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11.发明授权Polyisocyanurate-based polyoxazolidone polymers and process for their preparation 失效聚异氰脲酸酯基聚恶唑烷酮聚合物及其制备方法
公开(公告)号：US4658007A
公开(公告)日：1987-04-14
申请号：US731253
申请日：1985-05-07
CPC分类号： C08G18/003
摘要： This invention is an improvement in a process by which a polyepoxide and a polyisocyanate are reacted to form an oxazolidone containing polymer or polymer precursor. This improvement comprises conducting said reaction in the presence of a catalytic amount of an organoantimony iodide catalyst. In such improved process, the oxazolidone forming reaction proceeds much more rapidly than the trimerization reaction of the polyisocyanate or the homopolymerization of the polyepoxide. As a result, the product polymer or polymer precursor contains a surprisingly small proportion of isocyanurates. In addition, the overall rate of reaction is substantially increased as compared to that achieved with conventional catalysts, thereby reducing the time and stringency of conditions required to form the desired product.
摘要翻译： 本发明是使多环氧化物和多异氰酸酯反应以形成含有恶唑烷酮的聚合物或聚合物前体的方法的改进。 该改进包括在催化量的有机锑碘化物催化剂的存在下进行所述反应。 在这种改进的方法中，恶唑烷酮形成反应比多异氰酸酯的三聚反应进行得更快，或者聚环氧化物的均聚。 结果，产物聚合物或聚合物前体含有惊人的小比例的异氰脲酸酯。 此外，与用常规催化剂相比，总体反应速率显着增加，从而减少形成所需产物所需的条件的时间和严格性。
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公开(公告)号：US20140213755A1
公开(公告)日：2014-07-31
申请号：US14240987
申请日：2012-09-05
申请人： Maurice J. Marks , Gyongyi Gulyas
发明人： Maurice J. Marks , Gyongyi Gulyas
IPC分类号： C08G59/24
CPC分类号： C08G59/245 , C08G59/066 , C08G59/184 , C08L63/00
摘要： An epoxy-functional resin composition including the reaction product of (a) a stoichiometric excess of at least one divinylarene dioxide, and (b) at least one of: a primary (1°) monoamine, a bis-secondary (2°) amine lacking nitrogen atoms, or mixtures thereof; a curable composition including (i) the epoxy-functional resin composition, and (ii) at least one curing agent; and a cured thermoset resin prepared from the curable composition.
摘要翻译： 一种环氧官能树脂组合物，其包含（a）化学计量过量的至少一种二乙烯基芳烃二氧化物的反应产物和（b）至少一种：伯（1）单胺，双仲（2））胺 缺少氮原子或其混合物; 可固化组合物，其包含（i）环氧官能树脂组合物和（ii）至少一种固化剂; 和由可固化组合物制备的固化的热固性树脂。
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13.发明授权Intercalation agent free compositions useful to make nanocomposite polymers 失效可用于制备纳米复合材料聚合物的嵌入剂自由组合物公开(公告)号：US08481616B2
公开(公告)日：2013-07-09
申请号：US13351004
申请日：2012-01-16
申请人： Luyi Sun , Jae Woong Boo , Hung-jue Sue , Maurice J. Marks , Richard F. Fibiger , Michael S. Paquette
发明人： Luyi Sun , Jae Woong Boo , Hung-jue Sue , Maurice J. Marks , Richard F. Fibiger , Michael S. Paquette
CPC分类号： C08J3/2053 , B82Y30/00 , C08J5/005 , C08J2363/00 , Y10S977/778 , Y10S977/779 , Y10S977/783 , Y10S977/785 , Y10S977/786 , Y10S977/787
摘要： A two step method for preparing a filler composition, the filler composition useful to prepare a nanocomposite polymer and an epoxy nanocomposite coating. First, disperse a water dispersible filler material in a liquid comprising water, but without any added intercalation agent, to form a dispersion. Second, replace at least a portion of the water of the liquid with an organic solvent so that the water concentration of the liquid is less than six percent by weight to form the filler composition, the average size of at least one dimension of the filler material being less than two hundred nanometers upon examination by transmission electron microscopy of a representative freeze dried sample of the dispersion of the first step. A nanocomposite polymer can be prepared by mixing the filler composition with one or more polymer, polymer component, monomer or prepolymer to produce a polymer containing the filler composition.
摘要翻译： 用于制备填料组合物的两步法，用于制备纳米复合聚合物和环氧纳米复合涂层的填料组合物。 首先，将水分散性填料分散在包含水的液体中，但不加任何添加的嵌入剂，以形成分散体。 第二，用有机溶剂代替液体的至少一部分水，使得液体的水浓度小于6重量％以形成填料组合物，填料的至少一个维度的平均尺寸 通过透射电子显微镜检查第一步的分散体的代表性冷冻干燥样品，小于二百纳米。 可以通过将填料组合物与一种或多种聚合物，聚合物组分，单体或预聚物混合以制备含有填料组合物的聚合物来制备纳米复合聚合物。
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公开(公告)号：US20130005899A1
公开(公告)日：2013-01-03
申请号：US13576062
申请日：2011-02-10
申请人： Maurice J. Marks
发明人： Maurice J. Marks
IPC分类号： C08F301/00 , C09D199/00
CPC分类号： C08G59/245 , C08G59/621
摘要： A curable divinylarene dioxide resin composition including (a) at least one divinylarene dioxide, and (b) at least one diphenol curing agent; a process for making the curable divinylarene dioxide resin composition; and a cured divinylarene dioxide resin composition made therefrom. The cured product made from the above curable divinylarene dioxide resin composition offers improved properties such as lower viscosity and a high heat resistance compared to known cured products prepared from known epoxy resins.
摘要翻译： 一种可固化的二乙烯基芳烃二氧化物树脂组合物，其包含（a）至少一种二乙烯基芳烃二氧化物，和（b）至少一种二酚固化剂; 制造可固化二乙烯基芳烃二氧化物树脂组合物的方法; 和由其制成的固化二乙烯基芳烃二氧化物树脂组合物。 由上述可固化的二乙烯基芳烃二氧化物树脂组合物制成的固化产物与已知的已知的环氧树脂制备的已知固化产物相比具有较低的粘度和较高的耐热性能。
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公开(公告)号：US20120214958A1
公开(公告)日：2012-08-23
申请号：US13498709
申请日：2010-10-15
申请人： Maurice J. Marks
发明人： Maurice J. Marks
IPC分类号： C08G59/02
CPC分类号： C08G59/02 , C08G18/003 , C08G59/26 , C08G59/28
摘要： An epoxy oxazolidone including the reaction product of (a) a divinylarene dioxide, and (b) an excess of a polyisocyanate to provide an epoxy oxazolidone composition; wherein the composition has an oxazolidone selectivity of greater than 40% relative to the total of the carbonyl compounds; a process for making the epoxy oxazolidone; and a curable epoxy resin composition including (i) the epoxy oxazolidone derived from a divinylarene dioxide such as divinylbenzene dioxide (DVBDO) and a polyisocyanate, (ii) at least one curing agent; and/or (iii) a catalyst. The cured product made from the above epoxy resin composition is thermally stable and offers improved properties such as a lower viscosity and a high heat resistance compared to known cured products prepared from known epoxy resins.
摘要翻译： 包括（a）二乙烯基芳烃二氧化物的反应产物和（b）过量的多异氰酸酯的环氧恶唑烷酮，以提供环氧恶唑烷酮组合物; 其中所述组合物相对于羰基化合物的总量具有大于40％的恶唑烷酮选择性; 制备环氧恶唑烷酮的方法; 和可固化的环氧树脂组合物，其包含（i）衍生自二乙烯基芳烃二氧化物的环氧恶唑烷酮如二乙烯基二氧化物（DVBDO）和多异氰酸酯，（ii）至少一种固化剂; 和/或（iii）催化剂。 由上述环氧树脂组合物制成的固化产物与已知的已知环氧树脂制备的已知固化产物相比，是热稳定的，具有较低的粘度和较高的耐热性能。
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16.发明申请公开(公告)号：US20120010330A1
公开(公告)日：2012-01-12
申请号：US13254180
申请日：2010-02-16
CPC分类号： C08G59/56 , C08G59/621 , C08L63/00
摘要： A curable composition including (a) at least one cyclic diamine, (b) at least one non-heterocyclic amine that has a pKa value of approximately 9.5 to about 12 at 25° C. for the most basic amine group in the non-heterocyclic amine molecule, (c) at least one epoxy resin, and (d) at least one alkylated phenol; (i) wherein the equivalents of the amine hydrogens from the cyclic diamine compared to the total amine hydrogens from both the cyclic diamine and the non-heterocyclic amine in the composition are greater than about 5%; (ii) wherein the ratio of the equivalents of the total amine hydrogens in the composition to the equivalents of the total epoxies in the composition is greater than or equal to about 1; and (iii) wherein the alkylated phenol is in an amount greater than about 10 wt % of the curable composition.
摘要翻译： 一种可固化组合物，其包含（a）至少一种环状二胺，（b）至少一种在25℃下对于非杂环中最碱性的胺基具有约9.5至约12的pKa值的非杂环胺 胺分子，（c）至少一种环氧树脂，和（d）至少一种烷基化苯酚; （i）其中来自环二胺的胺氢的当量与组合物中来自环二胺和非杂环胺的总胺氢相比大于约5％; （ii）其中组合物中总胺氢的当量与组合物中总环氧化物的当量的比例大于或等于约1; 和（iii）其中烷基化苯酚的量大于可固化组合物的约10重量％。
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17.发明申请HYDROXYL-TERMINATED OR CARBOXYLIC ACID-TERMINATED REACTIVE MONOMER COMPOSITIONS, THEIR PREPARATION AND THEIR USE 审中-公开羟基封端或羧酸终止反应单体组合物，其制备及其使用公开(公告)号：US20100041794A1
公开(公告)日：2010-02-18
申请号：US12522638
申请日：2007-12-11
CPC分类号： C09D5/03 , C07C67/31 , C07C235/08 , C07C235/28 , C11C3/00 , C07C69/675
摘要： The present invention relates to new reactive monomer compositions that have a plurality of reactive, functional moieties, such as one or both of a hydroxyl moiety or a carboxylic acid moiety. The present invention also further relates to use of such reactive monomer compositions as a component of curable coating compositions, especially curable powder coating compositions.
摘要翻译： 本发明涉及具有多个反应性功能部分，例如羟基部分或羧酸部分中的一个或两个的新的反应性单体组合物。 本发明还涉及这种反应性单体组合物作为可固化涂料组合物的组分，特别是可固化的粉末涂料组合物的用途。
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公开(公告)号：US09695272B2
公开(公告)日：2017-07-04
申请号：US13169358
申请日：2011-06-27
IPC分类号： C08G59/22 , C08G59/24 , C08G59/68 , C08G65/18 , C09D11/101 , C09D11/322
CPC分类号： C08G59/22 , C08G59/245 , C08G59/68 , C08G65/18 , C09D11/101 , C09D11/322
摘要： A curable divinylarene dioxide resin composition including (a) at least one divinylarene dioxide, (b) at least one cationic photoinitiator, and (c) optionally, at least one pigment material; a process for making the curable divinylarene dioxide resin composition; and a cured divinylarene dioxide resin composition made therefrom. The cured product made from the above curable divinylarene dioxide resin composition offers improved properties and are useful for various applications including ink formulations.
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公开(公告)号：US09550748B2
公开(公告)日：2017-01-24
申请号：US14237185
申请日：2012-07-19
IPC分类号： C07D317/36 , C08G71/04 , C07D317/40
CPC分类号： C07D317/36 , C07D317/40 , C08G71/04
摘要： A cyclic carbonate monomer including the reaction product of (a) a divinylarene dioxide, and (b) carbon dioxide; a process for making the cyclic carbonate monomer; and a polymer such as a poly(hydroxyurethane) composition made therefrom. The poly(hydroxyurethane) composition made from the above cyclic carbonate monomer forms a reactive intermediate that can be used for making, for example, a poly(hydroxyurethane) foam product.
摘要翻译： 包含（a）二乙烯基芳烃二氧化物和（b）二氧化碳的反应产物的环状碳酸酯单体; 制备环状碳酸酯单体的方法; 和由其制成的聚（羟基氨基甲酸酯）组合物的聚合物。 由上述环状碳酸酯单体制成的聚（羟基氨基甲酸酯）组合物形成可用于制备例如聚（羟基氨基甲酸酯）泡沫产品的反应性中间体。
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公开(公告)号：US20160024336A1
公开(公告)日：2016-01-28
申请号：US14857215
申请日：2015-10-12
IPC分类号： C09D163/00 , C09D165/00
CPC分类号： C09D163/00 , B32B27/38 , C08G18/003 , C08G59/027 , C08G59/1438 , C08G59/245 , C08G2150/20 , C08G2650/56 , C08L63/00 , C09D165/00 , C09D171/00
摘要： A solid epoxy resin powder coarting composition which includes a divinylarene dioxide resin as one component; and wherein the solid epoxy resin powder coating composition can be formed by blending or reacting various other components with the divinylarene dioxide resin. For example, other components can include other epoxy resins; phenolic resins; or monomeric and/or polymeric isocyanates. The powder coating composition or formulation may advantageously provide, for example, a Fusion Bonded Epoxy coating on a substrate.
摘要翻译： 一种固体环氧树脂粉末共聚组合物，其包含二乙烯基芳烃二氧化物树脂作为一种组分; 并且其中固体环氧树脂粉末涂料组合物可以通过使各种其它组分与二乙烯基芳烃二氧化物树脂共混或反应而形成。 例如，其它组分可以包括其它环氧树脂; 酚醛树脂; 或单体和/或聚合异氰酸酯。 粉末涂料组合物或制剂可以有利地提供例如在基材上的熔融粘合环氧涂层。
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