Abstract:
The present disclosure relates membrane-electrode assemblies and electrochemical cells and liquid flow batteries produced therefrom. The membrane-electrode assemblies include a first porous electrode; an ion permeable membrane, having a first major surface and an opposed second major surface; a first discontinuous transport protection layer disposed between the first porous electrode and the first major surface of the ion permeable membrane; and a first adhesive layer in contact with the first porous electrode and at least one of the first discontinuous transport protection layer and the ion permeable membrane. The first adhesive layer is disposed along the perimeter of the membrane-electrode assembly. The first porous electrode and first discontinuous transport protection layer, without the presence of the first adhesive layer, are not an integral structure and the membrane-electrode assembly is an integral structure
Abstract:
The present disclosure relates to membrane assemblies, electrode assemblies and membrane-electrode assemblies; and electrochemical cells and liquid flow batteries produced therefrom. The disclosure further provides methods of making the membrane assemblies, electrode assemblies and membrane-electrode assemblies. The membrane assemblies includes an ion exchange membrane and at least one microporous protection layer. The electrode assemblies includes a porous electrode and a microporous protection layer. The membrane-electrode assembly includes an ion exchange membrane, at least one microporous protection layer and at least one porous electrode. The microporous protection layer includes a resin and at least one of an electrically conductive particulate and a non-electrically conductive particulate. The ratio of the weight of the resin to total weight of particulate is from about 1/99 to about 10/1. The resin may be at least one of an ionic resin and a non-ionic resin.
Abstract:
The present disclosure relates to porous electrodes, membrane-electrode assemblies, electrode assemblies and electro-chemical cells and liquid flow batteries produced therefrom. The disclosure further provides methods of making porous electrodes, membrane-electrode assemblies and electrode assemblies. The porous electrodes include a porous electrode material comprising a non-electrically conductive, polymer particulate; and an electrically conductive carbon particulate; wherein the electrically conductive carbon particulate is at least one of carbon nanotubes and branched carbon nanotubes. The electrically conductive carbon particulate is adhered directly to the surface of the non-electrically conductive, polymer particulate and at least a portion of the non-electrically conductive polymer particulate surface is fused to form a unitary, porous electrode material.
Abstract:
Catalyst comprising an Ir layer having an outer layer with a layer comprising Pt directly thereon, wherein the Ir layer has an average thickness in a range from 0.04 to 30 nanometers, wherein the layer comprising Pt has an average thickness in a range from 0.04 to 50 nanometers, and wherein the Pt and Ir are present in an atomic ratio in a range from 0.01:1 to 10:1. Catalysts described herein are useful, for example, in fuel cell membrane electrode assemblies.
Abstract:
Nanoporous oxygen reduction catalyst material comprising at least 90 collectively Pt, Ni, and Ta. The nanoporous oxygen reduction catalyst material is useful, for example, in fuel cell membrane electrode assemblies.
Abstract:
The present disclosure relates to porous electrodes, membrane-electrode assemblies, electrode assemblies and electrochemical cells and liquid flow batteries produced therefrom. The disclosure further provides methods of making porous electrodes, membrane-electrode assemblies and electrode assemblies. The porous electrodes include a porous electrode material comprising a polymer and an electrically conductive carbon particulate; and a solid film substrate having a first major surface and a second major surface, wherein the solid film substrate includes a plurality of through holes extending from the first major surface to the second major surface. The porous electrode material is disposed on at least the first major surface and within the plurality of through holes of the solid film substrate. The plurality of through holes with the porous electrode material provide electrical communication between the first major surface and the opposed second major surface of the porous electrode.
Abstract:
Membrane electrode assembly comprising oxygen evolution reaction catalyst disposed in gas distribution layer (100, 700) or between gas distribution layer (100, 700 and gas dispersion layer (200, 600). Membrane electrode assemblies described herein are useful, for example, in electrochemical devices such as a fuel cell.
Abstract:
Gas permeable layers in fuel cell membrane electrode assemblies are provided which comprises a mixture of first and second types of carbon particles, which may provide relatively hydrophilic and relatively hydrophobic pathways. In some embodiments, the first type of carbon particle oxidizes at a lower rate than said second type of carbon particle. In some embodiments, the first type of carbon particle is graphitized and the second type of carbon particle is not graphitized.
Abstract:
Polymer electrolyte membrane fuel cell membrane electrode assemblies are provided having multilayer cathodes, where a first layer of the cathode which is more proximate to the polymer electrolyte membrane is more hydrophilic than a second more distal layer of the cathode. In some embodiments, the first layer includes a polymer electrolyte having a lower equivalent weight than a polymer electrolyte included in the second layer.
Abstract:
Described herein is a coating composition comprising: (a) a metal catalyst, wherein the metal catalyst comprises at least one of platinum, ruthenium, iridium, and alloys and combinations thereof; (b) an at least highly fluorinated ionomer comprising a polymer backbone and a plurality of first side chains pendant therefrom, wherein the first side chain comprises at least one protogenic group, wherein the protogenic group is selected from a sulfonic acid, a bis(sulfonyl)imide, a sulfonamide, a sulfonyl methide, and salts and combinations thereof, and wherein the polymer backbone comprises an average of at least 14 carbon atoms between adjacent first side chains along the polymer backbone; and (c) a solvent. Such coating compositions may be used to make electrodes for electrochemical cells and have been shown to have reduced poisoning of the catalyst.