公开(公告)号：US20160039959A1

公开(公告)日：2016-02-11

申请号：US14918245

申请日：2015-10-20

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Harald Kaspar ,  Ludwig Mayer ,  Tilman C. Zipplies

IPC: C08F214/26 ,  C09D127/18

CPC classification number: C08F214/262 ,  C08F16/24 ,  C09D127/18 ,  C08F2/16

Abstract: Provided are a tetrafluoroethylene copolymers having a melting point of at least 317° C., a melt flow index (MFI) at 372° C. and a 5 kg load (MFI 372/5) of from about 0.60 g/10 min up to about 15 g/10 min. Also provided are methods of forming a shaped article using the copolymers described above, shaped articles made with those copolymers and compositions containing such copolymers.

公开(公告)号：US20140094564A1

公开(公告)日：2014-04-03

申请号：US14032912

申请日：2013-09-20

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Kai H. Lochhaas ,  Michael Jürgens ,  Harald Kaspar ,  Tilman C. Zipplies ,  André Streiter

IPC: C08K5/19

CPC classification number: C08K5/19 ,  C08F2/24 ,  C08F14/18 ,  C08F214/18 ,  C08K5/095 ,  C08F2/16 ,  C08L27/12

Abstract: There is provided an article prepared from a fluoroelastomer, the fluoroelastomer being derived from an emulsion, the emulsion comprising a fluorinated emulsifier represented by the formula F—(CF2)t—[O(CF2)n]m—O—(CHF)o—(CF2)p—X.

Abstract translation: 提供由含氟弹性体制备的制品，所述含氟弹性体衍生自乳液，所述乳液包含由式F-（CF 2）t- [O（CF 2）n] m -O-（CHF）o表示的氟化乳化剂 - （CF2）p-X。

公开(公告)号：US08633328B2

公开(公告)日：2014-01-21

申请号：US13862905

申请日：2013-04-15

Applicant: 3M Innovative Properties Company

Inventor： Tilman C. Zipplies ,  Klaus Hintzer ,  Oleg Shyshkov

IPC: C07C247/04 ,  C07C255/13 ,  C07C253/14 ,  C07C51/08

CPC classification number: C07C255/13 ,  C07C51/08 ,  C07C59/135 ,  C07C67/08 ,  C07C69/708 ,  C07C247/04 ,  C07C253/14

Abstract: Provided are saturated partially fluorinated alkoxy carboxylic acids or salts thereof and methods of preparation.

Abstract translation: 提供的是饱和部分氟化的烷氧基羧酸或其盐及其制备方法。

公开(公告)号：US20210189031A1

公开(公告)日：2021-06-24

申请号：US16756261

申请日：2018-10-23

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Harald Kaspar ,  Kai Helmut Lochhaas ,  Jens Schrooten ,  Helmut Traunspurger ,  Tilman C. Zipplies

IPC: C08F214/26

Abstract: Described herein is a fluorothermoplast with long chain branching and a method of making such a polymer using a modifier of the formula: F2C═CF(CF2)a(O)RfH wherein a is 0 or 1 and Rf is a linear or branched fluorinated alkylene group comprising 1 to 5 carbon atoms and optionally comprising at least one ether linkage and optionally comprising 1 or 2 hydrogen atoms. This fluorothermoplast may be processed through polymer melt processes, such as blow molding, injection molding, film extrusion, and wire extrusion. Preferably, said polymer contains structural units derived from tetrafluoroethylene and a perfluorinated olefin or ether, and comprises chain branching.

公开(公告)号：US20210155790A1

公开(公告)日：2021-05-27

申请号：US16970233

申请日：2019-02-15

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Harald Kaspar ,  Jens Schrooten ,  Tilman C. Zipplies ,  Florian Jochum ,  Michael C. Dadalas ,  Tatsuo Fukushi ,  Naiyong Jing ,  Karl D. Weilandt

IPC: C08L27/18 ,  C08L27/20 ,  C08F216/14 ,  C08F2/22 ,  C08K3/04

Abstract: A tetrafluoroethene copolymer having a melting point of from about 240° C. to 325° C., a melt flow index (MFI at 372° C. and 5 kg load) of 0.5-80 grams/10 minutes and having at least 70% by weight of units derived from tetrafluoroethene and further comprising units derived from at least one perfluorinated alkyl allyl ether (PAAE) comonomer corresponding to the general formula: CF2═CF—CF2—O—Rf (I) where Rf is a perfluorinated alkyl residue having from 1 to 10 carbon atoms and wherein the alkyl chain of the residue may be interrupted once or more than once by an oxygen atom and further, optionally, comprising units derived from perfluoromethyl vinyl ether (PMVE), perfluoroethyl vinyl ether (PEVE) and a combination thereof and wherein the content of units CA derived PAAEs and, optionally, PMVE, PEVE or a combination thereof, is at least 1.0% by weight.

公开(公告)号：US20200303755A1

公开(公告)日：2020-09-24

申请号：US16646638

申请日：2018-09-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Lisa P. Chen ,  Gregg D. Dahlke ,  Denis Duchesne ,  Steven J. Hamrock ,  Klaus Hintzer ,  Markus E. Hirschberg ,  Arne Thaler ,  Tilman C. Zipplies

IPC: H01M8/1039 ,  C08F214/26 ,  H01M4/86 ,  H01M8/1004 ,  H01M8/1023

Abstract: The copolymer includes divalent units represented by formula —[CF2-CF2]—, divalent units represented by formula: (I), and one or more divalent units independently represented by formula: (II) When Z is hydrogen, the copolymer has an alpha transition temperature of up to 100 ?C. The copolymer has an —SO3Z equivalent weight in a range from 300 to 1400, and a variation of the copolymer in which —SO3Z is replaced with —SO2F has a melt flow index of up to 80 grams per ten minutes measured at a temperature of 265° C. and at a support weight of 5 kg. A catalyst ink or polymer electrolyte membrane including the copolymer are also provided.

公开(公告)号：US10730980B2

公开(公告)日：2020-08-04

申请号：US15550324

申请日：2016-02-12

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Denis Duchesne ,  Klaus Hintzer ,  Harald Kaspar ,  Kai H. Lochhaas ,  Per M. Nelson ,  Jens C. Schrooten ,  Karl D. Weilandt ,  Tilman C. Zipplies

IPC: C08F214/28 ,  C08F8/22 ,  C08F214/26 ,  H01B3/44

Abstract: A copolymer having tetrafluoroethylene units, hexafluoropropylene units, and units independently represented by formula in a range from 0.02 to 2 mole percent, based on the total amount of the copolymer. Rf is a linear or branched perfluoroalkyl group having from 1 to 8 carbon atoms and optionally interrupted by one or more —O— groups, z is 1 or 2, each n is independently from 1 to 6, and m is 0 or 1. The copolymer has a melt flow index in a range from 25 grams per 10 minutes to 35 grams per 10 minutes and has a combined number of unstable end groups and —CF2H end groups in a range from 25 per 106 carbon atoms up to 120 per 106 carbon atoms. The copolymer can be extruded to make articles, such as insulated cables. A method of making the copolymer is also disclosed.

公开(公告)号：US10717795B2

公开(公告)日：2020-07-21

申请号：US15550314

申请日：2016-02-12

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Denis Duchesne ,  Klaus Hintzer ,  Harald Kaspar ,  Kai H. Lochhaas ,  Jens Schrooten ,  Tilman C. Zipplies

IPC: C08F214/26 ,  C08K5/42 ,  C08J9/00 ,  H01B3/44 ,  H01B7/02

Abstract: A copolymer having tetrafluoroethylene units, hexafluoropropylene units, and units independently represented by formula in a range from 0.001 to 2 mole percent, based on the total amount of the copolymer. In these units, a is 0 or 1, each b is independently from 1 to 4, c is 0 to 4, d is 0 or 1, and e is 1 to 6. In the —SO2X groups, X is independently —F, —NH2, —OH, or —OZ, wherein Z is independently a metallic cation or a quaternary ammonium cation. The copolymer has a melt flow index in a range from 20 grams per 10 minutes to 40 grams per 10 minutes. The copolymer can be extruded to make articles, such as insulated cables. A method of making the copolymer is also disclosed.

公开(公告)号：US20200055971A1

公开(公告)日：2020-02-20

申请号：US16346145

申请日：2017-11-03

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Florian D. Jochum ,  Harald Kaspar ,  Kai H. Lochhaas ,  Tilman C. Zipplies

IPC: C08F214/22 ,  C08F214/26 ,  C08F214/28 ,  C08F214/18

Abstract: Described herein is a peroxide curable, partially fluorinated polymer derived from: (a) comonomers comprising: (i) 5-28 wt. % of tetrafluoroethylene; (ii) 30-70 wt. % of vinylidene fluoride; and (iii) a monomer selected from 10-45 wt. % of hexafluoropropylene and 10-40 wt, % of a perfluoro ether monomer of the formula Rf-0-(CF2)n—CF═CF2 wherein n is 1 or 0, and Rf represents a perfluoroalkyl residue which may or may not be interrupted by one or more than one oxygen atoms; (b) 0.01-2 wt % of a perfluorinated iodinated vinyl ether based on the total amount of comonomer, wherein the perfluorinated iodinated vinyl ether has the formula: F2C═CF—(CF2)m(0)o—(CF2)n—O—(CF2)p—I where m is 0 or 1; n is an integer of 0-5: o is 0 or 1: and p is an integer of 1-5, wherein when n is 0, o is 0; and (c) 0.01-2 wt % of a chain transfer agent based on the total amount of comonomers wherein the chain transfer agent consists of a diiodo-fluoroalkane and a diiodo-methane. Further described are methods of making the curable partially fluorinated polymers and articles comprising the cured fluoropolymer.

公开(公告)号：US20190202951A1

公开(公告)日：2019-07-04

申请号：US16325831

申请日：2017-08-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Harald Kaspar ,  Klaus Hintzer ,  Markus E. Hirschberg ,  Herbert Koenigsmann ,  Karl D. Weilandt ,  Tilman C. Zipplies

IPC: C08F214/26 ,  C08F214/28 ,  C08L27/18 ,  C08L27/20 ,  H01B3/44

CPC classification number: C08F214/262 ,  C08F214/26 ,  C08F214/28 ,  C08L27/18 ,  C08L27/20 ,  C08L2203/16 ,  C08L2203/18 ,  H01B3/445

Abstract: A copolymer having tetrafluoroethylene units and second polymerized monomer units in a range from 0.2 to 1 percent by weight, based on the total weight of the copolymer. Rf is a linear or branched perfluoroalkyl group having from 1 to 8 carbon atoms and optionally interrupted by one or more —O— groups, n is independently from 1 to 6, and z is 0, 1, or 2. The copolymer has a melt flow index in a range from 0.02 grams per 10 minutes to 19.4 grams per 10 minutes. The copolymer can be extruded to make articles, such as insulated cables. A method of making the copolymer is also disclosed.