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    Amorphous, iron promoted Mo and W sulfide hydroprocessing catalysts and process for their preparation
    12.
    发明授权
    Amorphous, iron promoted Mo and W sulfide hydroprocessing catalysts and process for their preparation 失效
    无定形，铁促进的Mo和W硫化物加氢催化剂及其制备方法

    公开(公告)号：US4820677A

    公开(公告)日：1989-04-11

    申请号：US687536

    申请日：1984-12-28

    申请人： Allan J. Jacobson ,  Teh C. Ho ,  Russell R. Chianelli ,  Theresa Pecoraro

    发明人： Allan J. Jacobson ,  Teh C. Ho ,  Russell R. Chianelli ,  Theresa Pecoraro

    IPC分类号： B01J27/049 ,  B01J27/051 ,  C10G45/08

    CPC分类号： C10G45/08 ,  B01J27/049 ,  B01J27/0515

    摘要： Hydrocarbon feeds are upgraded by contacting a feed, at elevated temperature and in the presence of hydrogen, with a catalyst comprising an amorphous sulfide of iron and a metal selected from the group consisting of Mo, W and mixture thereof. The catalysts are prepared by heating one or more catalyst precursor salts under oxygen-free conditions in the presence of sulfur at a temperature of at least about 250.degree. C. The precursor salts will contain a thiometallate anion of Mo, W or mixture thereof and a cation comprising iron as a promoter metal and, optionally, additional divalent promoter metals, wherein said promoter metal or metals are chelated by at least one neutral, nitrogen-containing polydentate ligand and wherein said additional promoter metal is selected from the group consisting of Ni, Co, Mn, Zn, Cu and mixture thereof.

    摘要翻译： 通过在升高的温度和在氢的存在下使进料接触的催化剂与包含铁的无定形硫化物和选自Mo，W及其混合物的金属的催化剂进行升级。 催化剂是通过在至少约250℃的温度下在硫的存在下在无氧条件下加热一种或多种催化剂前体盐来制备的。前体盐将含有Mo，W或其混合物的硫代金属阴离子和 包含铁作为助催化剂金属的阳离子和任选的另外的二价助催化剂金属，其中所述促进剂金属或金属由至少一种中性含氮多齿配体螯合，并且其中所述另外的助催化剂金属选自Ni， Co，Mn，Zn，Cu及其混合物。

    Amorphous sulfide catalysts of trivalent chromium and promoter metals and method of making same
    13.
    发明授权
    Amorphous sulfide catalysts of trivalent chromium and promoter metals and method of making same 失效
    三价铬和助催化剂金属的无定形硫化物催化剂及其制备方法

    公开(公告)号：US4716139A

    公开(公告)日：1987-12-29

    申请号：US846219

    申请日：1986-03-31

    申请人： Allan J. Jacobson ,  Teh C. Ho ,  Russell R. Chianelli ,  John J. Steger ,  Angelo A. Montagna

    发明人： Allan J. Jacobson ,  Teh C. Ho ,  Russell R. Chianelli ,  John J. Steger ,  Angelo A. Montagna

    IPC分类号： B01J27/047 ,  C10G49/04 ,  B01J31/00 ,  B01J27/049 ,  B01J27/051

    CPC分类号： B01J27/047 ,  C10G49/04

    摘要： A catalyst composition comprising an amorphous sulfide of trivalent chromium and at least one metal selected from the group consisting of (a) molybdenum, tungsten and mixture thereof and (b) mixtures of (a) with Fe, Ni, Co, Mn, Cu, Zn and mixture thereof is prepared by heating one or more precursors at a temperature of at least about 200.degree. C. under oxygen-free conditions in the presence of a sulfur, wherein said precursor is selected from the group consisting of [Cr.sub.1-z M.sub.z LX.sub.y ](MoS.sub.4).sub.n, [Cr.sub.1-z M.sub.z LX.sub.y ](WS.sub.4).sub.n and mixtures thereof, wherein M is one or more divalent promoter metals selected from the group consisting of Mn, Fe, Co, Ni, Cu, Zn and mixtures thereof, wherein L is one or more neutral nitrogen-containing ligands, wherein ligand X is a singly-charged anionic species and wherein 1>z.gtoreq.0, 1-z.gtoreq.y.gtoreq.0, and wherein n equals (3-z-y)/2. These compositions have been found to be good hydroprocessing catalysts, particularly hydrotreating catalysts exhibiting a very high hydrodenitrogenation activity and/or selectivity in nitrogen and sulfur-containing hydrocarbon feeds.

    摘要翻译： 一种催化剂组合物，其包含三价铬的无定形硫化物和选自（a）钼，钨及其混合物的至少一种金属和（b）（a）与Fe，Ni，Co，Mn，Cu， Zn及其混合物通过在无硫条件下在硫存在下在至少约200℃的温度下加热一种或多种前体而制备，其中所述前体选自[Cr1-zMzLXy] （MoS4）n，[Cr1-zMzLXy]（WS4）n及其混合物，其中M是一种或多种选自Mn，Fe，Co，Ni，Cu，Zn的二价助催化剂金属及其混合物，其中L 是一种或多种中性含氮配体，其中配体X是单电荷阴离子物质，并且其中n等于（3-zy） ）/ 2。 已经发现这些组合物是良好的加氢处理催化剂，特别是在含氮和含硫烃进料中表现出非常高的加氢脱氮活性和/或选择性的加氢处理催化剂。

    Supported chromium-molybdenum and tungsten sulfide catalysts
    14.
    发明授权
    Supported chromium-molybdenum and tungsten sulfide catalysts 失效
    支持铬钼和硫化钨催化剂

    公开(公告)号：US4626339A

    公开(公告)日：1986-12-02

    申请号：US656090

    申请日：1984-09-28

    申请人： Russell R. Chianelli ,  Teh C. Ho ,  Allan J. Jacobson ,  Archie R. Young

    发明人： Russell R. Chianelli ,  Teh C. Ho ,  Allan J. Jacobson ,  Archie R. Young

    IPC分类号： C10G45/04 ,  B01J27/047 ,  B01J31/22 ,  B01J37/20 ,  C10G45/08 ,  C10G49/04 ,  C10G71/00

    CPC分类号： C10G49/04 ,  B01J27/047 ,  B01J37/20

    摘要： Supported hydroprocessing catalysts comprising a sulfide of trivalent chromium and molybdenum or tungsten which optionally may contain one or more promotor metals such as Co, Fe, Ni and mixture thereof. These catalysts are obtained by comprising a preselected quantity of support material with a precursor salt containing a tetrathiometallate anion of Mo or W and a cation comprising trivalent chromium and, optionally, one or more promoter metals wherein both said trivalent chromium and promoter metal are chelated by at least one neutral, nitrogen-containing polydentate ligand and heating the composite in the presence of sulfur and hydrogen in an oxygen-free atmosphere. These catalysts have high selectivity for nitrogen removal. The chromium and promoter metal do not have to be in the same cation.

    摘要翻译： 包括三价铬硫化物和钼或钨的负载型加氢处理催化剂，其任选地可以含有一种或多种助催化剂金属如Co，Fe，Ni及其混合物。 这些催化剂通过包含预选量的载体材料而获得，其前体盐含有Mo或W的四金属硫酸盐阴离子和包含三价铬的阳离子，以及任选的一种或多种助催化剂金属，其中所述三价铬和助催化剂金属都被 至少一种中性的含氮多齿配体，并在无氧气氛中在硫和氢的存在下加热复合物。 这些催化剂对脱氮具有高选择性。 铬和助催化剂金属不必在同一阳离子中。

    Stacked bed catalyst system for deep hydrodesulfurization
    19.
    发明授权
    Stacked bed catalyst system for deep hydrodesulfurization 失效
    用于深加氢脱硫的堆叠床催化剂体系

    公开(公告)号：US5474670A

    公开(公告)日：1995-12-12

    申请号：US245181

    申请日：1994-05-17

    申请人： Michel Daage ,  Teh C. Ho ,  Kenneth L. Riley

    发明人： Michel Daage ,  Teh C. Ho ,  Kenneth L. Riley

    IPC分类号： B01J27/045 ,  B01J27/047 ,  C10G45/08 ,  C10G45/10 ,  C10G65/04 ,  C10G45/04

    CPC分类号： C10G65/04 ,  B01J27/045

    摘要： The present invention relates to a method of removing sulfur from a hydrotreating process stream comprising contacting a sulfur containing feedstock with a stacked bed catalyst system comprising a first catalyst bed comprising hydrodesulfurization catalysts followed by a second catalyst bed comprising ruthenium sulfide having a surface area of at least about 30 m.sup.2 /g and wherein said hydrodesulfurization process is conducted at a temperature of about 150.degree. C. to about 400.degree. C. and a pressure of about 50 psig (344.74 kPa) to about 2500 psig (17236.89 kPa).

    摘要翻译： 本发明涉及一种从加氢处理工艺流中除去硫的方法，包括使含硫原料与堆叠床催化剂体系接触，所述堆叠床催化剂体系包含第一催化剂床，所述第一催化剂床包含加氢脱硫催化剂，随后是第二催化剂床，所述第二催化剂床包含表面积为 至少约30m 2 / g，并且其中所述加氢脱硫方法在约150℃至约400℃的温度和约50psig（344.74kPa）至约2500psig（17236.89kPa）的压力下进行。

    Hydrotreating process with mixed catalysts
    20.
    发明授权
    Hydrotreating process with mixed catalysts 失效
    加氢处理工艺与混合催化剂

    公开(公告)号：US4973397A

    公开(公告)日：1990-11-27

    申请号：US214996

    申请日：1988-07-05

    申请人： Teh C. Ho

    发明人： Teh C. Ho

    IPC分类号： B01J31/16 ,  B01J31/18 ,  B01J37/04 ,  C10G45/04 ,  C10G45/08

    CPC分类号： B01J31/1616 ,  B01J31/1805 ,  B01J37/04 ,  C10G45/04 ,  C10G45/08 ,  B01J2531/16 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847

    摘要： Disclosed is a process for hydrotreating a hydrocarbonaceous feed wherein the feed is contacted in a mixed catalyst bed at a temperature of about 200.degree. C. to 450.degree. C., in the presence of hydrogne, which catalyst bed is comprised of: (a0 one or more catalysts comprised of at least one metal selected from Group VIB and at lease one metal selected from Group VIII of the Periodic Table of the Elements, on an inorganic oxide support material; and (b) one or more catlayst represented by MM'.sub.a S.sub.x where M is Cr or one or more divalent promoter metals selected from Mn, Fe, Co, Ni, Cu and Zn; M' is one or both of MO and W; x is 0.5 to 9, and a=1 when Cr is not one of metals represented by M, and 0.5.ltoreq.a.ltoreq.3 when Cr is one of the metals represented by M.

    摘要翻译： 公开了一种加氢处理含烃原料的方法，其中在约200℃至450℃的温度下，在液体存在下，在混合催化剂床中将进料接触，该催化剂床由以下组成：（a0一 或更多的催化剂，其由选自VIB族的至少一种金属和至少一种选自元素周期表第Ⅷ族的金属组成，在无机氧化物载体材料上;以及（b）一种或多种由MM'aSx 其中M是Cr或选自Mn，Fe，Co，Ni，Cu和Zn中的一种或多种二价助催化剂金属; M'是MO和W之一或两者; x是0.5至9，当Cr不是时，a = 1 当M是由M表示的金属之一，当Cr是由M表示的金属之一时，0.5≤a≤3。