公开(公告)号：US07608226B2

公开(公告)日：2009-10-27

申请号：US12053876

申请日：2008-03-24

Applicant: Teresa Grocela Rocha ,  Alison Liana Palmatier ,  Jonathan Lloyd Male ,  John Dewey Blouch ,  Benjamin Rue Wood ,  Frederic Vitse

Inventor： Teresa Grocela Rocha ,  Alison Liana Palmatier ,  Jonathan Lloyd Male ,  John Dewey Blouch ,  Benjamin Rue Wood ,  Frederic Vitse

IPC: B01D53/56 ,  B01D53/74

CPC classification number: B01D53/9409 ,  B01D2251/208 ,  F01N3/2066 ,  F01N2610/03 ,  F01N2610/10 ,  F02C3/30 ,  F05D2270/082 ,  Y02T10/24

Abstract: A method comprises injecting a reductant stream comprising a hydrocarbon reductant and water into an exhaust chamber comprising a nitrogen oxide-containing exhaust stream; contacting a composition comprising the reductant stream and exhaust stream with a catalyst; and decreasing a concentration of the nitrogen oxide in the composition comprising the reductant stream and exhaust stream. An exhaust stream treatment system, comprises an exhaust chamber comprising a catalyst; an exhaust stream comprising a nitrogen oxide; and a reductant stream comprising a hydrocarbon reductant and water.

Abstract translation: 一种方法包括将包含烃还原剂和水的还原剂流注入包含含氮氧化物的废气流的排气室中; 使包含还原剂流和排气流的组合物与催化剂接触; 并且降低包含还原剂流和排气流的组合物中的氮氧化物的浓度。 排气流处理系统包括：包括催化剂的排气室; 包含氮氧化物的排气流; 以及包含烃还原剂和水的还原剂流。

公开(公告)号：US07431905B2

公开(公告)日：2008-10-07

申请号：US11242655

申请日：2005-10-04

Applicant: Dan Hancu ,  Jonathan Lloyd Male ,  Jennifer Kathleen Redline ,  Stanlee Teresa Buddle ,  Teresa Grocela Rocha ,  Alison Liana Palmatier ,  Benjamin Rue Wood ,  Job Thomas Rijssenbeek

Inventor： Dan Hancu ,  Jonathan Lloyd Male ,  Jennifer Kathleen Redline ,  Stanlee Teresa Buddle ,  Teresa Grocela Rocha ,  Alison Liana Palmatier ,  Benjamin Rue Wood ,  Job Thomas Rijssenbeek

IPC: B01D53/56 ,  B01D53/94 ,  B01J8/00 ,  B01J19/00

CPC classification number: B01D53/8628 ,  B01D53/9477 ,  B01J23/10 ,  B01J23/34 ,  B01J23/62 ,  B01J23/83 ,  B01J23/888 ,  B01J23/8892 ,  B01J35/0006

Abstract: A catalyst system for the reduction of NOx. is provided. The system comprises a catalyst in a first zone comprising a catalyst support, a catalytic metal comprising gallium, and at least one promoting metal selected from the group consisting of silver, gold, vanadium, zinc, tin, bismuth, cobalt, molybdenum, tungsten, indium and mixtures thereof; a catalyst in the second zone comprising a second catalyst support, a second catalytic metal selected from the group consisting of indium, copper, manganese, tungsten, molybdenum, titanium, vanadium, iron, cerium and mixtures thereof The catalyst system further comprises a gas stream comprising an organic reductant. The catalyst system may further comprise a catalyst in a third zone; the catalyst comprising a third catalyst support and a third catalytic metal selected from the group consisting of platinum, palladium, and mixtures thereof. A method for reducing NOx utilizing the catalyst system is also provided.

Abstract translation: 用于还原NOx的催化剂体系。 被提供。 该系统包括在包含催化剂载体，包含镓的催化金属和至少一种选自银，金，钒，锌，锡，铋，钴，钼，钨， 铟及其混合物; 第二区中的催化剂，包括第二催化剂载体，选自铟，铜，锰，钨，钼，钛，钒，铁，铈及其混合物的第二催化剂金属。催化剂体系还包含气流 包括有机还原剂。 催化剂体系还可以包括在第三区中的催化剂; 所述催化剂包含第三催化剂载体和选自铂，钯及其混合物的第三催化金属。 还提供了一种利用催化剂体系还原NOx的方法。

公开(公告)号：US07361321B2

公开(公告)日：2008-04-22

申请号：US11178555

申请日：2005-07-11

Applicant: Teresa Grocela Rocha ,  Alison Liana Palmatier ,  Jonathan Lloyd Male ,  John Dewey Blouch ,  Benjamin Roe Wood ,  Frederic Vitse

Inventor： Teresa Grocela Rocha ,  Alison Liana Palmatier ,  Jonathan Lloyd Male ,  John Dewey Blouch ,  Benjamin Roe Wood ,  Frederic Vitse

IPC: B01D53/56

CPC classification number: B01D53/9409 ,  B01D2251/208 ,  F01N3/2066 ,  F01N2610/03 ,  F01N2610/10 ,  F02C3/30 ,  F05D2270/082 ,  Y02T10/24

Abstract: A method comprises injecting a reductant stream comprising a hydrocarbon reductant and water into an exhaust chamber comprising a nitrogen oxide-containing exhaust stream; contacting a composition comprising the reductant stream and exhaust stream with a catalyst; and decreasing a concentration of the nitrogen oxide in the composition comprising the reductant stream and exhaust stream. An exhaust stream treatment system, comprises an exhaust chamber comprising a catalyst; an exhaust stream comprising a nitrogen oxide; and a reductant stream comprising a hydrocarbon reductant and water.

Abstract translation: 一种方法包括将包含烃还原剂和水的还原剂流注入包含含氮氧化物的废气流的排气室中; 使包含还原剂流和排气流的组合物与催化剂接触; 并且降低包含还原剂流和排气流的组合物中的氮氧化物的浓度。 排气流处理系统包括：包括催化剂的排气室; 包含氮氧化物的排气流; 以及包含烃还原剂和水的还原剂流。

公开(公告)号：US06982356B2

公开(公告)日：2006-01-03

申请号：US10664093

申请日：2003-09-17

Applicant: Eric James Pressman ,  Jonathan Lloyd Male ,  Ryan Christopher Mills ,  John Yaw Ofori

Inventor： Eric James Pressman ,  Jonathan Lloyd Male ,  Ryan Christopher Mills ,  John Yaw Ofori

IPC: C07C39/24

CPC classification number: B01J31/2234 ,  B01J23/72 ,  B01J27/122 ,  B01J31/28 ,  B01J31/34 ,  B01J31/4015 ,  B01J31/403 ,  B01J38/48 ,  B01J2231/4277 ,  B01J2231/52 ,  B01J2531/16 ,  B01J2531/46 ,  B01J2531/56 ,  C07C37/00 ,  C07C37/62 ,  C07C37/68 ,  C07C37/72 ,  Y02P20/582 ,  Y02P20/584 ,  C07C39/27

Abstract: A method for preparing hydroxyaromatic compounds brominated in the para-position, such as p-bromophenol, is disclosed. The method yields overall high process selectivity through isomeric equilibration and separation of the brominated products, thereby eliminating the need for high para selectivity in the products of catalytic oxybromination reactions of hydroxyaromatic compounds using oxygen, a bromine source, and an acidic medium in the presence of a metal catalyst. Furthermore, the invention provides an efficient method for recycling the metal catalyst, as well as reagents used in the bromination, to further reactions.

Abstract translation: 公开了一种制备在对位溴化的羟基芳族化合物的方法，例如对溴苯酚。 该方法通过异构平衡和溴化产物的分离产生总体高的工艺选择性，从而消除了在存在有氧，溴源和酸性介质的情况下，使用氧，芳族化合物和酸性介质的羟基芳族化合物的催化氧溴化反应的产物中对高选择性的需要 金属催化剂。 此外，本发明提供了将金属催化剂以及用于溴化的试剂再循环到进一步反应的有效方法。