoms with carbon monoxide and hydrogen at temperatures of 20.degree. to 150.degree. C. and pressures of 0.1 to 20 mPa in the liquid phase and in the presence of an aqueous solution containing 50 to 800 wt. ppm of rhodium and 25 to 30 wt. % of phosphines, in each case based on the aqueous solution as a catalyst system and in addition the transformation products of the phosphines, the improvement comprising draining off a portion of the aqueous solution of the catalyst system together with the reaction product and replacing the same by fresh aqueous solution of the catalyst system whereby the original catalyst selectivity for formation of n-aldehydes is maintained.
Abstract translation: 在通过使2至12个碳原子的脂族烯烃与一氧化碳和氢气在20至150℃的温度和0.1至20mPa的压力下在液相中以及在 含有50〜800重量％ ppm的铑和25〜30wt。 膦的百分比，在每种情况下基于作为催化剂体系的水溶液，此外，膦的转化产物，改进包括将一部分催化剂体系的水溶液与反应产物一起排出并将其替换 通过新鲜的催化剂体系水溶液，由此维持形成正醛的初始催化剂选择性。
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公开(公告)号：US4593126A
公开(公告)日：1986-06-03
申请号：US719754
申请日：1985-04-04
Applicant: Boy Cornils , Werner Konkol , Hanswilhelm Bach , Georg Dambkes , Wilhelm Gick , Wolfgang Greb , Ernst Wiebus , Helmut Bahrmann
Inventor： Boy Cornils , Werner Konkol , Hanswilhelm Bach , Georg Dambkes , Wilhelm Gick , Wolfgang Greb , Ernst Wiebus , Helmut Bahrmann
CPC classification number: C07C45/50
Abstract: A process for the hydroformylation of aldehydes comprising reacting aliphatic olefins with carbon monoxide and hydrogen in a liquid phase in the presence of water, a rhodium catalyst and a water soluble salt of a sulfonated or carboxylated triarylphosphine, the reaction taking place in the presence of an aqueous phase having a pH of about 5.5 to about 6.2.
Abstract translation: 醛的加氢甲酰化的方法，包括在水，铑催化剂和磺化或羧化的三芳基膦的水溶性盐的存在下，将脂族烯烃与一氧化碳和氢气在液相中反应，该反应在 水相的pH为约5.5至约6.2。
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Patent Agency Ranking
公开(公告)号：US5124485A
公开(公告)日：1992-06-23
申请号：US560021
申请日：1990-07-26
Applicant: Jurgen Weber , Volker Falk , Gerhardt Horn , Hanswilhelm Bach , Klaus Mathieu , Claus Kniep
Inventor： Jurgen Weber , Volker Falk , Gerhardt Horn , Hanswilhelm Bach , Klaus Mathieu , Claus Kniep
IPC: B01J23/75 , B01J23/74 , B01J23/889 , B01J27/232 , C07B61/00 , C07C67/00 , C07C209/00 , C07C209/48 , C07C211/09 , C07C211/10
CPC classification number: B01J27/232 , C07C209/48
Abstract: A method of preparation of a cobalt catalyst particularly adapted for hydrogenation of nitriles, the catalyst which is the product of the method, and the method of use thereof.
Abstract translation: 特别适用于腈的氢化的钴催化剂的制备方法，作为该方法的乘积的催化剂及其使用方法。
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17.发明授权Process for preparing 3(4),8(9)-bis(aminomethyl)-tricyclo[5.2.1.0.sup.2,6 ] d 失效制备3（4），8（9） - 双（氨基甲基） - 三环[5.2.1.02,6]癸烷的方法
公开(公告)号：US5041675A
公开(公告)日：1991-08-20
申请号：US569581
申请日：1990-08-17
Applicant: Rainer Lukas , Klaus Mathieu , Franz Thonnessen , Georg Dambkes , Hanswilhelm Bach
Inventor： Rainer Lukas , Klaus Mathieu , Franz Thonnessen , Georg Dambkes , Hanswilhelm Bach
IPC: B01J31/22 , C07B61/00 , C07C45/00 , C07C45/50 , C07C47/02 , C07C67/00 , C07C209/00 , C07C209/24 , C07C209/26 , C07C211/19
CPC classification number: C07C211/19 , C07C209/26 , C07C2103/68
Abstract: This invention relates to a process for preparing 3(4),8(9)-bis(aminomethyl)tricyclo[5.2.1.0.sup.2,6 ]decane. The starting material for the synthesis of this compound is dicyclopentadiene, which is hydroformylated in the presence of a rhodium compound and subjected to reductive amination without the hydroformylation catalyst being separated from the reaction mixture.
Abstract translation: 本发明涉及制备3（4），（9） - 双（氨基甲基）三环[5.2.1.02,6]癸烷的方法。 用于合成该化合物的起始原料是二环戊二烯，其在铑化合物的存在下被加氢甲酰化，并进行还原胺化，而没有加成甲酰化催化剂与反应混合物分离。
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18.发明授权Process for separating mixtures of substances contained in an aqueous or aqueous/organic solution 失效用于分离水或水/有机溶液中所含物质的混合物的方法
公开(公告)号：US5041228A
公开(公告)日：1991-08-20
申请号：US373097
申请日：1989-06-28
Applicant: W. A. Herrmann , Jurgen Kulpe , Werner Konkol , Hanswilhelm Bach , Wilhelm Gick , Ernst Wiebus , Thomas Muller , Helmut Bahrmann
Inventor： W. A. Herrmann , Jurgen Kulpe , Werner Konkol , Hanswilhelm Bach , Wilhelm Gick , Ernst Wiebus , Thomas Muller , Helmut Bahrmann
CPC classification number: C07F15/008 , B01D15/34 , Y02P20/584
Abstract: Mixtures of substances containing metal complex compounds, organoelemental ligands, and/or other components are separated according to the invention by chromatography on stationary supports in an aqueous or aqueous/organic medium.
Abstract translation: 根据本发明，通过在水性或水/有机介质中的固定载体上的色谱分离含有金属络合物，有机配体和/或其它组分的物质的混合物。
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公开(公告)号：US4684750A
公开(公告)日：1987-08-04
申请号：US900389
申请日：1986-08-26
Applicant: Gunther Kessen , Boy Cornils , Wilhelm Gick , Ernst Wiebus , Joseph Hibbel , Hanswilhelm Bach , Wolfgang Zgorzelski
Inventor： Gunther Kessen , Boy Cornils , Wilhelm Gick , Ernst Wiebus , Joseph Hibbel , Hanswilhelm Bach , Wolfgang Zgorzelski
IPC: C07C29/16 , B01J31/00 , B01J31/24 , C07B61/00 , C07C27/00 , C07C29/141 , C07C29/17 , C07C31/125 , C07C39/02 , C07C45/00 , C07C45/45 , C07C45/50 , C07C45/74 , C07C45/82 , C07C47/02 , C07C47/052 , C07C47/21 , C07C67/00
CPC classification number: C07C45/74 , C07C29/175 , C07C45/50 , C07C45/82
Abstract: A process for the production of 2-ethyl-hexanol comprising reacting propene with carbon monoxide and hydrogen, in the presence of an aqueous catalyst containing rhodium and at least one sulfonated triarylphosphine, to form an aqueous phase and an organic phase, said organic phase comprising a mixture of materials having boiling points lower than that of n-butanal and substances having boiling points equal to or higher than that of n-butanal, said materials including i-butanal, separating said material from said substances, subjecting said substances to aldol condensation, in the presence of aqueous alkali, to form 2-ethyl hexenal, first hydrogenating said 2-ethyl-hexenal in a gas phase in the presence of a first hydrogenation catalyst and thereafter hydrogenating said 2-ethyl-hexenal in a liquid phase to form 2-ethyl-hexanol in the presence of a second hydrogenation catalyst.
Abstract translation: 一种生产2-乙基己醇的方法，包括在含有铑和至少一种磺化三芳基膦的含水催化剂存在下使丙烯与一氧化碳和氢气反应，形成水相和有机相，所述有机相包含 沸点低于正丁醛和沸点等于或高于正丁醛的物质的混合物，所述材料包括异丁醛，将所述物质与所述物质分离，使所述物质进行醛醇缩合 在碱水溶液存在下，形成2-乙基己烯醛，首先在气相中在第一氢化催化剂存在下氢化所述2-乙基己烯，然后在液相中氢化所述2-乙基己烯醛以形成 2-乙基己醇在第二氢化催化剂存在下反应。
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公开(公告)号：US4533755A
公开(公告)日：1985-08-06
申请号：US558788
申请日：1983-12-07
Applicant: Boy Cornils , Josef Hibbel , Gunther Kessen , Werner Konkol , Bernhard Lieder , Ernst Wiebus , Heinz Kalbfell , Hanswilhelm Bach
Inventor： Boy Cornils , Josef Hibbel , Gunther Kessen , Werner Konkol , Bernhard Lieder , Ernst Wiebus , Heinz Kalbfell , Hanswilhelm Bach
CPC classification number: C07C45/50
Abstract: A process for the hydroformylation of olefins having 2 to 5 carbon atoms using rhodium catalysts in a low pressure process, wherein the waste gas from the low pressure plant containing the olefin is compressed and used in a high pressure plant.
Abstract translation: 在低压方法中使用铑催化剂加氢甲酰化具有2至5个碳原子的烯烃的方法，其中来自含有烯烃的低压装置的废气被压缩并用于高压设备中。
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