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公开(公告)号：US07314963B2
公开(公告)日：2008-01-01
申请号：US10951359
申请日：2004-09-28
IPC分类号： C07C4/06
CPC分类号： B01J29/035 , B01J29/40 , B01J2229/42 , C07C4/06 , Y02P20/52 , C07C11/04 , C07C11/06
摘要： The present invention comprises a process for producing propylene comprising the steps of contacting an olefin feed containing between about 40 and about 80 wt-% olefins and between about 20 and about 60 wt-% olefins and aromatics with a spherical catalyst to form a cracked product, the catalyst comprising about 30 to about 80 wt-% of a crystalline zeolite, the reaction conditions including a temperature from about 500° to 650° C., a hydrocarbon partial pressure of 70 to 280 kPa (10 to 40 psia), a liquid hourly space velocity in the range of 5 to 40 hr−1 and wherein propylene comprises at least 90 mol-% of the total C3 products.
摘要翻译： 本发明包括一种生产丙烯的方法，包括以下步骤：将含有约40至约80重量％的烯烃和约20至约60重量％的烯烃和芳族化合物的烯烃进料与球形催化剂接触以形成裂化产物 ，催化剂包含约30至约80重量％的结晶沸石，反应条件包括约500℃至650℃的温度，70至280kPa（10至40psia）的烃分压， 在5至40小时-1的范围内的液时空速，其中丙烯占总C 3 N 3产物的至少90摩尔％。
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公开(公告)号：US06228341B1
公开(公告)日：2001-05-08
申请号：US09149606
申请日：1998-09-08
IPC分类号： C01C104
CPC分类号： F28D9/0037 , B01J19/249 , B01J19/32 , B01J2208/022 , B01J2219/2453 , B01J2219/2459 , B01J2219/246 , B01J2219/2462 , B01J2219/2464 , B01J2219/2465 , B01J2219/2466 , B01J2219/2479 , B01J2219/2481 , B01J2219/3221 , B01J2219/32217 , B01J2219/32475 , C01B3/382 , C01B3/384 , C01B2203/0233 , C01B2203/0244 , C01B2203/0844 , C01B2203/0883 , C01B2203/1011 , C01B2203/1035 , C01B2203/1041 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , C01B2203/1276 , C01B2203/141 , C01B2203/143 , C01B2203/82 , C01C1/0417 , F28F3/04 , Y02P20/124 , Y02P20/52
摘要： A process and apparatus cools a heat exchange type reaction zone by passing the incoming reactants through heat exchange channels in heat exchange relationship with the reaction zone. The invention simplifies the operation and construction of the heat exchanging type reaction zone by directly communicating reaction channels that contain the reaction with the heating channels that heat reactant across an open manifold located at the end of the channels. Additional reactants, cooling fluids, or other diluents may enter the process directly through the manifold space to permit further temperature control of the reaction zone. The invention promotes better heat transfer efficiency than tube and shell heat transfer arrangements that have been used for similar purposes. The narrow channels are preferably defined by corrugated plates. The reaction channels will contain a catalyst for the promotion of the primary reaction.
摘要翻译： 一种方法和装置通过使进入的反应物通过与反应区的热交换关系的热交换通道冷却热交换反应区。 本发明简化了热交换型反应区的操作和构造，其通过将反应通道与加热通道直接连通，该反应通道将反应物加热穿过位于通道末端的开放歧管。 另外的反应物，冷却流体或其它稀释剂可以通过歧管空间直接进入该过程，以允许对反应区进行进一步的温度控制。 与已经用于相似目的的管和壳体传热装置相比，本发明提高了传热效率。 窄通道优选地由波纹板限定。 反应通道将含有促进初级反应的催化剂。
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公开(公告)号：US5015783A
公开(公告)日：1991-05-14
申请号：US445255
申请日：1989-12-04
IPC分类号： C07C41/06
CPC分类号： C07C41/06 , C07C41/09 , Y02P20/582
摘要： Processes for the production of ethers from alcohols and isoolefins are disclosed. Isoolefins having four to five carbon atoms per molecule are combined with a monohydroxy alcohol having from one to five carbon atoms per molecule and with a recycle stream comprising alcohol and water to form an etherification zone feed stream which is passed through an etherification zone to produce the desired ether. The effluent from the etherification zone is separated into an ether product and an aqueous product containing unreacted alcohol which is recycled to provide a portion of the etherification zone feed stream. Distillation can be employed to separate the effluent from the etherification zone into a bottoms product stream, comprising the ether, a distillate product comprising other hydrocarbons and the above-mentioned recycle stream. When producing ethyl-tertiary-butyl ether (ETBE), azeotropic grade ethanol, i.e., about 5 vol. % water, is preferably utilized. The utilization of the alcohol/water recycle stream can obviate the need for additional alcohol recovery from the distillate product.
摘要翻译： 公开了从醇和异烯烃生产醚的方法。 每分子具有4至5个碳原子的异烯烃与每分子具有1至5个碳原子的单羟基醇和包含醇和水的再循环料流组合以形成醚化区进料流，其通过醚化区以产生 所需的醚。 来自醚化区的流出物被分离成醚产物和含有未反应的醇的含水产物，其被再循环以提供一部分醚化区进料流。 可以使用蒸馏将来自醚化区的流出物分离成塔底产物流，其包含醚，包含其它烃的馏出物产物和上述循环物流。 当生产乙基叔丁基醚（ETBE）时，共沸级乙醇即约5体积％ ％的水。 酒精/水循环流的利用可以避免从馏出物产品中再次进行酒精回收的需要。
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公开(公告)号：US4754078A
公开(公告)日：1988-06-28
申请号：US020806
申请日：1987-03-02
CPC分类号： C07C41/06 , C07C5/2791
摘要： A multistep hydrocarbon conversion process for the production of ethers including methyl tertiary butyl ether (MTBE) from light paraffins and alcohols is disclosed. A mixture of C.sub.4 isoparaffins, normal paraffins, an etherification recycle and butane isomerization effluent enter a deisobutanizer column. Normal paraffins withdrawn from the fractionator are isomerized and returned to the fractionator, and isoparaffins are withdrawn from the fractionator and dehyrogenated. The resulting olefins enter an etherification zone for reaction of isobutene with a C.sub.2 -C.sub.5 alcohol. Unreacted paraffins and olefins comprise the etherification effluent entering the deisobutanizer. Normal butanes and olefins are withdrawn as a sidecut from the deisobutanizer. Hydrogenation of the sidecut saturates any olefins contained therein which would interfere with the isomerization of normal butanes. The saturated sidecut passes to an isomerization zone and a mixture of isobutane and normal butane is recycled to the deisobutanizer. In a highly perferred embodiment, spent catalyst from the isomerization zone fulfills the catalyst requirement of the dehydrogenation zone.
摘要翻译： 公开了一种用于从轻链烷烃和醇生产包括甲基叔丁基醚（MTBE）的醚的多步烃转化方法。 C4异构烷烃，正链烷烃，醚化再循环和丁烷异构化流出物的混合物进入脱异丁烷塔。 从分馏器中取出的正链烷烃被异构化并返回到分馏器中，并从分馏器中取出异链烷烃并进行脱氢。 所得烯烃进入醚化区以使异丁烯与C 2 -C 5醇反应。 未反应的链烷烃和烯烃包含进入脱异丁烷的醚化流出物。 正丁烷和烯烃作为脱离异构化剂的副反应物被排出。 旁路的氢化使其中含有的任何烯烃饱和会干扰正常丁烷的异构化。 饱和侧面经过异构化区，异丁烷和正丁烷的混合物再循环到脱异丁烷。 在高度推断的实施方案中，来自异构化区域的废催化剂满足脱氢区的催化剂需求。
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15.发明授权Preparing a light-olefin containing product stream from an oxygenate-containing feed steam using reactors directing a flow of a fluidized dual-function catalyst system 有权使用引导流化双功能催化剂体系流的反应器从含氧化合物的进料蒸汽制备含轻烯烃的产物流公开(公告)号：US08735639B2
公开(公告)日：2014-05-27
申请号：US12755632
申请日：2010-04-07
CPC分类号： C07C11/06 , C07C1/20 , C07C4/06 , C07C2529/40 , C07C2529/85
摘要： The present process provides a method for converting an oxygenate-containing feed stream to an olefin-containing product stream. The method includes: (1) providing a first fluidized catalytic reactor for converting methanol to propylene, the first reactor having a fluidized catalyst system comprising a first catalyst and a second catalyst; (2) providing a second fluidized catalytic reactor communicating with the first fluidized catalytic reactor for cracking heavy olefins having four carbon atoms or greater into propylene, the second reactor having the fluidized catalyst system; (3) providing an oxygenate containing feed to the first reactor; and (4) fluidizing the catalyst system with the oxygenate containing feed.
摘要翻译： 本发明方法提供了将含氧化合物的进料流转化为含烯烃的产物流的方法。 该方法包括：（1）提供用于将甲醇转化为丙烯的第一流化催化反应器，所述第一反应器具有包含第一催化剂和第二催化剂的流化催化剂体系; （2）提供与第一流化催化反应器连通的第二流化催化反应器，用于将具有四个或更多碳原子的重质烯烃裂解成丙烯，第二反应器具有流化催化剂体系; （3）向第一反应器提供含氧化合物进料; 和（4）用含氧化合物进料使催化剂体系流化。
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16.发明申请Preparing A Light-Olefin Containing Product Stream from an Oxygenate-Containing Feed Steam Using Reactors Directing a Flow of a Fluidized Dual-Function Catalyst System 有权使用引导流化双功能催化剂体系流动的反应器，从含氧化合物的进料蒸汽制备含有轻烯烃的轻质烯烃公开(公告)号：US20100204530A1
公开(公告)日：2010-08-12
申请号：US12755632
申请日：2010-04-07
IPC分类号： C07C1/20
CPC分类号： C07C11/06 , C07C1/20 , C07C4/06 , C07C2529/40 , C07C2529/85
摘要： The present invention provides a reactor system for converting an oxygenate-containing feed stream to an olefin-containing product stream. The system includes: (1) a first fluidized catalytic reactor for converting methanol to propylene, the first reactor having a fluidized catalyst system comprising a first catalyst and a second catalyst; (2) a second fluidized catalytic reactor communicating with the first fluidized catalytic reactor for cracking heavy olefins having four carbon atoms or greater into propylene, the second reactor having the fluidized catalyst system; (3) wherein the first catalyst is a non-zeolite molecular sieve catalyst; and (4) wherein the second catalyst is a zeolite molecular sieve catalyst.
摘要翻译： 本发明提供了一种用于将含氧化合物的进料流转化为含烯烃的产物流的反应器系统。 该系统包括：（1）用于将甲醇转化成丙烯的第一流化催化反应器，所述第一反应器具有包含第一催化剂和第二催化剂的流化催化剂体系; （2）与第一流化催化反应器连通的第二流化催化反应器，用于将具有四个或更多碳原子的重质烯烃裂解成丙烯，第二反应器具有流化催化剂体系; （3）其中第一催化剂是非沸石分子筛催化剂; 和（4）其中第二催化剂是沸石分子筛催化剂。
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17.发明授权Preparing a light-olefin containing product stream from an oxygenate-containing feed stream using reactors directing a flow of a fluidized dual-function catalyst system 有权使用引导流化双功能催化剂体系流的反应器从含氧化合物的进料流中制备含轻烯烃的产物流公开(公告)号：US07722825B1
公开(公告)日：2010-05-25
申请号：US11461288
申请日：2006-07-31
CPC分类号： C07C11/06 , C07C1/20 , C07C4/06 , C07C2529/40 , C07C2529/85
摘要： The present invention provides a reactor system for converting an oxygenate-containing feed stream to an olefin-containing product stream. The system includes: (1) a first fluidized catalytic reactor for converting methanol to propylene, the first reactor having a fluidized catalyst system comprising a first catalyst and a second catalyst; (2) a second fluidized catalytic reactor communicating with the first fluidized catalytic reactor for cracking heavy olefins having four carbon atoms or greater into propylene, the second reactor having the fluidized catalyst system; (3) wherein the first catalyst is a non-zeolite molecular sieve catalyst; and (4) wherein the second catalyst is a zeolite molecular sieve catalyst.
摘要翻译： 本发明提供了一种用于将含氧化合物的进料流转化为含烯烃的产物流的反应器系统。 该系统包括：（1）用于将甲醇转化成丙烯的第一流化催化反应器，所述第一反应器具有包含第一催化剂和第二催化剂的流化催化剂体系; （2）与第一流化催化反应器连通的第二流化催化反应器，用于将具有四个或更多碳原子的重质烯烃裂解成丙烯，第二反应器具有流化催化剂体系; （3）其中第一催化剂是非沸石分子筛催化剂; 和（4）其中第二催化剂是沸石分子筛催化剂。
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18.发明授权公开(公告)号：US06346645B1
公开(公告)日：2002-02-12
申请号：US09551642
申请日：2000-04-18
IPC分类号： C07C5112
摘要： Carbonyl compounds (e.g. acetone and acetaldehyde) are often present as impurities in oxygenated organic liquids such as acetic acid made by the carbonylation of methanol or in phenol produced by the oxidation of cumene. These impurities can render petrochemical products unsuitable for long-term storage or otherwise adversely affect downstream processing operations. It has now been found that detrimental carbonyl impurities can be easily removed from oxygenated organic liquids by contact with resins having amine functional groups.
摘要翻译： 羰基化合物（例如丙酮和乙醛）通常作为杂质存在于氧化的有机液体中，例如通过羰基化甲醇或通过异丙苯的氧化产生的苯酚制得的乙酸。 这些杂质可能导致石化产品不适合长期储存或以其他方式不利地影响下游加工操作。 现在已经发现，通过与具有胺官能团的树脂接触，可以容易地从有氧氧化有机液体中除去有害的羰基杂质。
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公开(公告)号：US5600052A
公开(公告)日：1997-02-04
申请号：US365622
申请日：1994-12-28
申请人： Christine J. B. Girod , William W. Levy , Peter R. Pujado , Jacques J. L. Romatier , Dominique J. J. M. Sabin , Paul A. Sechrist
发明人： Christine J. B. Girod , William W. Levy , Peter R. Pujado , Jacques J. L. Romatier , Dominique J. J. M. Sabin , Paul A. Sechrist
CPC分类号： F28F13/14 , B01J8/0207 , B01J8/0285 , B01J8/0403 , B01J8/0496 , B01J8/087 , B01J8/125 , F28D9/0006 , F28F3/04 , F28F9/0268 , B01J2208/00106 , B01J2208/0053 , B01J2208/022 , B01J2219/2453 , B01J2219/2459 , B01J2219/2464 , B01J2219/247 , B01J2219/2471 , B01J2219/2474 , B01J2219/2481 , B01J2219/2498 , Y02P20/582 , Y10S585/91 , Y10S585/911
摘要： A reactor arrangement and process for indirectly contacting a reactant stream with a heat exchange stream uses an arrangement of heat exchange plates to control temperature conditions by varying the heat transfer factor in different portions of a continuous channel defined by the heat exchange plates. The reactor arrangement and process of this invention may be used to operate a reactor under isothermal or other controlled temperature conditions. The variation in the heat transfer factor within a single heat exchange section is highly useful in maintaining a desired temperature profile in an arrangement having a cross-flow of heat exchange medium relative to reactants. The corrugations arrangement eliminates or minimizes the typical step-wise approach to isothermal conditions.
摘要翻译： 用于间接地将反应物流与热交换流接触的反应器装置和方法使用热交换板的布置来通过改变由热交换板限定的连续通道的不同部分中的传热因子来控制温度条件。 本发明的反应器装置和方法可用于在等温或其它受控温度条件下操作反应器。 在单个热交换部分内的热传递因子的变化对于在具有相对于反应物的热交换介质的交叉流动的布置中维持期望的温度分布非常有用。 波纹布置消除或最小化了等温条件的典型逐步方法。
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公开(公告)号：US5559274A
公开(公告)日：1996-09-24
申请号：US427783
申请日：1995-04-25
申请人： John I. Hammerman , Peter R. Pujado
发明人： John I. Hammerman , Peter R. Pujado
IPC分类号： C07C37/60
摘要： Phenol is produced from a hydrocarbon feedstock using a process combination offering unexpected synergy. Benzene is produced from the hydrocarbon feedstock using a highly selective aromatization catalyst which provides substantial quantities of high-purity hydrogen. The hydrogen is converted to hydrogen peroxide, which in turn is used to convert the benzene to phenol in high yield.
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