Synthesis of 1,1-dichloro-1,2,2,2-tetrafluoroethane
    11.
    发明授权
    Synthesis of 1,1-dichloro-1,2,2,2-tetrafluoroethane 失效
    1,1-二氯-1,2,2,2-四氟乙烷的合成

    公开(公告)号:US5055624A

    公开(公告)日:1991-10-08

    申请号:US451861

    申请日:1989-12-18

    CPC classification number: B01J27/08 B01J23/18 C07C17/206

    Abstract: The invention relates to the selective manufacture of 1,1-dichloro-1,2,2,2-tetrafluoroethane by catalytic fluorination of 1,1,1-trichloro-2,2,2-trifluoroethane with anhydrous hydrofluoric acid.The reaction is carried out in the liquid phase at a temperature of between 70.degree. and 170.degree. C. and under a pressure of between 10 and 80 bars absolute, in the presence of an antimony-containing catalyst.

    Abstract translation: 本发明涉及通过用无水氢氟酸催化氟化1,1,1-三氯-2,2,2-三氟乙烷选择性制备1,1-二氯-1,2,2,2-四氟乙烷。 在含锑催化剂存在下,反应在液相中在70〜170℃的温度和10〜80巴绝对压力下进行。

    Synthesis of 1-chloro-1, 1-difluoroethane
    12.
    发明授权
    Synthesis of 1-chloro-1, 1-difluoroethane 失效
    合成1-氯-1,1-二氟乙烷

    公开(公告)号:US4849555A

    公开(公告)日:1989-07-18

    申请号:US205941

    申请日:1988-06-13

    CPC classification number: C07C17/206

    Abstract: The invention relates to a process for the manufacture of 1-chloro-1,1-difluoroethane in the liquid phase by reacting hydrofluoric acid with 1,1,1-trichloroethane and/or 1,1-dichloro-1-fluoroethane.The selectively is improved by using a perfluoroalkanesulphonic acid, in particular trifluoromethanesulphonic acid, as a catalyst.

    Abstract translation: 本发明涉及通过氢氟酸与1,1,1-三氯乙烷和/或1,1-二氯-1-氟乙烷反应制备液相中的1-氯-1,1-二氟乙烷的方法。 通过使用全氟烷基磺酸,特别是三氟甲磺酸,作为催化剂来选择性地改进。

    Synthesis of 2-(perfluoroalkyl) ethanethiols
    13.
    发明授权
    Synthesis of 2-(perfluoroalkyl) ethanethiols 失效
    2-(全氟烷基)乙硫醇的合成

    公开(公告)号:US4845300A

    公开(公告)日:1989-07-04

    申请号:US141847

    申请日:1988-01-11

    Applicant: Andre Lantz

    Inventor: Andre Lantz

    CPC classification number: C07C323/00

    Abstract: The subject of the invention is a process for the preparation of 2-(perfluoroalkyl)ethanethiols R.sub.f CH.sub.2 CH.sub.2 SH, R.sub.f denoting a straight-chain or branched perfluoroalkyl radical containing from 2 to 20 carbon atoms. The proceses comprises reacting a 2-(perfluoroalkyl)ethyl iodide with thiourea and then decomposing the isothiouronium salt formed with an alkaline base, and is characterized in that it is carried out in a non-alcoholic inert solvent.

    Abstract translation: 本发明的主题是制备2-(全氟烷基)乙硫醇RfCH 2 CH 2 SH,Rf表示含有2至20个碳原子的直链或支链全氟烷基的方法。 方法包括使2-(全氟烷基)乙基碘与硫脲反应,然后分解由碱性碱形成的异硫脲盐,其特征在于其在非醇惰性溶剂中进行。

    Process for the purification of 1,1,1,2-tetrafluoroethane
    20.
    发明授权
    Process for the purification of 1,1,1,2-tetrafluoroethane 失效
    1,1,1,2-四氟乙烷纯化方法

    公开(公告)号:US06395941B1

    公开(公告)日:2002-05-28

    申请号:US08888294

    申请日:1997-07-03

    CPC classification number: C07C17/395 C07C19/08

    Abstract: In order to remove the impurities (in particular 1-chloro-2,2-difluoroethylene) present in crude 1,1,1,2-tetrafluoroethane (F134a), a gaseous mixture of crude F134a and hydrofluoric acid is treated in the gas phase, in the presence of a fluorination catalyst, at a temperature of between 200 and 380° C. and under a pressure between atmospheric pressure and 2.5 MPa, the HF/F134a molar ratio being between 0.05 and 0.5.

    Abstract translation: 为了除去原料1,1,1,2-四氟乙烷(F134a)中存在的杂质(特别是1-氯-2,2-二氟乙烯),将粗F134a和氢氟酸的气体混合物在气相 在氟化催化剂的存在下,在200-380℃的温度下,在大气压和2.5MPa之间的压力下,HF / F134a的摩尔比为0.05-0.5。

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