公开(公告)号：US20160310934A1

公开(公告)日：2016-10-27

申请号：US15105611

申请日：2014-12-18

Applicant: BASF SE

Inventor： Kirsten BRAUNSMANN ,  Bernd Bastian SCHAACK ,  Ekkehard SCHWAB ,  Manuela GAAB ,  Mathias FEYEN

IPC: B01J29/40 ,  B01J37/04 ,  B01J37/08 ,  C07C1/20 ,  B01J37/02

CPC classification number: B01J29/40 ,  B01J29/70 ,  B01J29/7038 ,  B01J29/90 ,  B01J35/002 ,  B01J35/023 ,  B01J35/10 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/04 ,  B01J37/08 ,  B01J37/28 ,  B01J38/02 ,  B01J2229/12 ,  B01J2229/123 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/32 ,  B01J2229/37 ,  B01J2229/42 ,  C07C1/20 ,  C07C1/207 ,  C07C11/02 ,  C07C11/06 ,  C07C11/08 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/20

Abstract: The present invention relates to a catalyst for the conversion of oxygenates to olefins, wherein the catalyst comprises one or more zeolites of the MFI, MEL and/or MWW structure type and particles of one or more metal oxides, the one or more zeolites of the MFI, MEL and/or MWW structure type comprising one or more alkaline earth metals selected from the group consisting of Mg, Ca, Sr, Ba and combinations of two or more thereof, wherein the catalyst displays a water uptake of 9.0 wt.-% or less, as well as to a process for the production thereof and to its use, in particular in a process for converting oxygenates to olefins.

公开(公告)号：US20160304436A1

公开(公告)日：2016-10-20

申请号：US15103652

申请日：2014-12-10

Applicant: BASF SE

Inventor： Bernd Bastian SCHAACK ,  Martin BOCK ,  Kirsten DAHMEN

IPC: C07C209/72

CPC classification number: C07C209/72 ,  C07C2601/14 ,  C07C211/36

Abstract: The present invention relates to a method for hydrogenating aromatic compounds with hydrogen in the presence of a catalyst, in which the catalyst comprises ruthenium on a zirconium oxide support material, and also the use of a catalyst comprising ruthenium on a zirconium oxide support material for hydrogenating aromatic compounds.

Abstract translation: 本发明涉及一种在催化剂存在下用氢气氢化芳族化合物的方法，其中催化剂在氧化锆载体材料上包含钌，以及在氧化锆载体材料上使用包含钌的催化剂进行氢化 芳香族化合物。

公开(公告)号：US20180297013A1

公开(公告)日：2018-10-18

申请号：US15765821

申请日：2016-10-04

Applicant: BASF SE

Inventor： Bernd Bastian SCHAACK ,  Helmut WANISCH ,  Barbara WUCHER ,  Sabine HUBER

IPC: B01J21/18 ,  B01J23/89 ,  B01J33/00 ,  B01J37/03 ,  B01J37/18 ,  B01J37/00 ,  C07C29/141 ,  C07C33/025

CPC classification number: B01J21/18 ,  B01J23/8906 ,  B01J33/00 ,  B01J37/0018 ,  B01J37/03 ,  B01J37/035 ,  B01J37/18 ,  B01J2523/821 ,  B01J2523/842 ,  C07C29/141 ,  C07C33/025 ,  C07C33/02

Abstract: The present invention relates to a process for producing iron-doped ruthenium-carbon support catalysts and also their use for the selective liquid-phase hydrogenation of carbonyl compounds to the corresponding alcohols, in particular for the hydrogenation of citral to geraniol or nerol or of citronellal to citronellal.

公开(公告)号：US20170001874A1

公开(公告)日：2017-01-05

申请号：US15264314

申请日：2016-09-13

Applicant: BASF SE

Inventor： Mathias FEYEN ,  Ulrich MÜLLER ,  Andrei-Nicolae PARVULESCU ,  Bernd Bastian SCHAACK ,  Sebastian AHRENS ,  Dirk GERHARD ,  Sunghee SON ,  Gabriele IFFLAND ,  Bianca SEELIG

IPC: C01B39/48 ,  C01B37/02 ,  C01B37/00 ,  B01J29/40 ,  B01J37/30 ,  B01J29/035 ,  B01J35/10 ,  B01J37/00 ,  B01J37/04 ,  B01J37/06 ,  C01B39/40 ,  B01J29/89

CPC classification number: C01B39/48 ,  B01J20/18 ,  B01J20/186 ,  B01J20/28057 ,  B01J20/3085 ,  B01J29/00 ,  B01J29/035 ,  B01J29/06 ,  B01J29/40 ,  B01J29/89 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0018 ,  B01J37/009 ,  B01J37/04 ,  B01J37/06 ,  B01J37/30 ,  B01J2229/183 ,  B01J2229/186 ,  C01B37/005 ,  C01B37/02 ,  C01B39/04 ,  C01B39/065 ,  C01B39/085 ,  C01B39/40 ,  C01P2002/72 ,  C01P2006/12

Abstract: The present invention relates to a process for the preparation of a zeolitic material comprising the steps of: (1) providing a mixture comprising one or more sources for YO2 and one or more alkenyltrialkylammonium cation R1R2R3R4N+-containing compounds as structure directing agent; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material; wherein Y is a tetravalent element, and wherein R1, R2, and R3 independently from one another stand for alkyl; and R4 stands for alkenyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.

Abstract translation: 本发明涉及一种制备沸石材料的方法，包括以下步骤：（1）提供包含一种或多种YO 2源和一种或多种烯基三烷基铵阳离子R 1 R 2 R 3 R 4 N +化合物作为结构导向剂的混合物; 和（2）使步骤（1）中获得的混合物结晶以获得沸石材料; 其中Y是四价元素，并且其中R 1，R 2和R 3彼此独立地代表烷基; 并且R4代表烯基，以及可以根据本发明方法获得的沸石材料及其用途。

公开(公告)号：US20160326094A1

公开(公告)日：2016-11-10

申请号：US15103789

申请日：2014-12-10

Applicant: BASF SE

Inventor： Andreas WEICKGENANNT ,  Bernd Bastian SCHAACK ,  Barbara WUCHER ,  Alexander PANCHENKO ,  Frank HETTCHE ,  Martin BOCK ,  Aik Meam TAN ,  Kirsten DAHMEN

IPC: C07C209/72 ,  B01J37/18 ,  B01J37/02 ,  B01J37/08 ,  B01J23/46 ,  B01J35/10

CPC classification number: C07C209/72 ,  B01J23/462 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0225 ,  B01J37/0236 ,  B01J37/08 ,  B01J37/18 ,  Y02P20/582 ,  C07C211/36

Abstract: The present invention relates to a process for hydrogenating 4,4′-methylenedianiline and/or polymeric MDA with hydrogen in the presence of a catalyst comprising ruthenium on a zirconium oxide support material, and also to the use of a catalyst comprising ruthenium on a zirconium oxide support material for hydrogenating 4,4′-methylenedianiline and/or polymeric MDA.

Abstract translation: 本发明涉及一种在包含钌在氧化锆载体材料上的催化剂存在下用氢气氢化4,4'-亚甲基二苯胺和/或聚合的MDA的方法，还涉及使用包含钌的催化剂在锆 用于氢化4,4'-亚甲基二苯胺和/或聚合的MDA的氧化物载体材料。

公开(公告)号：US20130236801A1

公开(公告)日：2013-09-12

申请号：US13781965

申请日：2013-03-01

Applicant: BASF SE

Inventor： Bernd Bastian SCHAACK ,  Alexander Panchenko ,  Philipp Brueggemann

IPC: H01M8/06 ,  C07C209/02 ,  H01M8/10

CPC classification number: H01M8/0612 ,  C07C209/02 ,  H01M2008/1095 ,  Y02P20/582 ,  C07C211/04 ,  C07C211/46 ,  C07C211/47 ,  C07C211/50 ,  C07C211/51

Abstract: The present invention relates to a process for direct amination of hydrocarbons to amino hydrocarbons, comprising (a) the reaction of a reactant stream E comprising at least one hydrocarbon and at least one aminating reagent to give a reaction mixture R comprising at least one amino hydrocarbon and hydrogen in a reaction zone RZ, and (b) electrochemical removal of at least a portion of the hydrogen formed in the reaction from the reaction mixture R by means of at least one gas-tight membrane electrode assembly which is in contact with the reaction zone RZ on the retentate side and which has at least one selectively proton-conducting membrane, at least a portion of the hydrogen being oxidized over an anode catalyst to protons on the retentate side of the membrane, and the protons, after passing through the membrane, being partly or fully reacted with an oxidizing agent over a cathode catalyst to give water on the permeate side, and the oxidizing agent originating from a stream O which is contacted with the permeate side of the membrane.

Abstract translation: 本发明涉及将烃直接胺化成氨基烃的方法，其包括（a）包含至少一种烃和至少一种胺化试剂的反应物流E的反应，得到包含至少一种氨基烃的反应混合物R 和反应区RZ中的氢，和（b）通过与反应接触的至少一个气密膜电极组件电化学去除反应混合物R中形成的氢的至少一部分 并且具有至少一个选择性质子传导膜，所述氢的至少一部分在阳极催化剂上被氧化以在所述膜的滞留侧上的质子和所述质子在通过所述膜之后 ，在阴极催化剂上与氧化剂部分或完全反应以在渗透侧产生水，并且源自流O的氧化剂，其中i s与膜的渗透侧接触。

公开(公告)号：US20130233721A1

公开(公告)日：2013-09-12

申请号：US13785980

申请日：2013-03-05

Applicant: BASF SE

Inventor： Bernd Bastian SCHAACK ,  Alexander Panchenko ,  Philipp Brueggemann

IPC: C07C209/02 ,  C25B3/04

CPC classification number: C07C209/02 ,  C25B3/00 ,  C25B3/04 ,  Y02P20/582 ,  C07C211/46 ,  C07C211/47 ,  C07C211/50 ,  C07C211/51 ,  C07C211/04

Abstract: The present invention relates to a process for direct amination of hydrocarbons to amino hydrocarbons, comprising (a) the reaction of a reactant stream E comprising at least one hydrocarbon and at least one aminating reagent to give a reaction mixture R comprising at least one amino hydrocarbon and hydrogen in a reaction zone RZ, and (b) electrochemical removal of at least a portion of the hydrogen formed in the reaction from the reaction mixture R by means of at least one gas-tight membrane electrode assembly which is in contact with the reaction zone RZ on the retentate side and which has at least one selectively proton-conducting membrane, at least a portion of the hydrogen being oxidized over an anode catalyst to protons on the retentate side of the membrane, and the protons, after passing through the membrane, being partly or fully reduced by applying a voltage over a cathode catalyst to give hydrogen on the permeate side.

Abstract translation: 本发明涉及将烃直接胺化成氨基烃的方法，其包括（a）包含至少一种烃和至少一种胺化试剂的反应物流E的反应，得到包含至少一种氨基烃的反应混合物R 和反应区RZ中的氢，和（b）通过与反应接触的至少一个气密膜电极组件电化学去除反应混合物R中形成的氢的至少一部分 并且具有至少一个选择性质子传导膜，所述氢的至少一部分在阳极催化剂上被氧化以在所述膜的滞留侧上的质子和所述质子在通过所述膜之后 ，通过在阴极催化剂上施加电压以在渗透侧产生氢来部分或完全还原。