公开(公告)号：US20160122495A1

公开(公告)日：2016-05-05

申请号：US14992250

申请日：2016-01-11

Applicant: Arkema Inc.

Inventor： Benjamin Bin CHEN ,  Philippe BONNET ,  Brett L. VAN HORN ,  Joseph S. COSTA

IPC: C08J9/14 ,  C08G18/06

CPC classification number: C08J9/144 ,  C08G18/06 ,  C08G18/4018 ,  C08G18/482 ,  C08G18/6674 ,  C08G18/7664 ,  C08G2101/00 ,  C08J9/146 ,  C08J9/149 ,  C08J2203/142 ,  C08J2203/162 ,  C08J2203/182 ,  C08J2375/04

Abstract: A blowing agent for thermosetting foams is disclosed. The blowing agent is predominately the trans isomer of the hydrochlorofluoroolefin (HCFO) HFCO-1233zd alone or in combination with a hydrofluoroolefin (HFO), hydrofluorocarbon (HFC), hydrochlorofluoroolefin (HCFO), a hydrocarbon. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.

公开(公告)号：US20150038603A1

公开(公告)日：2015-02-05

申请号：US14519456

申请日：2014-10-21

Applicant: Arkema Inc.

Inventor： Brett L. VAN HORN ,  Maher Y. ELSHEIKH ,  Benjamin Bin CHEN ,  Philippe BONNET

IPC: C08J9/14

CPC classification number: C08J9/144 ,  C08J9/122 ,  C08J9/127 ,  C08J9/141 ,  C08J9/146 ,  C08J9/149 ,  C08J2201/03 ,  C08J2203/06 ,  C08J2203/14 ,  C08J2203/162 ,  C08J2203/182 ,  C08J2203/202 ,  C08J2205/052 ,  C08J2323/06 ,  C08J2323/12 ,  C08J2325/06

Abstract: The present invention relates to foam products made with blowing agent compositions comprising at least one hydrochlorofluoroolefin (HCFO) used in the preparation of foamable thermoplastic compositions. The HCFOs of the present invention include, but are not limited to, 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd), particularly the trans-isomer, 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), dichloro-fluorinated propenes, and mixtures thereof. The blowing agent compositions of the present invention are used with coblowing agents including carbon dioxide, atmospheric gases, hydrofluorocarbons (HFC), hydrofluoroolefins (HFO), alkanes, hydrofluoroethers (HFE), and mixtures thereof. Preferred HFCs used as coblowing agents in the present invention include, but are not limited too, 1,1,1,2-tetrafluoroethane (HFC-134a), 1,1-difluoroethane (HFC-152a), 1,1,1-trifluoroethane (HFC-143a), pentafluorethane (HFC-125), difluoromethane (HFC-32). The blowing agent compositions are useful in the production of low density insulating foams with improved k-factor.

Abstract translation: 本发明涉及由用于制备可发泡热塑性组合物的至少一种氢氯氟烯烃（HCFO）的发泡剂组合物制成的泡沫产品。 本发明的HCFO包括但不限于1-氯-3,3,3-三氟丙烯（HCFO-1233zd），特别是反式异构体2-氯-3,3,3-三氟丙烯（HCFO -1233xf），二氯氟化丙烯及其混合物。 本发明的发泡剂组合物与包括二氧化碳，大气，氢氟烃（HFC），氢氟烯烃（HFO），烷烃，氢氟醚（HFE）及其混合物的助熔剂一起使用。 在本发明中用作起泡剂的优选的HFCs包括但不限于1,1,1,2-四氟乙烷（HFC-134a），1,1-二氟乙烷（HFC-152a），1,1,1-三氟乙烷 三氟乙烷（HFC-143a），五氟乙烷（HFC-125），二氟甲烷（HFC-32）。 发泡剂组合物可用于生产具有改进的k因子的低密度绝缘泡沫。

公开(公告)号：US20170022128A1

公开(公告)日：2017-01-26

申请号：US15279680

申请日：2016-09-29

Applicant: ARKEMA INC.

Inventor： Maher Y. Elsheikh ,  Philippe BONNET ,  Olga C. N. KEELEY ,  Benjamin Bin CHEN

IPC: C07C17/25 ,  B01J37/00 ,  B01J37/14 ,  B01J27/132 ,  B01J21/18

CPC classification number: C07C17/25 ,  B01J21/18 ,  B01J23/26 ,  B01J27/132 ,  B01J37/0018 ,  B01J37/0072 ,  B01J37/08 ,  B01J37/14 ,  C07C21/18

Abstract: A method for producing a tetrafluoroolefin, such as 2,3,3,3-tetrafluoropropene (HFO-1234yf), comprises dehydrofluorinating a pentafluoroalkane in a gas phase in the presence of a catalyst comprising chromium oxyfluoride. In a preferred embodiment, 2,3,3,3-tetrafluoropropene (HFO-1234yf) is produced by forming a catalyst comprising chromium oxyfluoride by calcining CrF3.xH2O, where x is 1-10, in the presence of a flowing gas comprising nitrogen to form a calcined chromium oxyfluoride, and dehydrofluorinating 1,1,1,2,2-pentafluoropropane (HFC-245cb) in a gas phase in the presence of the catalyst to form the 2,3,3,3-tetrafluoropropene (HFO-1234yf).

Abstract translation: 一种生产四氟烯烃的方法，如2,3,3,3-四氟丙烯（HFO-1234yf），包括在包含氟氧化铬的催化剂存在下，在气相中脱氟氟化五氟烷烃。 在优选的实施方案中，通过在包含氮气的流动气体存在下，通过煅烧CrF 3·xH 2 O（其中x为1-10）形成包含氟氧化铬的催化剂来生产2,3,3,3-四氟丙烯（HFO-1234yf） 形成煅烧的氟氧化铬，在催化剂存在下，在气相中脱氟化氢化1,1,1,2,2-五氟丙烷（HFC-245cb），形成2,3,3,3-四氟丙烯（HFO- 1234yf）。

公开(公告)号：US20160152787A1

公开(公告)日：2016-06-02

申请号：US15015184

申请日：2016-02-04

Applicant: Arkema Inc.

Inventor： Benjamin Bin Chen ,  Joseph S. COSTA ,  Philippe BONNET ,  Maher Y. ELSHEIKH ,  Brett L. VAN HORN

IPC: C08J9/14 ,  B01F17/00

CPC classification number: C08J9/144 ,  B01F17/0085 ,  C08G18/06 ,  C08J9/146 ,  C08J9/149 ,  C08J2203/142 ,  C08J2203/162 ,  C08J2203/182 ,  C08J2300/104 ,  C08J2300/106 ,  C08J2375/04

Abstract: A blowing agent for thermosetting foams is disclosed. The blowing agent is a hydrofluoroolefin (HCFO), preferably HFCO-1234yf in combination with a hydrochlorofluoroolefin (HCFO) preferably one selected from HCFO-1233zd, HCFO-1223, HCFO-1233xf and mixtures thereof. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.

Abstract translation: 公开了一种用于热固性泡沫的发泡剂。 发泡剂是氢氟氟烯烃（HCFO），优选HFCO-1234yf与氢氯氟烯烃（HCFO），优选一种选自HCFO-1233zd，HCFO-1223，HCFO-1233xf及其混合物。 发泡剂在制造热固性泡沫时作为发泡剂是有效的。

公开(公告)号：US20160023034A1

公开(公告)日：2016-01-28

申请号：US14773775

申请日：2014-02-28

Applicant: ARKEMA INC.

Inventor： Maher Y. ELSHEIKH ,  Philippe BONNET

IPC: A62D1/00 ,  C07C17/42 ,  C09K3/30 ,  C09K5/04 ,  C09K3/00 ,  C08J9/14 ,  C07C17/389 ,  C07C21/18

CPC classification number: A62D1/0092 ,  C07C17/389 ,  C07C17/42 ,  C07C21/18 ,  C08J9/146 ,  C08J2300/22 ,  C09K3/00 ,  C09K3/30 ,  C09K5/044 ,  C09K5/045 ,  C09K2205/126

Abstract: Hydrofluoroolefins and hydrochlorofluoroolefins contaminated with acid and/or iron compounds are purified and stabilized by contacting the haloolefin with a solid adsorbent such as alumina and then combining the purified haloolefin with one or more stabilizers such as an epoxide. The purified, stabilized haloolefins thus obtained are useful in a wide variety of end-use applications, including, for example, as refrigerants, propellants, foaming agents, fire suppression or extinguishing agents, and solvents.

Abstract translation: 通过使卤代烯烃与固体吸附剂如氧化铝接触，然后将纯化的卤代烯烃与一种或多种稳定剂如环氧化合物进行组合，纯化和稳定由酸和/或铁化合物污染的氢氟烯烃和氢氯氟烯烃。 由此获得的纯化的稳定的卤代烯烃可用于多种最终用途应用，包括例如制冷剂，推进剂，发泡剂，灭火剂或灭火剂和溶剂。