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    LAYER SYSTEM FOR ELECTROCHEMICAL CELLS
    13.
    发明申请
    LAYER SYSTEM FOR ELECTROCHEMICAL CELLS 审中-公开
    电化学细胞层系统

    公开(公告)号：US20130273435A1

    公开(公告)日：2013-10-17

    申请号：US13859948

    申请日：2013-04-10

    Applicant: BASF SE

    Inventor： Klaus LEITNER ,  Alexander Panchenko ,  Oliver Gronwald ,  Ruediger Oesten ,  Evgueni Klimov

    IPC: H01M4/60 ,  H01M4/04

    CPC classification number: H01M4/602 ,  H01M2/162 ,  H01M2/1673 ,  H01M4/0402 ,  H01M4/13 ,  H01M10/052 ,  H01M10/0565 ,  H01M2300/0082 ,  H01M2300/0094

    Abstract: A layer system for electrochemical cells comprising at least one fibrous nonwoven fabric (A) formed by fibers of one or more organic polymers or mixtures of organic polymers (A1) wherein (i) the fibrous nonwoven fabric (A) contains a polymer electrolyte (C) comprising (C1) an electrolyte solvent or a mixture of electrolyte solvents, (C2) at least one electrolyte salt, and (C3) at least one organic polymer or polymer mixture, and/or (ii) a second fibrous nonwoven fabric (B) formed by fibers of one or more organic polymers or mixtures of organic polymers (B1) is aligned parallel to (A), wherein (B) may contain a polymer electrolyte (D) comprising (D1) an electrolyte solvent or a mixture of electrolyte solvents, (D2) at least one electrolyte salt, and (D3) at least one organic polymer or polymer mixture.

    Abstract translation: 一种用于电化学电池的层系统，包括由一种或多种有机聚合物的纤维或有机聚合物（A1）的混合物形成的至少一种纤维无纺布（A），其中（i）所述纤维无纺布（A）含有聚合物电解质 ）包括（C1）电解质溶剂或电解质溶剂的混合物，（C2）至少一种电解质盐和（C3）至少一种有机聚合物或聚合物混合物，和/或（ii）第二纤维无纺布 由（A）组成的一种或多种有机聚合物的纤维或有机聚合物（B1）的混合物形成的聚合物电解质（D）可以包含聚合物电解质（D），其包含（D1）电解质溶剂或电解质的混合物 溶剂，（D2）至少一种电解质盐，和（D3）至少一种有机聚合物或聚合物混合物。

    PROCESS FOR PREPARING AMINO HYDROCARBONS BY DIRECT AMINATION OF HYDROCARBONS
    14.
    发明申请
    PROCESS FOR PREPARING AMINO HYDROCARBONS BY DIRECT AMINATION OF HYDROCARBONS 审中-公开
    通过直接甲烷化来制备氨基烃的方法

    公开(公告)号：US20130236801A1

    公开(公告)日：2013-09-12

    申请号：US13781965

    申请日：2013-03-01

    Applicant: BASF SE

    Inventor： Bernd Bastian SCHAACK ,  Alexander Panchenko ,  Philipp Brueggemann

    IPC: H01M8/06 ,  C07C209/02 ,  H01M8/10

    CPC classification number: H01M8/0612 ,  C07C209/02 ,  H01M2008/1095 ,  Y02P20/582 ,  C07C211/04 ,  C07C211/46 ,  C07C211/47 ,  C07C211/50 ,  C07C211/51

    Abstract: The present invention relates to a process for direct amination of hydrocarbons to amino hydrocarbons, comprising (a) the reaction of a reactant stream E comprising at least one hydrocarbon and at least one aminating reagent to give a reaction mixture R comprising at least one amino hydrocarbon and hydrogen in a reaction zone RZ, and (b) electrochemical removal of at least a portion of the hydrogen formed in the reaction from the reaction mixture R by means of at least one gas-tight membrane electrode assembly which is in contact with the reaction zone RZ on the retentate side and which has at least one selectively proton-conducting membrane, at least a portion of the hydrogen being oxidized over an anode catalyst to protons on the retentate side of the membrane, and the protons, after passing through the membrane, being partly or fully reacted with an oxidizing agent over a cathode catalyst to give water on the permeate side, and the oxidizing agent originating from a stream O which is contacted with the permeate side of the membrane.

    Abstract translation: 本发明涉及将烃直接胺化成氨基烃的方法，其包括（a）包含至少一种烃和至少一种胺化试剂的反应物流E的反应，得到包含至少一种氨基烃的反应混合物R 和反应区RZ中的氢，和（b）通过与反应接触的至少一个气密膜电极组件电化学去除反应混合物R中形成的氢的至少一部分 并且具有至少一个选择性质子传导膜，所述氢的至少一部分在阳极催化剂上被氧化以在所述膜的滞留侧上的质子和所述质子在通过所述膜之后 ，在阴极催化剂上与氧化剂部分或完全反应以在渗透侧产生水，并且源自流O的氧化剂，其中i s与膜的渗透侧接触。

    PROCESS FOR PREPARING AMINO HYDROCARBONS BY DIRECT AMINATION OF HYDROCARBONS
    15.
    发明申请
    PROCESS FOR PREPARING AMINO HYDROCARBONS BY DIRECT AMINATION OF HYDROCARBONS 审中-公开
    通过直接甲烷化来制备氨基烃的方法

    公开(公告)号：US20130233721A1

    公开(公告)日：2013-09-12

    申请号：US13785980

    申请日：2013-03-05

    Applicant: BASF SE

    Inventor： Bernd Bastian SCHAACK ,  Alexander Panchenko ,  Philipp Brueggemann

    IPC: C07C209/02 ,  C25B3/04

    CPC classification number: C07C209/02 ,  C25B3/00 ,  C25B3/04 ,  Y02P20/582 ,  C07C211/46 ,  C07C211/47 ,  C07C211/50 ,  C07C211/51 ,  C07C211/04

    Abstract: The present invention relates to a process for direct amination of hydrocarbons to amino hydrocarbons, comprising (a) the reaction of a reactant stream E comprising at least one hydrocarbon and at least one aminating reagent to give a reaction mixture R comprising at least one amino hydrocarbon and hydrogen in a reaction zone RZ, and (b) electrochemical removal of at least a portion of the hydrogen formed in the reaction from the reaction mixture R by means of at least one gas-tight membrane electrode assembly which is in contact with the reaction zone RZ on the retentate side and which has at least one selectively proton-conducting membrane, at least a portion of the hydrogen being oxidized over an anode catalyst to protons on the retentate side of the membrane, and the protons, after passing through the membrane, being partly or fully reduced by applying a voltage over a cathode catalyst to give hydrogen on the permeate side.

    Abstract translation: 本发明涉及将烃直接胺化成氨基烃的方法，其包括（a）包含至少一种烃和至少一种胺化试剂的反应物流E的反应，得到包含至少一种氨基烃的反应混合物R 和反应区RZ中的氢，和（b）通过与反应接触的至少一个气密膜电极组件电化学去除反应混合物R中形成的氢的至少一部分 并且具有至少一个选择性质子传导膜，所述氢的至少一部分在阳极催化剂上被氧化以在所述膜的滞留侧上的质子和所述质子在通过所述膜之后 ，通过在阴极催化剂上施加电压以在渗透侧产生氢来部分或完全还原。

    Method for producing cis- and trans-enriched MDACH
    18.
    发明授权
    Method for producing cis- and trans-enriched MDACH 有权

    公开(公告)号：US10336668B2

    公开(公告)日：2019-07-02

    申请号：US15529133

    申请日：2015-11-18

    Applicant: BASF SE

    Inventor： Jan-Oliver Weidert ,  Sandra Kramp ,  Regina Benfer ,  Alexander Panchenko ,  Andreas Weickgenannt ,  Norbert Gutfrucht ,  Klaus Breuer ,  Artur Kozicki ,  Ralph Busch

    IPC: C07C7/04 ,  B01D3/00 ,  B01D3/10 ,  C07C209/86 ,  C07C211/36

    Abstract: A process for preparing trans-enriched MDACH, including: distilling an MDACH starting mixture in the presence of an auxiliary, which is an organic compound having a molar mass of 62 to 500 g/mol, a boiling point at least 5° C. above the boiling point of cis,cis-2,6-diamino-1-methylcyclohexane, and 2 to 4 functional groups, each of which is independently an alcohol group or a primary, secondary or tertiary amino group. The MDACH starting mixture includes 0 to 100% by weight of 2,4-MDACH and 0 to 100% by weight of 2,6-MDACH, based on the total amount of MDACH present in the MDACH starting mixture. The MDACH starting mixture includes both trans and cis isomers. Trans-enriched MDACH includes 0 to 100% by weight of 2,4-MDACH and 0 to 100% by weight of 2,6-MDACH, where the proportion of trans isomers in the mixture is higher than the proportion of trans isomers in the MDACH starting mixture.

    2,6-bis-(aminomethyl)piperidine derivatives
    20.
    发明授权
    2,6-bis-(aminomethyl)piperidine derivatives 有权

    公开(公告)号：US09695121B2

    公开(公告)日：2017-07-04

    申请号：US14764010

    申请日：2014-01-27

    Applicant: BASF SE

    Inventor： Stephanie Jaegli ,  Thomas Schmidt ,  Alfred Oftring ,  Alexander Panchenko ,  Kirsten Dahmen ,  Oliver Molt

    IPC: C07D211/26 ,  C07D211/60

    CPC classification number: C07D211/26 ,  C07D211/60

    Abstract: The present invention relates to 2,6-bis(aminomethyl)piperidine derivatives as such (in the following text abbreviated to “2,6-BAMP derivatives”) which are defined by the general formula (I) shown in the following text. In addition, the present invention relates to a process for preparing such 2,6-BAMP derivatives by hydrogenation of the corresponding 2,6-dicyanopiperidine derivatives (hereinafter abbreviated to “2,6-DCP derivatives”) in the presence of a catalyst. The present invention further provides for the use of the 2,6-BAMP derivatives of the invention as hardeners for epoxy resins, as intermediate in the preparation of diisocyanates, which play an important role in the production of polyurethanes, as starters in the preparation of polyetherols and/or as monomers for polyamide production. The present invention further relates to the diisocyanates as such prepared from the 2,6-BAMP derivatives and also the corresponding preparative process.

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