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    Solid organic electrolytes
    12.
    发明授权
    Solid organic electrolytes 有权

    公开(公告)号：US10297394B2

    公开(公告)日：2019-05-21

    申请号：US15075953

    申请日：2016-03-21

    申请人： Sitaraman Krishnan ,  Lalitha Ganapatibhotla ,  Dipankar Roy ,  Jianping Zheng

    发明人： Sitaraman Krishnan ,  Lalitha Ganapatibhotla ,  Dipankar Roy ,  Jianping Zheng

    IPC分类号： H01G9/20 ,  H01G11/56 ,  H01G11/58 ,  H01G11/62 ,  H01L51/00 ,  H01M10/0525 ,  H01M10/0564 ,  H01M10/0565 ,  H01M10/0566

    摘要： Solid, or highly viscous, organic electrolytes consisting of alkylimidazolium cation with alkyl, PEGylated and fluorinated side chains of different molecular weights were synthesized and characterized (cf. chemical structures in Schemes 1 and 2). The PEGylated/fluorinated imidazolium iodide is a solid organic electrolyte that has a conductivity of about 2×10−5 S/cm at 30° C. The ionic conductivity could be significantly increased (1.11×10−4 S/cm at 30° C. and S/cm at 2.88×10−3 at 90° C.) by blending the PEGylated/fluorinated imidazolium iodide with another solid electrolyte, 1-ethyl-3-methylimidazolium iodide (EtMImI). The PEGylated imidazolium iodides synthesized in the present work have conductivities in the range 1.6×10−4 S/cm to 2×10−4 S/cm at 30° C. and viscosities in the range 620 cP to 720 cP at 30° C. The iodide counter ion in the present electrolytes supplies the anion for the I−/I3− redox mediators for DSSCs. Therefore, the organic electrolytes of the present invention can be used even without the addition of inorganic salts such as LiI or KI. We found that the addition of an organic solid electrolyte, EtMImI, resulted in an increase in the ionic conductivity of the PEGylated/fluorinated imidazolium iodides, whereas the addition of the inorganic LiI led to a decrease in ionic conductivity. All the electrolytes are thermally stable until high temperatures (250° C. to 300° C.).

    Electrically conducting thin films and methods of making same
    16.
    发明授权
    Electrically conducting thin films and methods of making same 有权
    导电薄膜及其制造方法

    公开(公告)号：US08945429B2

    公开(公告)日：2015-02-03

    申请号：US13444354

    申请日：2012-04-11

    申请人： Stephan DeLuca ,  Sitaraman Krishnan

    发明人： Stephan DeLuca ,  Sitaraman Krishnan

    IPC分类号： H01B1/12

    CPC分类号： H01L51/0034 ,  C08F8/00 ,  C08F38/02 ,  C08G2261/126 ,  C08G2261/3327 ,  C08G2261/418 ,  C08G2261/75 ,  C08G2261/80 ,  C08J5/18 ,  G02B5/3033 ,  H01B1/12 ,  H01B1/125 ,  H01L51/0043 ,  H01L51/0097 ,  H01L51/42 ,  H01L51/441 ,  Y02E10/549

    摘要： The present invention relates conductive nanostructured copolymer materials, such as thin film. In particular, the nanostructured copolymer material comprises plurality of chains substantially parallel to each other, each conductive chain comprising a plurality of conductive polyacetylene polymer blocks positioned along the chain and a plurality of polar poly(vinyl alcohol) polymer blocks in between the polyacetylene polymer blocks to form a pattern of alternatively repeating polyacetylene polymer blocks and poly(vinyl alcohol) polymer blocks and a ratio of polyacetylene polymer to poly(vinyl alcohol) polymer to provide the nanostructured copolymer material with conductivity of at least 1 S/cm. In some aspects, the invention relates to photoelectric devices comprising a nanostructured copolymer material and capable to convert light to electrical current.

    摘要翻译： 本发明涉及导电纳米结构共聚物材料，如薄膜。 特别地，纳米结构共聚物材料包括基本上彼此平行的多个链，每个导电链包括沿链条定位的多个导电聚乙炔聚合物嵌段和在聚乙炔聚合物嵌段之间的多个极性聚（乙烯醇）聚合物嵌段 形成交替重复的聚乙炔聚合物嵌段和聚（乙烯醇）聚合物嵌段的图案以及聚乙炔聚合物与聚（乙烯醇）聚合物的比例，以提供导电率至少为1S / cm的纳米结构共聚物材料。 在一些方面，本发明涉及包含纳米结构共聚物材料并能够将光转换成电流的光电器件。