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公开(公告)号：US10023495B2
公开(公告)日：2018-07-17
申请号：US14075630
申请日：2013-11-08
Applicant: CORNING INCORPORATED
Inventor： Theresa Chang , Paul Stephen Danielson , Steven Edward DeMartino , Andrei Gennadyevich Fadeev , Robert Michael Morena , Santona Pal , John Stephen Peanasky , Robert Anthony Schaut , Christopher Lee Timmons , Natesan Venkataraman , Ronald Luce Verkleeren , Dana Craig Bookbinder
IPC: A61J1/14 , C03C17/42 , B65D25/14 , B65D23/08 , C03C17/00 , C03C15/02 , B65D1/02 , B65D25/34 , B32B17/06 , B65D1/40 , C03C17/30 , C03C17/32 , C03C21/00 , C09D179/08 , B65D23/02 , C03C17/34 , B65D65/42
Abstract: The glass containers described herein have at least two performance attributes selected from resistance to delamination, improved strength, and increased damage resistance. In one embodiment, a glass container may include a body having an inner surface, an outer surface and a wall thickness extending between the outer surface and the inner surface. A compressively stressed layer may extend from the outer surface of the body into the wall thickness. The compressively stressed layer may have a surface compressive stress greater than or equal to 150 MPa. A lubricous coating may be positioned around at least a portion of the outer surface of the body. The outer surface of the body with the lubricous coating may have a coefficient of friction less than or equal to 0.7.
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公开(公告)号：US09428302B2
公开(公告)日：2016-08-30
申请号：US14057697
申请日：2013-10-18
Applicant: Corning Incorporated
Inventor： Andrei Gennadyevich Fadeev , Theresa Chang , Dana Craig Bookbinder , Santona Pal , Chandan Kumar Saha , Steven Edward DeMartino , Christopher Lee Timmons , John Stephen Peanasky , Robert Anthony Schaut , Paul Stephen Danielson , Melinda Ann Drake , Robert Michael Morena , Kaveh Adib , James Patrick Hamilton , Susan Lee Schiefelbein
IPC: B28B11/00 , B28B21/00 , A47G19/22 , B65D23/08 , B32B17/06 , B65D1/40 , B65D25/14 , C03C17/00 , C03C17/30 , C03C17/32 , C03C17/42 , C03C21/00 , C08G73/10 , C09D179/08
CPC classification number: B65D23/0814 , A61J1/1468 , B32B17/06 , B65D1/40 , B65D25/14 , C03C3/087 , C03C17/005 , C03C17/30 , C03C17/32 , C03C17/3405 , C03C17/42 , C03C21/002 , C03C2217/78 , C03C2218/111 , C08G73/105 , C08G73/1071 , C09D179/08 , C08K5/544
Abstract: Delamination resistant glass containers with heat-tolerant coatings are disclosed. In one embodiment, a glass container may include a glass body having an interior surface, an exterior surface and a wall thickness extending from the exterior surface to the interior surface. At least the interior surface of the glass body is delamination resistant. The glass container may further include a heat-tolerant coating positioned on at least a portion of the exterior surface of the glass body. The heat-tolerant coating may be thermally stable at temperatures greater than or equal to 260° C. for 30 minutes.
Abstract translation: 公开了具有耐热涂层的耐剥落玻璃容器。 在一个实施例中，玻璃容器可以包括具有内表面，外表面和从外表面延伸到内表面的壁厚的玻璃体。 至少玻璃体的内表面具有防分层性。 玻璃容器还可以包括位于玻璃体的外表面的至少一部分上的耐热涂层。 耐热涂层可以在大于或等于260℃的温度下热稳定30分钟。
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公开(公告)号：US09340447B2
公开(公告)日：2016-05-17
申请号：US14701185
申请日：2015-04-30
Applicant: Corning Incorporated
Inventor： Paul Stephen Danielson , Steven Edward DeMartino , Melinda Ann Drake , Robert Michael Morena , Santona Pal , Robert Anthony Schaut
CPC classification number: C03C3/091 , A61J1/00 , C03C3/087 , C03C4/18 , C03C4/20 , C03C21/002 , C03C2204/00 , Y10T428/131 , Y10T428/1317 , Y10T428/26 , Y10T428/315
Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and pharmaceutical packaging formed from the same. According to one embodiment, a glass for pharmaceutical packaging includes from about 70 mol. % to about 80 mol. % SiO2; from about 4 mol. % to about 8 mol. % alkaline earth oxide, the alkaline earth oxide comprising MgO and CaO; X mol. % Al2O3, wherein X is from about 4 to about 8; and Y mol. % alkali oxide comprising non-zero amounts of Na2O and K2O, wherein Y is about 9-15 mol. % and a ratio of Y:X is greater than 1.
Abstract translation: 本文所述的实施方案涉及由其形成的化学和机械耐久的玻璃组合物和药物包装。 根据一个实施方案，用于药物包装的玻璃包括约70mol。 ％至约80mol。 ％SiO2; 约4mol。 ％至约8mol。 碱土金属氧化物，碱土金属氧化物包含MgO和CaO; X mol。 ％Al 2 O 3，其中X为约4至约8; 和Y mol。 包含非零量Na 2 O和K 2 O的碱金属氧化物，其中Y为约9-15mol。 ％，Y：X的比例大于1。
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公开(公告)号：US20150079318A1
公开(公告)日：2015-03-19
申请号：US14551773
申请日：2014-11-24
Applicant: Corning Incorporated
Inventor： Paul Stephen Danielson , Steven Edward DeMartino , Melinda Ann Drake , Robert Michael Morena , Santona Pal , Robert Anthony Schaut
CPC classification number: C03C3/091 , A61J1/00 , C03C3/087 , C03C4/18 , C03C4/20 , C03C21/002 , C03C2204/00 , Y10T428/131 , Y10T428/1317 , Y10T428/26 , Y10T428/315
Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and glass articles formed from the same. In another embodiment, a glass composition may include from about 70 mol. % to about 80 mol. % SiO2; from about 3 mol. % to about 13 mol. % alkaline earth oxide; X mol. % Al2O3; and Y mol. % alkali oxide. The alkali oxide may include Na2O in an amount greater than about 8 mol. %. A ratio of Y:X may be greater than 1 and the glass composition may be free of boron and compounds of boron. In some embodiments, the glass composition may also be free of phosphorous and compounds of phosphorous. Glass articles formed from the glass composition may have at least a class S3 acid resistance according to DIN 12116, at least a class A2 base resistance according to ISO 695, and a type HGA1 hydrolytic resistance according to ISO 720.
Abstract translation: 本文所述的实施方案涉及由其形成的化学和机械耐久的玻璃组合物和玻璃制品。 在另一个实施方案中，玻璃组合物可以包含约70mol。 ％至约80mol。 ％SiO2; 约3mol。 ％至约13mol。 ％碱土金属氧化物; X mol。 ％Al2O3; 和Y mol。 ％碱金属氧化物。 碱金属氧化物可以包括大于约8mol的量的Na 2 O。 ％。 Y：X的比例可以大于1，玻璃组合物可以不含硼和硼化合物。 在一些实施方案中，玻璃组合物还可以不含磷和磷的化合物。 由玻璃组合物形成的玻璃制品可以具有根据DIN 12116的至少S3级耐酸性，至少根据ISO 695的A2级耐碱性和根据ISO 720的HGA1型耐水解性。
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公开(公告)号：US20140151371A1
公开(公告)日：2014-06-05
申请号：US14075605
申请日：2013-11-08
Applicant: Corning Incorporated
Inventor： Theresa Chang , Paul Stephen Danielson , Steven Edward DeMartino , Andrei Gennadyevich Fadeev , Robert Michael Morena , Santona Pal , John Stephen Peanasky , Robert Anthony Schaut , Natesan Venkataraman , Ronald Luce Verkleeran
IPC: B65D25/34
CPC classification number: C03C17/42 , A61J1/1468 , B32B17/06 , B65D1/0207 , B65D1/0215 , B65D1/40 , B65D23/02 , B65D23/0814 , B65D23/0821 , B65D25/14 , B65D25/34 , B65D65/42 , C03C15/02 , C03C17/00 , C03C17/005 , C03C17/30 , C03C17/32 , C03C17/3405 , C03C21/002 , C03C2217/78 , C03C2218/111 , C09D179/08 , Y10T428/13 , Y10T428/131 , Y10T428/1317 , Y10T428/315
Abstract: The glass containers described herein have at least two performance attributes selected from resistance to delamination, improved strength, and increased damage resistance. In one embodiment, a glass container with resistance to delamination and improved strength may include a body having an inner surface, an outer surface and a wall thickness extending between the outer surface and the inner surface. At least the inner surface of the body may have a delamination factor less than or equal to 10. The glass container may further include a compressively stressed layer extending from the outer surface of the body into the wall thickness. The compressively stressed layer may have a surface compressive stress greater than or equal to 150 MPa.
Abstract translation: 本文所述的玻璃容器具有至少两种性能属性，其选自抗分层，改善的强度和增加的耐损伤性。 在一个实施例中，具有耐分层性和改善强度的玻璃容器可以包括具有内表面，外表面和在外表面和内表面之间延伸的壁厚的主体。 至少本体的内表面可以具有小于或等于10的分层因子。玻璃容器还可以包括从主体的外表面延伸到壁厚的压缩应力层。 压应力层可具有大于或等于150MPa的表面压应力。
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Patent Agency Ranking
公开(公告)号：US20130344263A1
公开(公告)日：2013-12-26
申请号：US14011376
申请日：2013-08-27
Applicant: Corning Incorporated
Inventor： Paul Stephen Danielson , Steven Edward DeMartino , Melinda Ann Drake , Robert Michael Morena , Santona Pal , Robert Anthony Schaut
CPC classification number: C03C3/091 , A61J1/00 , C03C3/087 , C03C4/18 , C03C4/20 , C03C21/002 , C03C2204/00 , Y10T428/131 , Y10T428/1317 , Y10T428/26 , Y10T428/315
Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and glass articles formed from the same. In another embodiment, a glass composition may include from about 70 mol. % to about 80 mol. % SiO2; from about 3 mol. % to about 13 mol. % alkaline earth oxide; X mol. % Al2O3; and Y mol. % alkali oxide. The alkali oxide may include Na2O in an amount greater than about 8 mol. %. A ratio of Y:X may be greater than 1 and the glass composition may be free of boron and compounds of boron. In some embodiments, the glass composition may also be free of phosphorous and compounds of phosphorous. Glass articles formed from the glass composition may have at least a class S3 acid resistance according to DIN 12116, at least a class A2 base resistance according to ISO 695, and a type HGA1 hydrolytic resistance according to ISO 720.
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公开(公告)号：US12275671B2
公开(公告)日：2025-04-15
申请号：US17699447
申请日：2022-03-21
Applicant: CORNING INCORPORATED
Inventor： Paul Stephen Danielson , Steven Edward DeMartino , Melinda Ann Drake , Robert Michael Morena , Santona Pal , Robert Anthony Schaut
Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and glass articles formed from the same. In embodiments, the glass composition may include 74-78 mol. % SiO2; X mol. % Al2O3, wherein X is 5-7; alkaline earth oxide comprising MgO and CaO, wherein: CaO is 0.1-1.0 mol. %; MgO is 4-7 mol. %; and a ratio (CaO (mol. %)/(CaO (mol. %)+MgO (mol. %)) is less than or equal to 0.5. The glass composition may further include Y mol. % alkali oxide, wherein the alkali oxide comprises 9-13 mol. % Na2O and less than or equal to 0.4 mol. % of a fining agent. The glass composition may be free of boron and compounds of boron.
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公开(公告)号：US11951072B2
公开(公告)日：2024-04-09
申请号：US16653974
申请日：2019-10-15
Applicant: CORNING INCORPORATED
Inventor： Dana Craig Bookbinder , Theresa Chang , Paul Stephen Danielson , Steven Edward DeMartino , Andrei Gennadyevich Fadeev , Robert Michael Morena , Santona Pal , John Stephen Peanasky , Robert Anthony Schaut , Christopher Lee Timmons , Natesan Venkataraman , Ronald Luce Verkleeren
IPC: A61J1/14 , A61J1/06 , B32B17/06 , B65D1/02 , B65D1/40 , B65D23/02 , B65D23/08 , B65D25/14 , B65D25/34 , B65D65/42 , C03B23/04 , C03C15/02 , C03C17/00 , C03C17/22 , C03C17/30 , C03C17/32 , C03C17/34 , C03C17/42 , C03C21/00 , C09D179/08
CPC classification number: A61J1/1468 , A61J1/065 , B32B17/06 , B65D1/0207 , B65D1/0215 , B65D1/40 , B65D23/02 , B65D23/0814 , B65D23/0821 , B65D25/14 , B65D25/34 , B65D65/42 , C03B23/04 , C03C15/02 , C03C17/005 , C03C17/22 , C03C17/30 , C03C17/32 , C03C17/3405 , C03C17/42 , C03C21/002 , C09D179/08 , C03C2217/78 , C03C2218/111 , Y10T428/13 , Y10T428/131 , Y10T428/1317 , Y10T428/24802 , Y10T428/315
Abstract: A coated glass pharmaceutical package includes a glass body having a Type 1 chemical durability according to USP 660, at least a class A2 base resistance or better according to ISO 695, and at least a type HGB2 hydrolytic resistance or better according to ISO 719, the glass body having an interior surface and an exterior surface and a wall extending therebetween. A lubricous coating having a thickness of less than or equal to 90 nm may be positioned on at least a portion of the exterior surface of the glass body but not on any portion of the interior surface. The portion of the coated glass package with the lubricous coating comprises a coefficient of friction that is at least 20% less than an uncoated glass package and the coefficient of friction does not increase by more than 30% after undergoing a depyrogenation cycle including exposure to a temperature of 250° C. for a time period of 30 minutes. A horizontal compression strength of the coated glass package is at least 10% greater than an uncoated glass package and the horizontal compression strength is not reduced by more than 20% after undergoing the depyrogenation cycle including exposure to a temperature of 250° C. for a time period of 30 minutes and then being abraded. The lubricous coating comprises a polymer.
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公开(公告)号：US11124328B2
公开(公告)日：2021-09-21
申请号：US15968583
申请日：2018-05-01
Applicant: CORNING INCORPORATED
Inventor： Kaveh Adib , Paul Stephen Danielson , James Patrick Hamilton , Robert Michael Morena , John Stephen Peanasky , Robert Anthony Schaut , Susan Lee Schiefelbein
Abstract: Embodiments of glass containers resistant to delamination and methods for forming the same are disclosed. According to one embodiment, a delamination resistant glass container may include a glass article having a body extending between an interior surface and an exterior surface. The body defines an interior volume. The body may include an interior region extending from 10 nm below the interior surface of the body into a thickness of the body. The interior region has a persistent layer homogeneity such that the body is resistant to delamination.
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公开(公告)号：US10786431B2
公开(公告)日：2020-09-29
申请号：US16185828
申请日：2018-11-09
Applicant: CORNING INCORPORATED
Inventor： Theresa Chang , Paul Stephen Danielson , Steven Edward DeMartino , Andrei Gennadyevich Fadeev , Robert Michael Morena , Santona Pal , John Stephen Peanasky , Robert Anthony Schaut , Christopher Lee Timmons , Natesan Venkataraman , Ronald Luce Verkleeren
IPC: A61J1/14 , B65D23/08 , C03C17/22 , B65D25/14 , B65D1/40 , C03C17/00 , C03C21/00 , B65D23/02 , C03C17/34 , A61J1/06 , C03C15/02 , B65D1/02 , B65D25/34 , B32B17/06 , C03C17/30 , C03C17/32 , C03C17/42 , C09D179/08 , B65D65/42
Abstract: A delamination resistant glass pharmaceutical container may include a glass body comprising a borosilicate glass having a Type 1 chemical durability according to USP . At least an inner surface of the glass body may have a delamination factor less than or equal to 10. A thermally stable coating may be positioned around at least a portion of the outer surface of the glass body. The thermally stable coating may be an outermost coating on the outer surface of the glass body and the outer surface of the glass body with the thermally stable coating has a coefficient of friction less than or equal to 0.7. The thermally stable coating comprising at least one of a metal nitride coating, a metal oxide coating, a metal sulfide coating, SiO2, diamond-like carbon, graphene, and a carbide coating.
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