COMPOSITE GRAPHITE PARTICLES AND LITHIUM RECHARGEABLE BATTERY USING THE SAME
    16.
    发明申请
    COMPOSITE GRAPHITE PARTICLES AND LITHIUM RECHARGEABLE BATTERY USING THE SAME 有权
    使用相同的复合石墨颗粒和锂可充电电池

    公开(公告)号:US20090202917A1

    公开(公告)日:2009-08-13

    申请号:US12097001

    申请日:2006-12-20

    摘要: The invention provides composite graphite particles, comprising a core material consisting of graphite having a interlayer distance d(002) of 0.337 nm or less and a surface layer consisting of graphite in which the intensity ratio ID/IG (R value) between the peak intensities (ID) in a range of 1300 to 1400 cm−1 and ( IG) in a range of 1580 to 1620 cm−1 as measured by Raman scattering spectroscopy is 0.3 or higher, wherein the peak intensity ratio I110/I004 between the peak intensities (I110)of face (110) and (I004)of face (004) obtained by XRD measurement on the graphite crystal is 0.15 or higher when the graphite has been mixed with a binder and pressure-molded to a density of 1.55 to 1.65 g/cm3, which composite graphite particles are useful in a secondary battery negative electrode having a high capacity, high charge/discharge characteristics and an excellent charging property, and also provides a paste for negative electrode, a negative electrode and a lithium secondary battery using the composite graphite.

    摘要翻译: 本发明提供复合石墨颗粒,其包含由石墨构成的芯材,其中层间距离d(002)为0.337nm或更小,以及由石墨组成的表面层,其中峰强度之间的强度比ID / IG(R值) 通过拉曼散射光谱法测定的范围为1300〜1400cm -1的范围((IG))为1580〜1620cm -1的范围(IG)为0.3以上,峰强度之间的峰强度比I110 / I004 当将石墨与粘合剂混合并加压成型为1.55至1.65克的密度时,在石墨晶体上通过XRD测量获得的面(004)的面(110)和(I004)的(I110)为0.15以上 / cm3,该复合石墨颗粒可用于具有高容量,高充电/放电特性和优异的充电性能的二次电池负极中,并且还提供负极,负极和锂二次电池用途的糊 g复合石墨。

    Method for producing composite material for electrode comprising quinoxaline based polymer, such material, electrode and battery using the same
    20.
    发明授权
    Method for producing composite material for electrode comprising quinoxaline based polymer, such material, electrode and battery using the same 失效
    包括喹喔啉基聚合物的电极复合材料的制造方法,这种材料,电极和使用其的电池

    公开(公告)号:US07226695B2

    公开(公告)日:2007-06-05

    申请号:US10479486

    申请日:2002-06-11

    IPC分类号: H01M4/02

    摘要: The present invention relates to a method for producing a polymer/conductive carbon composite electrode comprising dehydration condensation polymerization of a tetramine derivative and a tetracarbonyl compound in the presence of an electrically conductive carbon material. The synthetized polymer comprises quinoxaline structural units such as polyphenyl quinoxaline (PPQ) and serves as an active material having proton conductivity. The composite material for electrode obtained by the method has a large capacity of inserting/releasing a proton and excellent in durability. An electrode comprising the composite material and a secondary battery comprising the electrode is excellent in safety and reliability high-speed current characteristics, has a longer life and a larger gravimetric energy density (Wh/kg).

    摘要翻译: 本发明涉及一种聚合物/导电性碳复合电极的制造方法,其特征在于,在导电性碳材料的存在下,包括四胺衍生物和四羰基化合物的脱水缩聚。 合成的聚合物包括喹喔啉结构单元如聚苯基喹喔啉(PPQ),并且用作具有质子传导性的活性材料。 通过该方法获得的电极用复合材料具有大的插入/释放质子的能力,并且耐久性优异。 包含复合材料的电极和包含电极的二次电池具有优异的安全性和可靠性的高速电流特性,具有更长的寿命和更大的重量能量密度(Wh / kg)。