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公开(公告)号:US20190016931A1
公开(公告)日:2019-01-17
申请号:US16069320
申请日:2017-01-10
Applicant: BASF SE
Inventor: Karl-Heinz SCHUMACHER , Christine TONHAUSER , Christoph KIENER , Peter PREISHUBER-PFLUEGL , Andrea KUNTZ
IPC: C09J133/10 , C09J133/08 , B32B37/12 , B32B7/12 , B32B27/36
Abstract: A description is given of the use of a one-component laminating adhesive for composite film lamination, and also of a method for composite film lamination. The laminating adhesive comprises an aqueous polymer dispersion preparable by radical emulsion polymerization of monomers comprising (a) at least 60 wt %, based on the total amount of monomers, of at least one monomer selected from the group consisting of C1 to C20 alkyl acrylates, C1 to C20 alkyl methacrylates, vinyl esters of carboxylic acids comprising up to 20 carbon atoms, vinylaromatics having up to 20 carbon atoms, vinyl halides, vinyl ethers of alcohols comprising 1 to 10 carbon atoms, aliphatic hydrocarbons having 2 to 8 carbon atoms and one or two double bonds, and mixtures of these monomers, and (b) at least 0.1 wt %, based on the total amount of monomers, of at least one monomer having at least one acid group, and (c) 0.1 to 5 wt %, based on the total amount of monomers, of at least one ethylenically unsaturated compound having at least one functional group selected from keto groups and aldehyde groups; where the aqueous polymer dispersion comprises at least one compound A which has at least two functional groups that are able to enter into a crosslinking reaction with keto groups or with aldehyde groups; where the molar ratio of the groups of the compound A that are reactive with keto groups or with aldehyde groups to the keto and aldehyde groups of the monomer (b) is from 1:10 to 2:1; and where, in the composite film lamination, at least two films are bonded to one another with the laminating adhesive so firmly that the peel strength is 2.5 N/15 mm or more or that the films bonded to one another are partable only with destruction of at least one of the films. The composite films can be used for the packing of foods.
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公开(公告)号:US20180118985A1
公开(公告)日:2018-05-03
申请号:US15565433
申请日:2016-04-13
Applicant: BASF SE
Inventor: Matthias ZORN , Karl-Heinz SCHUMACHER
IPC: C09J151/00 , C08L51/00 , B32B7/12
CPC classification number: C09J151/003 , B32B7/12 , B32B27/08 , B32B2255/10 , B32B2255/26 , C08F265/06 , C08L51/003 , C08L2201/54 , C09D151/003 , C08F2220/1825 , C08F220/18 , C08F212/08 , C08L33/14
Abstract: Described are aqueous polymer dispersions for composite film lamination, comprising a dispersed polymer and a dissolved polymer, and also a multistage process for preparing them from ethylenically unsaturated, radically polymerizable monomers. In a first stage, a first polymer is prepared by radical emulsion polymerization. In a second stage, an aqueous polymer dispersion is prepared in the presence of the first polymer. The monomers of the first stage comprise monomers with acid groups. The dissolved polymer comprises monomers having oxazoline groups, and also water-soluble monomers. The aqueous polymer dispersions can be used as adhesive for producing composite films.
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公开(公告)号:US20190256639A1
公开(公告)日:2019-08-22
申请号:US16343919
申请日:2017-10-24
Applicant: BASF SE
Inventor: Ulrike LICHT , Dirk WULFF , Karl-Heinz SCHUMACHER
IPC: C08G18/08 , C08G18/68 , C08G18/48 , C08G18/76 , B32B27/40 , B32B7/12 , C09D4/06 , C09D7/65 , C08G18/34
Abstract: Described are polyurethane-vinyl hybrid polymers, methods of making them and their use. The hybrid polymers are made from an anionic polyurethane and a polymerizable vinyl compound, wherein the polymerizable vinyl compound is selected from methylene malonates, methylene beta-ketoesters and methylene beta-diketones. The hybrid polymers can be used as binder in structural adhesives, as binder in pressure-sensitive adhesives, as binder in laminating adhesives, as binder in contact adhesives, as binder in ink, as binder in paints, as binder in coatings, as binder for fiber bonding, as binder for particle bonding or as binder in high cohesion adhesive tapes.
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公开(公告)号:US20190241538A1
公开(公告)日:2019-08-08
申请号:US16335153
申请日:2017-09-11
Applicant: BASF SE
Inventor: Ulrike LICHT , Viktoria LEONHARDT , Verena MORMUL , Karl-Heinz SCHUMACHER , Gabor BOERZSOENYI , Rainer KLOPSCH
IPC: C07D317/38 , C08G64/02 , C09D169/00
CPC classification number: C07D317/38 , C08G64/0241 , C09D169/00
Abstract: What are described are compounds having two or more exovinylene cyclocarbonate units, wherein the exovinylene cyclocarbonate units are bonded to one another via at least one organic, siloxane-free connecting group which is not bonded directly to the exovinylene double bonds, excluding connecting groups formed by polymerization of (meth)acrylic monomers. The connecting group preferably has at least one acetal group. Also described are a process for preparing the compounds, two-component binders comprising the compounds, and uses of the compounds.
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公开(公告)号:US20170355887A1
公开(公告)日:2017-12-14
申请号:US15529177
申请日:2015-12-02
Applicant: BASF SE
Inventor: Karl-Heinz SCHUMACHER , Gemma SANDERS , Kimberly SIMANCAS , Oliver HARTZ
IPC: C09J11/06 , C09J175/06 , C08G18/42 , C08G18/08 , C08G18/73 , C08G18/38 , C08G18/72 , C08G18/76 , C08G18/66 , C08K5/06
CPC classification number: C09J11/06 , B32B7/12 , B32B27/08 , B32B27/40 , B32B2307/546 , B32B2451/00 , B32B2605/003 , C08G18/0823 , C08G18/3821 , C08G18/4238 , C08G18/4854 , C08G18/6651 , C08G18/724 , C08G18/73 , C08G18/7621 , C08G2170/80 , C08K5/05 , C08K5/06 , C09J175/04 , C09J175/06 , C09J175/08
Abstract: Described are aqueous adhesive dispersions comprising dispersed polyurethanes and also ethoxylated fatty alcohols as emulsifiers. The polyurethanes are constructed from certain organic diisocyanates, dihydroxy compounds selected from certain polyester diols and polyether diols, and compounds having groups reactive toward isocyanate groups and having at least one ionic group. The adhesive dispersions can be used as laminating adhesives, for example for composite film lamination or for the lamination of rigid moldings with flexible decorative foils.
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公开(公告)号:US20160002486A1
公开(公告)日:2016-01-07
申请号:US14766807
申请日:2014-03-17
Applicant: BASF SE
Inventor: Andrea KUNTZ , Karl-Heinz SCHUMACHER , Christoph KIENER
IPC: C09D133/14 , B05D3/00
CPC classification number: C09D133/14 , B05D3/007 , C08F2/20 , C08F2/24 , C09J7/20 , C09J133/14 , C08F2220/1808 , C08F218/08 , C08F220/14 , C08F220/36
Abstract: A description is given of the use of a polymer dispersion for cold sealing, the polymer dispersion comprising a polymer in dispersion in water and having a glass transition temperature in the range from −20 to +10° C., said polymer being preparable by emulsion polymerization of radically polymerizable monomers in the presence of at least one polymeric protective colloid, and the polymer being formed to an extent of 0.05 to less than 1 wt % of a monomer M, selected from the group consisting of (meth)acrylate monomers having a substituent of the formula where X is CH2, O, NH or NR, and R is a C1 to C4 alkyl group.Descriptions are also given of a method for producing cold-sealed packaging, and of the packaging obtainable by said method.
Abstract translation: 给出了聚合物分散体用于冷密封的描述,聚合物分散体包含在水中分散的聚合物并且玻璃化转变温度在-20至+ 10℃的范围内,所述聚合物可由乳液制备 在至少一种聚合物保护胶体存在下聚合可自由基聚合的单体,并且该聚合物形成的量为单体M的0.05至小于1重量%,所述单体M选自(甲基)丙烯酸酯单体,其具有 下式的取代基,其中X是CH 2,O,NH或NR,R是C 1至C 4烷基。 还给出了用于生产冷封包装的方法以及通过所述方法可获得的包装的说明。
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