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11.发明授权Use of polymer dispersions as binding agents for sealing compounds and coating compounds 有权使用聚合物分散体作为密封化合物和涂料化合物的粘合剂公开(公告)号：US06242515B1
公开(公告)日：2001-06-05
申请号：US09284457
申请日：1999-07-26
Applicant: Cheng-Le Zhao , Eckehardt Wistuba , Joachim Roser , Paul Fitzgerald , Jan Spitzer
Inventor： Cheng-Le Zhao , Eckehardt Wistuba , Joachim Roser , Paul Fitzgerald , Jan Spitzer
IPC: C08K524
CPC classification number: C09K3/10 , C09D5/34 , C09D133/062 , C09K2200/0625 , Y10T428/2965 , C08L2666/36 , C08L2666/54
Abstract: The present invention relates to the use of compositions comprising at least one aqueous polymer dispersion wherein the polymer has carbonyl or oxirane groups (component a)) and at least one compound with at least two NH2 groups per molecule as sealing or coating compositions, especially for substrates with a hydrophobic surface. The present invention further relates to coating compositions containing such binder formulations.
Abstract translation: 本发明涉及包含至少一种含水聚合物分散体的组合物的用途，其中聚合物具有羰基或环氧乙烷基团（组分a））和至少一种每分子具有至少两个NH 2基团的化合物作为密封或涂料组合物，特别是用于 具有疏水性表面的底物。 本发明还涉及含有这种粘合剂制剂的涂料组合物。
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公开(公告)号：US08084631B2
公开(公告)日：2011-12-27
申请号：US12121609
申请日：2008-05-15
Applicant: Yeonsuk Roh , Rajesh Kumar , Cheng-Le Zhao , David Kaczan , Theodore M. Smiecinski
Inventor： Yeonsuk Roh , Rajesh Kumar , Cheng-Le Zhao , David Kaczan , Theodore M. Smiecinski
IPC: C07D303/02
CPC classification number: C08G18/7621 , C08G18/36 , C08G18/4081 , C08G18/4829 , C08G18/64 , C08G2101/0008 , C08G2101/0083 , C08L83/00 , C11C3/006
Abstract: A polyol includes the reaction product of an epoxidized oil and an organic acid. The epoxidized oil and the organic acid are reacted in the presence of a Lewis base catalyst including at least one of a phosphorous atom or a nitrogen atom. The polyol is formed by a method that includes the step of reacting the epoxidized oil with the organic acid in the presence of the Lewis base catalyst.
Abstract translation: 多元醇包括环氧化油和有机酸的反应产物。 在包含磷原子或氮原子中的至少一种的路易斯碱催化剂的存在下使环氧化油和有机酸反应。 通过包含在路易斯碱催化剂存在下使环氧化油与有机酸反应的步骤的方法形成多元醇。
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公开(公告)号：US07705082B2
公开(公告)日：2010-04-27
申请号：US11912289
申请日：2006-01-06
Applicant: Robert Shane Porzio , Cheng-Le Zhao , Michael Anchor
Inventor： Robert Shane Porzio , Cheng-Le Zhao , Michael Anchor
IPC: C08K3/26
Abstract: An aqueous latex coating composition and method of making an aqueous latex coating composition that comprises at least one oligomeric ethylene glycol derivative having the structure RO—(CH2—CH2—O—)n—H, at least one latex polymer, and water, wherein R is H or C1-C4 alkyl and preferably H, and n is from 3 to 9, preferably from 3 to 8, and more preferably from 3 to 6. The oligomeric ethylene glycol derivative functions as both a coalescing solvent and freeze-thaw stabilizer without contributing to the VOC content of the composition.
Abstract translation: 一种水性胶乳涂料组合物和制备水性胶乳涂料组合物的方法，其包含至少一种具有结构RO-（CH 2 -CH 2 -O-）n -H的至少一种乙二醇衍生物，至少一种胶乳聚合物和水，其中 R为H或C 1 -C 4烷基，优选为H，n为3至9，优选为3至8，更优选为3至6.低聚乙二醇衍生物用作聚结溶剂和冻融稳定剂 而不会对组合物的VOC含量作出贡献。
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公开(公告)号：US07705081B2
公开(公告)日：2010-04-27
申请号：US11112801
申请日：2005-04-22
Applicant: Robert Shane Porzio , Cheng-Le Zhao , Michael J. Anchor
Inventor： Robert Shane Porzio , Cheng-Le Zhao , Michael J. Anchor
IPC: C08K3/26
CPC classification number: C09D5/024
Abstract: An aqueous latex coating composition and method of making an aqueous latex coating composition that comprises at least one oligomeric ethylene glycol derivative having the structure RO—(CH2—CH2—O—)n—H, at least one latex polymer, and water, wherein R is H or Cl-C4 alkyl and preferably H, and n is from 3 to 9, preferably from 3 to 8, and more preferably from 3 to 6. The oligomeric ethylene glycol derivative functions as both a coalescing solvent and freeze-thaw stabilizer without contributing to the VOC content of the composition.
Abstract translation: 一种水性胶乳涂料组合物和制备水性胶乳涂料组合物的方法，其包含至少一种具有结构RO-（CH 2 -CH 2 -O-）n -H的至少一种乙二醇衍生物，至少一种胶乳聚合物和水，其中 R为H或C 1 -C 4烷基，优选为H，n为3至9，优选3至8，更优选为3至6.低聚乙二醇衍生物用作聚结溶剂和冻融稳定剂 而不会对组合物的VOC含量作出贡献。
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公开(公告)号：US20080188603A1
公开(公告)日：2008-08-07
申请号：US11912289
申请日：2006-01-06
Applicant: Robert Shane Porzio , Cheng-Le Zhao , Michael J. Anchor
Inventor： Robert Shane Porzio , Cheng-Le Zhao , Michael J. Anchor
Abstract: An aqueous latex coating composition and method of making an aqueous latex coating composition that comprises at least one oligomeric ethylene glycol derivative having the structure RO—(CH2—CH2—O—)n—H, at least one latex polymer, and water, wherein R is H or C1-C4 alkyl and preferably H, and n is from 3 to 9, preferably from 3 to 8, and more preferably from 3 to 6. The oligomeric ethylene glycol derivative functions as both a coalescing solvent and freeze-thaw stabilizer without contributing to the VOC content of the composition.
Abstract translation: 一种水性胶乳涂料组合物和制备水性胶乳涂料组合物的方法，所述组合物包含至少一种具有结构RO-（CH 2 CH 2 -CH 2）的低聚乙二醇衍生物 - ）N - H，至少一种胶乳聚合物和水，其中R是H或C 1 -C 4烷基，优选H ，n为3〜9，优选为3〜8，更优选为3〜6。低聚乙二醇衍生物用作聚结溶剂和冻融稳定剂两者，而无助于组合物的VOC含量。
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Patent Agency Ranking
16.发明申请Low-voc aqueous coating compositions with excellent freeze-thaw stability 审中-公开具有优异的冻融稳定性的低声级含水涂料组合物公开(公告)号：US20060052502A1
公开(公告)日：2006-03-09
申请号：US10515184
申请日：2003-05-13
Applicant: Cheng-Le Zhao , Terri Cunningham , Li Zhuo , Konrad Roschmann , Joerg Leuninger , Rolf Dersch
Inventor： Cheng-Le Zhao , Terri Cunningham , Li Zhuo , Konrad Roschmann , Joerg Leuninger , Rolf Dersch
IPC: C08K3/26
Abstract: The present invention is an aqueous coating composition having excellent freeze-thaw stability and a low-VOC content. The aqueous coating composition of the invention includes at least one latex polymer derived from at least one monomer and at least one polymerizable alkoxylated surfactant, at least one pigment, and water. In accordance with the invention, less than 3.0% by weight of anti-freeze agents based on the total weight of the aqueous coating composition are used in the composition. The present invention also includes a method of preparing an aqueous coating composition such as a latex paint including the above components.
Abstract translation: 本发明是具有优异的冻融稳定性和低VOC含量的水性涂料组合物。 本发明的水性涂料组合物包括至少一种衍生自至少一种单体和至少一种可聚合烷氧基化表面活性剂，至少一种颜料和水的胶乳聚合物。 根据本发明，在组合物中使用基于水性涂料组合物总重量的小于3.0重量％的防冻剂。 本发明还包括制备水性涂料组合物的方法，例如包括上述组分的乳胶漆。
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17.发明授权Aqueous polymer dispersion containing an emulsifier with phosphate groups 有权含有具有磷酸基团的乳化剂的聚合物水分散体分散体公开(公告)号：US06348528B1
公开(公告)日：2002-02-19
申请号：US09623459
申请日：2000-09-12
Applicant: Bernhard Schlarb , Gregor Ley , Cheng-Le Zhao , Alexander Haunschild , Maria Gyopar Rau , Rolf Dersch
Inventor： Bernhard Schlarb , Gregor Ley , Cheng-Le Zhao , Alexander Haunschild , Maria Gyopar Rau , Rolf Dersch
IPC: C08K552
Abstract: Aqueous polymer dispersion comprising from 0.1 to 10 parts by weight per 100 parts by weight of polymer of an emulsifier A) having a phosphate group, wherein said emulsifier consists at least 50% by weight of ethylene oxide and propylene oxide groups and the proportion of the ethylene oxide groups and propylene oxide groups is in each case at least 10% by weight, based on the overall amount of the ethylene oxide and propylene oxide groups.
Abstract translation: 含水聚合物分散体包含0.1至10重量份/ 100重量份具有磷酸基团的乳化剂A）的聚合物，其中所述乳化剂为至少50重量％的环氧乙烷和环氧丙烷基团， 在每种情况下，环氧乙烷基团和环氧丙烷基团基于环氧乙烷和环氧丙烷基团的总量至少为10重量％。
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18.发明授权Process for production of polymer dispersions containing an acetoacetate moiety 有权制备含有乙酰乙酸酯部分的聚合物分散体的方法公开(公告)号：US07999050B2
公开(公告)日：2011-08-16
申请号：US11502500
申请日：2006-08-10
Applicant: Cheng-Le Zhao
Inventor： Cheng-Le Zhao
CPC classification number: C08F246/00
Abstract: A method of making a composition comprising reacting, in a reactor, a non-halogenated acetoacetate group containing monomer, at least one additional monomer, and a base, wherein at least a portion of the base is fed to the reactor during reaction. Also, a composition comprising an aqueous polymer dispersion that is a product of a method comprising reacting a non-halogenated acetoacetate moiety containing monomer, at least one additional monomer, and a base, wherein the base is fed to the reaction during reaction, wherein the composition has a lower viscosity than a second composition, wherein the second composition is prepared from the same materials as the composition, and the second composition is made by a method wherein the base is added to the second composition after a reaction to form the second composition.
Abstract translation: 一种制备组合物的方法，包括在反应器中使含有非卤代乙酰乙酸酯基团的单体，至少一种另外的单体和碱反应，其中至少一部分碱在反应期间进料到反应器中。 此外，包含水性聚合物分散体的组合物，其是包含使含有非卤代乙酰乙酸酯部分的单体，至少一种另外的单体和碱反应的方法的产物，其中在反应期间将碱加入到反应中，其中 组合物具有比第二组合物更低的粘度，其中第二组合物由与组合物相同的材料制备，第二组合物通过以下方法制备，其中在反应后将碱添加到第二组合物中以形成第二组合物 。
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19.发明授权公开(公告)号：US07612126B2
公开(公告)日：2009-11-03
申请号：US10580250
申请日：2004-12-01
Applicant: Konrad Roschmann , Joerg Leuninger , Rolf Dersch , Cheng-Le Zhao , Li Zhuo , Terri A. Cunningham
Inventor： Konrad Roschmann , Joerg Leuninger , Rolf Dersch , Cheng-Le Zhao , Li Zhuo , Terri A. Cunningham
IPC: C08L83/00
CPC classification number: C09D151/003 , C08F265/06 , C08K3/013 , C08F2/22
Abstract: The present invention relates to an aqueous coating composition having excellent freeze-thaw stability and a low-VOC content, comprising a multi-stage polymer dispersion comprising (a) an inner phase comprising at least one latex polymer derived from at least one monomer and at least one polymerizable alkoxylated surfactant having the structure: R1—R2 wherein R1 is an allyl group selected from the group consisting of CH3—CH═CH— and CH2═CH—CH2—, or an acrylic group and R2 is a radical comprising at least two carbon atoms and at least one oxyethylene or oxypropylene unit; (b) an outer phase having a glass transition temperature of from 30° C. to 110° C. containing at least one ethylenic unsaturated monomer (c) at least one pigment; (d) water; and (e) less than 3.0% by weight based on the total weight of the aqueous coating composition of anti-freeze agents.
Abstract translation: 本发明涉及具有优异的冻融稳定性和低VOC含量的水性涂料组合物，其包含多级聚合物分散体，其包含（a）内相，其包含至少一种衍生自至少一种单体的胶乳聚合物和 至少一种具有以下结构的可聚合的烷氧基化表面活性剂：其中R 1是选自CH 3 -CH-CH-和CH 2 -CH-CH 2 - 或丙烯酸基的烯丙基，R 2是至少包含 两个碳原子和至少一个氧化乙烯或氧化丙烯单元; （b）含有至少一种烯属不饱和单体（c）至少一种颜料的玻璃化转变温度为30℃至110℃的外相; （d）水; 和（e）基于抗冻剂的水性涂料组合物的总重量小于3.0重量％。
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公开(公告)号：US06492451B1
公开(公告)日：2002-12-10
申请号：US09554073
申请日：2000-05-11
Applicant: Rolf Dersch , Joachim Roser , Bernhard Schlarb , Cheng-Le Zhao
Inventor： Rolf Dersch , Joachim Roser , Bernhard Schlarb , Cheng-Le Zhao
IPC: C08K318
CPC classification number: C08F220/18 , C03C17/009 , C08F230/02 , C09D133/062 , C09D143/02 , C08L2666/54
Abstract: A pigment-comprising formulation for coating substrates, comprising: (i) an aqueous dispersion of at least one water-insoluble polymer P which has phosphonate groups, as a binder, said polymer P having a glass transition temperature Tg in the range of −60° to 80° C., (ii) at least one inorganic pigment, (iii) optionally, one or more inorganic fillers, and (iv) at least one auxiliary, wherein water-insoluble polymer P is obtained by free-radical aqueous emulsion polymerization of ethylenically unsaturated monomers comprising: 90 to 99.9% by weight of at least one monomer a, which is selected from the group consisting of vinylaromatic monomers, the esters of acrylic acid with C1-C12-alkanols, the vinyl esters of aliphatic C1-C12-monocarboxylic acids, ethylene and vinylchloride, and 0.1 to 10% by weight of at least one phosphonate group containing monomer.
Abstract translation: 一种用于涂布基材的含颜料的制剂，包括：（i）至少一种具有膦酸酯基的水不溶性聚合物P的水性分散体作为粘合剂，所述聚合物P的玻璃化转变温度Tg在-60 （ii）至少一种无机颜料，（iii）任选的一种或多种无机填料，和（iv）至少一种助剂，其中水不溶性聚合物P由自由基水乳液获得 烯属不饱和单体的聚合包括：90-99.9重量％的至少一种单体a，其选自乙烯基芳族单体，丙烯酸与C 1 -C 12 - 链烷醇的酯，脂族C1- C12-一元羧酸，乙烯和氯乙烯，和0.1〜10重量％的至少一个含膦酸酯基团的单体。
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