摘要:
The present invention relates to trans-olefin compounds represented by the general formula (1) useful as an ingredient of liquid crystal composition, trans-olefin compounds useful as intermediate of pesticides, medical drugs, liquid crystal materials and the like, a process for producing those trans-olefin compounds, a liquid crystal composition containing the trans-olefin compound as an active ingredient, and a liquid crystal element using the liquid crystal composition. ##STR1## (In the general formula (1), R.sup.1, A.sup.1, A.sup.2, A.sup.3, Z and R.sup.2 are same as defined in the specification. Also, m, p, q, n, r, s and t are each an integer as defined in the specification.)
摘要:
A ferroelectric chiral smectic liquid crystal mixture comprising at least one compound of the formula (I): wherein R11 and R12 represent, independently each other, a C1-C20 alkyl, alkoxy or alkoxyalkyl group which may be substituted by at least one halogen atom and may have an unsaturated bond; A11, A12 and A13 represent, independently each other, a phenylene group which may be substituted by a fluorine atom, or the like; * indicates an asymmetric carbon atom; Z is a hydrogen atom or a fluorine atom; n is an integer of 0 to 10; r, s, t and u are each 0 or 1, provided that when u is 1, the compound (I) is a trans-olefin, and at least one compound of the formula (II): wherein R21 is a saturated or unsaturated C3-C20 alkyl group or a saturated or unsaturated C3-C20 alkoxyalkyl group; A21, A22 and A23 represent, independently each other, a phenylene group which may be substituted by a fluorine atom or the like; X2 is —C≡C— or the like; Z is a hydrogen atom or a fluorine atom; n is an integer of 1 to 10; m is 0 or 1; and * indicates an asymmetric carbon atom, which liquid crystal mixture has a high response speed and a small dependency of &tgr;-Vmin characteristic on temperature and a wide temperature driving margin.
摘要:
Provide is a novel phenylacetylene compound (1) which has a large anisotropy of refractive index, tends to be mixed with other liquid crystals, and is more advantageous in stability to light, a liquid crystal composition and a liquid crystal element usable for an optical shutter, a display element, ##STR1## A.sup.1 to A.sup.12 each independently represent a hydrogen atom, a fluorine atom, or an alkyl group having 1 to 10 carbon atoms, and at least one is an alkyl group.
摘要:
A fluorine-containing optically active compound represented by the formula (1): ##STR1## wherein R.sub.1 is a saturated or unsaturated C.sub.3 -C.sub.20 alkyl group or a saturated or unsaturated C.sub.3 -C.sub.20 alkoxyalkyl group; A.sup.1, A.sup.2 and A.sup.3 independently represent one of the following groups: ##STR2## provided that, when A.sup.1 is a condensed ring group, a sum of p and q is 0 or 1 and A.sup.2 and A.sup.3 are both monocyclic groups, or when A.sup.1 is a monocyclic group, a sum of p and q is 1 or 2 with the proviso that when the sum of p and q is 2, A.sup.2 and A.sup.3 are both monocyclic groups; X is --CH.sub.2 CH.sub.2 --, --CH.dbd.CH-- or --C.tbd.C--; W is a fluorine atom or a hydrogen atom; n is an integer of 1 to 10; m, p and q are each 0 or 1; u and w are each an integer of 0 to 3; and * indicates an asymmetric carbon atom, which is useful as a component of a liquid crystal mixture.
摘要:
Disclosed in this invention are the phenylpyrimidine derivatives represented by the general formula I: ##STR1## the alcohols represented by the formula: ##STR2## usable as starting material for the preparation of the phenylpyrimidine derivatives, and the processes for preparing such derivatives. The phenylpyrimidine derivatives of the formula I according to the present invention have very excellent properties as a liquid crystal compound and can be utilized effectively for the production of liquid crystal elements.
摘要:
A ferroelectric chiral smectic liquid crystal mixture comprising a compound of the formula (I): ##STR1## and at least one compound selected from the group consisting of a compound of the formula (II): ##STR2## and a compound of the formula (III): ##STR3##
摘要:
Disclosed in this invention are the phenylpyrimidine derivatives represented by the general formula I: ##STR1## the alcohols represented by the formula: ##STR2## usable as starting material for the preparation of the phenylpyrimidine derivatives, and the processes for preparing such derivatives. The phenylpyrimidine derivatives of the formula I according to the present invention have very excellent properties as a liquid crystal compound and can be utilized effectively for the production of liquid crystal elements.
摘要:
Disclosed in the present invention are the optically active aromatic compounds having a trifluoromethyl group useful as a component of ferroelectric liquid crystal compositions, a process for preparing the above compounds, liquid crystal compositions having the above compounds as an active ingredient, and liquid crystal elements using the above compositions. The optically active aromatic compounds of the Present invention represented by the formula: ##STR1## have the very excellent properties as a liquid crystal material and are useful for the preparation of liquid crystal compositions and the liquid crystal elements using such compositions.
摘要:
Optically active biphenyl derivatives including optically active biphenyl carboxylic acid derivative, hydroxybiphenyl derivative, alkoxybiphenylalkanol derivative and alkoxybiphenylalkanol derivative have the following structural formula: ##STR1## wherein R.sup.1 represents an alkyl group of 3-20 carbon atoms, R.sup.2 represents an alkyl group or alkoxyalkyl group of 1-20 carbon atoms which may optionally be substituted with at least one halogen atom. X represents --O--, --COO-- or --OCO--, m represents 0 or 1, n represents an integer of 1-6 and p represents 0 or 1, and the * mark represents an asymmetric carbon atom. These optically active biphenyl derivatives are useful as a ferroelectric liquid crystal material or its component having a sufficient spontaneous polarization and by which a high speed response is possible and which further exhibits a ferroelectric liquid crystal phase in a temperature region around room temperature.
摘要:
A liquid crystal mixture containing a compound of the formula (1) as an essential component, which has a large birefringence (.DELTA.n), an increased upper limit temperature of nematic phase and a widened temperature range of nematic phase, and a decreased responsiveness parameter.