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    ROOM TEMPERATURE CURABLE POLYMERS AND PRECURSORS THEREOF
    11.
    发明申请
    ROOM TEMPERATURE CURABLE POLYMERS AND PRECURSORS THEREOF 有权

    公开(公告)号：US20100249357A1

    公开(公告)日：2010-09-30

    申请号：US12668609

    申请日：2008-07-10

    申请人： Paul J. Popa ,  Zenon Lysenko ,  David A. Babb ,  William A. Koonce ,  Gary E. Spilman

    发明人： Paul J. Popa ,  Zenon Lysenko ,  David A. Babb ,  William A. Koonce ,  Gary E. Spilman

    IPC分类号： C08G18/42 ,  C08G63/00

    CPC分类号： C08G18/4288 ,  C08G18/4269 ,  C08G18/4277 ,  C08G18/718 ,  C08G2190/00 ,  C09J175/06

    摘要： A polyester polyol, referred to hereinafter as a MHMS polyol comprises fatty acid based mer units wherein at least about 80 weight percent of the fatty acid based mer units are from methyl 9 (10) hydroxymethylstearate, or is prepared from an oil having fatty acids or fatty acid esters which are at least about 80 weight percent oleic acid or esters thereof and which has an average hydroxyl functionality of from 1.5 to 4. A reaction product, referred to herein after as MHMS alkoxysilane prepolymer, is produced from at least one such MHMS polyol and at least one isocyanate functional silane. The prepolymer is moisture cured to form a silylated MHMS polymer. The process of preparing a MHMS polyol comprises (A) reacting a fatty acid ester wherein at least about 80 weight percent of the fatty acid esters are methyl 9 (10) hydroxymethylstearate, or are prepared from an oil having fatty acids or fatty acid esters which are at least about 80 weight percent oleic acid or esters thereof with an initiator having at least 2 reactive groups selected from primary hydroxyl groups, amine groups, terminal isocyanate groups, terminal carbonyl groups or a combination thereof. The process of preparing at least one MHMS alkoxysilane prepolymer comprises steps of: (a) supplying at least one MHMS polyol; (b) supplying at least one isocyanate functional silane and (c) admixing the MHMS polyol and isocyanate functional silane or combination thereof, optionally in the presence of at least one catalyst to produce at least one MHMS alkoxysilane prepolymer. A process of preparing at least one silylated MHMS polymer comprises steps of: (a) supplying at least one MHMS alkoxysilane prepolymer; and (b) exposing it to moisture under conditions such that at least one silylated MHMS polymer is formed. Articles comprising the polyol, prepolymer, or polymer include elastomers, sealants, adhesives, coatings and the like.

    POLYETHER NATURAL OIL POLYOLS AND POLYMERS THEREOF
    19.
    发明申请
    POLYETHER NATURAL OIL POLYOLS AND POLYMERS THEREOF 审中-公开
    聚醚天然油多元醇及其聚合物

    公开(公告)号：US20110015293A1

    公开(公告)日：2011-01-20

    申请号：US12933293

    申请日：2009-03-20

    申请人： Hongming Ma ,  Jorge Jimenez ,  Dwight D. Latham ,  David A. Babb ,  Imran Munshi ,  Christopher Noakes

    发明人： Hongming Ma ,  Jorge Jimenez ,  Dwight D. Latham ,  David A. Babb ,  Imran Munshi ,  Christopher Noakes

    IPC分类号： C08J9/00 ,  C07C59/147 ,  C08G18/72

    CPC分类号： C08G18/4804 ,  C08G18/4891 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

    摘要： A polyether NOP comprises at least two natural oil moieties separated by a molecular structure having at least about 19 ether groups or by a polyether molecular structure having an equivalent weight of at least about 480, said polyol referred to hereinafter as a polyether NOP. The polyether NOP is preferably prepared by a process comprising admixing at least one polyether initiator having an equivalent weight of at least about 480 or at least about 19 ether groups per active hydrogen group with at least one natural oil or derivative thereof under reaction conditions such that at least one polyether NOP is formed. The invention includes reaction products of the polyether NOP or combinations thereof, optionally and preferably in admixture with at least one other polyol which preferably includes at least one polyether polyol and at least one monomer reactive therewith, preferably at least one polyisocyanate to form a polyurethane, preferably in the form of a foam, especially a high resilience foam. The invention includes articles comprising at least one polyether NOP, at least one polymer thereof, or at least one foam thereof.

    摘要翻译： 聚醚NOP包含至少两个通过具有至少约19个醚基团的分子结构分开的天然油部分，或通过当量为至少约480的聚醚分子结构，所述多元醇在下文中称为聚醚NOP。 聚醚NOP优选通过包括在反应条件下将每个活性氢基团当量至少约480或至少约19个醚基团的至少一种聚醚引发剂与至少一种天然油或其衍生物混合的方法制备，使得 形成至少一种聚醚NOP。 本发明包括聚醚NOP或其组合的反应产物，任选和优选与至少一种其它多元醇混合，其中多元醇优选包括至少一种聚醚多元醇和至少一种与其反应的单体，优选至少一种多异氰酸酯以形成聚氨酯， 优选为泡沫形式，特别是高弹性泡沫。 本发明包括包含至少一种聚醚NOP，至少一种聚合物或其至少一种泡沫的制品。

    Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom
    20.
    发明授权
    Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom 失效
    包括羟基或静止反应性官能团的膨胀的阴离子化合物及其催化剂活化剂

    公开(公告)号：US06627573B2

    公开(公告)日：2003-09-30

    申请号：US09904422

    申请日：2001-07-12

    申请人： David A. Babb ,  Richard E. Campbell, Jr. ,  David R. Neithamer ,  Grant B. Jacobsen ,  Edmund M. Carnahan

    发明人： David A. Babb ,  Richard E. Campbell, Jr. ,  David R. Neithamer ,  Grant B. Jacobsen ,  Edmund M. Carnahan

    IPC分类号： B01J3000

    CPC分类号： C08F10/00 ,  C07F5/027 ,  C07F5/062 ,  C07F5/066 ,  C07F7/0803 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65927 ,  C08F210/16 ,  C08F4/61908 ,  C08F4/65908 ,  C08F210/14 ,  C08F2500/12

    摘要： A compound useful as a cocatalyst or cocatalyst component, especially for use as an addition polymerization catalyst compound, corresponding to the formula: (A*+a)b(Z*J*j)−cd, wherein: A* is a cation of from 1 to 80, preferably 1 to 60 atoms, not counting hydrogen atoms, said A* having a charge +a, Z* is an anion group of from 1 to 50, preferably 1 to 30 atoms, not counting hydrogen atoms, further containing two or more Lewis base sites; J* independently each occurrence is a Lewis acid of from 1 to 80, preferably 1 to 60 atoms, not counting hydrogen atoms, coordinated to at least one Lewis base site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is a number from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d, and provided further that one or more of A*, Z* or J* comprises a hydroxyl group or a polar group containing quiescent reactive functionality.

    摘要翻译： 用作助催化剂或助催化剂组分的化合物，特别是用作加成聚合催化剂化合物，其对应于下式：其中：A *是不计氢原子的1至80个，优选1至60个原子的阳离子，所述化合物 A *具有电荷+ a，Z *是1至50个，优选1至30个原子的阴离子基团，不计算氢原子，进一步含有两个或更多个路易斯碱基位点; J *各自独立地为路易斯酸 1至80个，优选1至60个原子，不计数氢原子，与Z *的至少一个路易斯碱碱基位点配位，并且任选地两个或多个这样的J *基团可以连接在具有多个路易斯酸官能团的部分中， j是2至12的数字，a，b，c和d是1至3的整数，条件是axb等于cxd，进一步提供A *，Z *或J *中的一个或多个包括 羟基或含有静止反应性官能团的极性基团。