Single ion conductor-containing composite polymer electrolyte for lithium secondary battery and method of manufacturing the same
    11.
    发明授权
    Single ion conductor-containing composite polymer electrolyte for lithium secondary battery and method of manufacturing the same 有权
    用于锂二次电池的单离子导体复合聚合物电解质及其制造方法

    公开(公告)号:US07211352B2

    公开(公告)日:2007-05-01

    申请号:US10750152

    申请日:2003-12-30

    Abstract: Provided are a composite polymer electrolyte for a lithium secondary battery that includes a composite polymer matrix structure having a single ion conductor-containing polymer matrix to enhance ionic conductivity and a method of manufacturing the same. The composite polymer electrolyte includes a first polymer matrix made of a first porous polymer with a first pore size; a second polymer matrix made of a single ion conductor, an inorganic material, and a second porous polymer with a second pore size smaller than the first pore size. The second polymer matrix is coated on a surface of the first polymer matrix. The composite polymer matrix structure can increase mechanical properties. The single ion conductor-containing porous polymer matrix of a submicro-scale can enhance ionic conductivity and the charge/discharge cycle stability.

    Abstract translation: 提供一种用于锂二次电池的复合聚合物电解质,其包括具有单离子导体的聚合物基质以提高离子导电性的复合聚合物基体结构及其制造方法。 复合聚合物电解质包括由具有第一孔径的第一多孔聚合物制成的第一聚合物基体; 由单一离子导体制成的第二聚合物基体,无机材料和具有小于第一孔径的第二孔径的第二多孔聚合物。 将第二聚合物基质涂覆在第一聚合物基质的表面上。 复合聚合物基体结构可增加机械性能。 具有亚微米级的单离子导体多孔聚合物基质可以提高离子电导率和充放电循环的稳定性。

    Anode for lithium metal polymer secondary battery comprising surface patterned anodic current collector and method of preparing the same
    14.
    发明授权
    Anode for lithium metal polymer secondary battery comprising surface patterned anodic current collector and method of preparing the same 失效
    包含表面图案化阳极集电器的锂金属聚合物二次电池用阳极及其制备方法

    公开(公告)号:US07427455B2

    公开(公告)日:2008-09-23

    申请号:US11231238

    申请日:2005-09-19

    Abstract: There are provided an anode for a lithium metal polymer secondary battery comprising an anodic current collector having a surface on which a plurality of recesses having a predetermined shape are formed and a method of preparing the same. The plurality of recesses are formed on a surface of the anodic current collector using a physical method or a chemical method. In a lithium metal polymer secondary battery employing the anode, oxidation/reduction of lithium and the formation of dendrite occur only in the recesses formed by surface patterning of the anodic current collector. Thus, expanding and shrinking of a battery due to a change in the thickness of the lithium anode can be prevented and cycling stability and the lifespan of a battery can be improved.

    Abstract translation: 提供了一种用于锂金属聚合物二次电池的阳极,其包括具有其上形成有多个具有预定形状的凹部的表面的阳极集电器及其制备方法。 使用物理方法或化学方法在阳极集电体的表面上形成多个凹部。 在使用阳极的锂金属聚合物二次电池中,锂的氧化/还原和枝晶的形成仅发生在通过阳极集电体的表面图案形成的凹部中。 因此,可以防止由于锂阳极的厚度变化引起的电池的膨胀和收缩,并且可以提高电池的循环稳定性和寿命。

    Lithium cationic single-ion conducting filler-containing composite polymer electrolyte for lithium secondary battery and method of manufacturing the same
    15.
    发明授权
    Lithium cationic single-ion conducting filler-containing composite polymer electrolyte for lithium secondary battery and method of manufacturing the same 有权
    锂二次电池用锂阳离子单离子导电填料复合聚合物电解质及其制造方法

    公开(公告)号:US07399556B2

    公开(公告)日:2008-07-15

    申请号:US11097730

    申请日:2005-04-01

    Abstract: Provided are a composite polymer electrolyte for a lithium secondary battery in which a composite polymer matrix multi-layer structure composed of a plurality of polymer matrices with different pore sizes is impregnated with an electrolyte solution, and a method of manufacturing the same. Among the polymer matrices, a microporous polymer matrix with a smaller pore size contains a lithium cationic single-ion conducting inorganic filler, thereby enhancing ionic conductivity, the distribution uniformity of the impregnated electrolyte solution, and maintenance characteristics. The microporous polymer matrix containing the lithium cationic single-ion conducting inorganic filler is coated on a surface of a porous polymer matrix to form the composite polymer matrix multi-layer structure, which is then impregnated with the electrolyte solution, to manufacture the composite polymer electrolyte. The composite polymer electrolyte is used in a unit battery. The composite polymer matrix structure can increase mechanical properties. The introduction of the lithium cationic single-ion conducting inorganic filler can provide excellent ionic conductivity and high rate discharge characteristics.

    Abstract translation: 本发明提供一种锂二次电池用复合高分子电解质及其制造方法,其中将由多个不同孔径的聚合物基体组成的复合聚合物基体多层结构浸渍在电解质溶液中。 在聚合物基质中,具有较小孔径的微孔聚合物基质包含阳离子单离子导电无机填料,从而提高离子电导率,浸渍电解质溶液的分布均匀性和维护特性。 将含有阳离子单离子导电无机填料的微孔聚合物基体涂覆在多孔聚合物基质的表面上以形成复合聚合物基质多层结构,然后用电解质溶液浸渍,制备复合聚合物电解质 。 复合聚合物电解质用于单位电池。 复合聚合物基体结构可增加机械性能。 引入锂阳离子单离子导电无机填料可以提供优异的离子导电性和高速率放电特性。

    MULTI-LAYERED POLYMER PACKAGE FOR FILM BATTERY AND COMBINED PACKAGE AND CURRENT COLLECTOR
    16.
    发明申请
    MULTI-LAYERED POLYMER PACKAGE FOR FILM BATTERY AND COMBINED PACKAGE AND CURRENT COLLECTOR 审中-公开
    多层聚合物包装用于电池和组合包装和电流收集器

    公开(公告)号:US20080118830A1

    公开(公告)日:2008-05-22

    申请号:US11861350

    申请日:2007-09-26

    Abstract: Provided are a multi-layered polymer package for a film battery and a combined package and current collector. The polymer package for the film battery and the combined package and current collector include a multi-layered polymer film having a construction of at least three layers, which includes a first polymer film, a second polymer film, and a third polymer film, the first, second, and third polymer films being made of different materials. The first polymer film is made of a hydrocarbon compound which is unsubstituted or substituted by a fluorine (F) atom. The second polymer film is made of an amorphous polymer. The third polymer film is made of a polymer having a tensile strength of a predetermined value or more and a tensile modulus of a predetermined value or more. In the combined package and current collector, a conductive layer is disposed on a surface of the multi-layered polymer film.

    Abstract translation: 提供了一种用于膜电池和组合封装和集电器的多层聚合物封装。 用于薄膜电池和组合封装和集电器的聚合物封装包括具有至少三层结构的多层聚合物膜,其包括第一聚合物膜,第二聚合物膜和第三聚合物膜,第一聚合物膜 ,第二和第三聚合物膜由不同的材料制成。 第一聚合物膜由未被取代或被氟(F)原子取代的烃化合物制成。 第二聚合物膜由无定形聚合物制成。 第三聚合物膜由具有预定值以上的拉伸强度和规定值以上的拉伸弹性模量的聚合物构成。 在组合封装和集电器中,在多层聚合物膜的表面上设置导电层。

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