摘要:
The present invention relates to compositions suitable for use as binders and containingA) 10 to 99 parts by weight of at least one copolymer which has a weight average molecular weight of 1500 to 75,000, is prepared from olefinically unsaturated compounds and containsi) 0.1 to 8.0% by weight of free hydroxyl groups andii) 1 to 29% by weight of epoxide groups (calculated as C.sub.2 H.sub.3 O) andB) 1 to 90 parts by weight of at least one organic polyanhydride containing at least two cyclic carboxylic acid anhydride groups per molecule,provided that 0.1 to 10 anhydride groups of component B) are present for each epoxide group of component A).The invention also relates to the use of the binder compositions as binders for thermosetting coating or sealing compositions, or, in the presence of catalysts, as binders for coating or sealing compositions which can be hardened at room temperature.
摘要翻译:本发明涉及适合用作粘合剂并含有A)的组合物,A)10至99重量份的至少一种重均分子量为1500至75,000的共聚物由烯属不饱和化合物制备,并包含i)0.1至 8.0重量%的游离羟基和ii)1〜29重量%的环氧基团(按C 2 H 3 O计算)和B)1〜90重量份的至少一种含有至少两个环状羧酸酐基团的有机聚酐 分子,条件是组分B)的每个环氧基团存在组分B)的0.1至10个酸酐基团。 本发明还涉及粘合剂组合物作为热固性涂层或密封组合物的粘合剂,或在催化剂存在下作为用于涂覆或密封可在室温下硬化的组合物的粘合剂的用途。
摘要:
The present invention relates to copolymers prepared from olefinically unsaturated compounds, having a molecular weight (M.sub.n) of 600 to 20,000 and containing 0.1 to 6.0% by weight of secondary amino groups, --NH--, in the form of structural units corresponding to formula I ##STR1## wherein R.sub.1 is a saturated aliphatic hydrocarbon radical containing 2 to 6 carbon atoms, provided that at least two carbon atoms are arranged between the two nitrogen atoms, andR.sub.2 is a methyl, ethyl or 2-hydroxyethyl group.The present invention also relates to a process for the production of these copolymers.
摘要:
A moisture-curing binder composition useful in paints and other coating compositions is prepared by mixing or mixing with spontaneous reaction in the absence of moistureA) 30 to 99 parts by weight of at least one compound containing at least two intramolecular carboxylic anhydride groups andB) 1 to 70 parts by weight of organic compounds having blocked amino groups, wherein B)comprises organic compounds containing hydrogen atoms which are reactive to acid anhydride groups and containing bicyclic amide acetal or bicyclic amide groups or both, wherein the ratios of the amounts of the individual components are chosen such that, by taking into account the addition reaction which occurs spontaneously between components A) and B) in the absence of moisture, in the resulting mixture 0.25 to 50 anhydride groups are present per bicyclic amide acetal and bicyclic amide aminal group.
摘要:
A moisture-hardening binder composition for lacquer of coating compositions is prepared by mixing(A) 50 to 97 parts by weight of copolymers of maleic anhydride with olefinically unsaturated monomers, said copolymers containing succinic anhydride units and having molecular weights Mw of 1,500 to 75,000 with(B) 3 to 50 parts by weight oxazolanes having a molecular weight Mw of 87 to 10,000,the quantitative ratios of (A) to (B) being such that the composition contains 0.25 to 10 anhydride groups for every oxazolane group,wherein component (A) consists essentially of copolymers of(a) 4.5 to 45 parts by weight of maleic anhydride,(b) 5 to 80 parts by weight of monomers of the formulae ##STR1## or both, and (c) 15 to 92 parts by weight of monomers of the formula ##STR2## wherein, R.sub.1 and R.sub.4 is each, independent of the other, an aliphatic or cycloaliphatic C.sub.1 -C.sub.12 hydrocarbon radical with or without oxygen, sulfur or nitrogen as a heteratom, R.sub.2 is hydrogen, methyl, ethyl, chlorine or fluorine,R.sub.3 is a C.sub.2 -C.sub.15 aliphatic hydrocarbon radical, a C.sub.5 -C.sub.10 cycloaliphatic hydrocarbon radical, a C.sub.7 -C.sub.18 araliphatic hydrocarbon radical, a C.sub.6 -C.sub.12 aromatic hydrocarbon radical, chlorine, fluorine, nitrile or a C.sub.2 -C.sub.18 hydrocarbon radical containing one or more heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen in the form of ether, ester, amide, urethane, urea, thioester, oxirane, ketone, lactam or lactone groups.
摘要:
The present invention relates to hydroxy functional polyacrylate copolymers having a molecular weight (M.sub.n) of about 2000 to 30,000 and containinga) about 1 to 70% by weight of structural units corresponding to the formula ##STR1## The present invention also relates to a process for the preparation of these hydroxy functional copolymers by reacting the corresponding anhydride functional copolymers with amino alcohols. Finally, the present invention also relates to the use of these hydroxy functional copolymers as binder components in combination with polyisocyanates for the production of polyurethane lacquers, coatings, sealants, adhesives or printing inks.
摘要:
Compositions useful as a binder in lacquers and coating compositions and which are curable by moisture contain:(A) from 30 to 99 parts by weight of at least one copolymer of olefinically unsaturated compounds having a weight average molecular weight of from 1500 to 75,000 and containing chemically incorporated moieties capable of undergoing an addition reaction with amino groups, and(B) from 1 to 70 parts by weight of at least one organic polyamine containing blocked amino groups,wherein (i) the copolymers of component (A) contain both intramolecular carboxylic acid anhydride moieties and epoxide moieties in a chemically bound form, with the anhydride equivalent weight of the copolymers being from 393 to 9,800 and the epoxide equivalent weight of the copolymers from 568 to 14,200, and (ii) the binder composition contains from 0.2 to 8 anhydride and epoxide moieties for each blocked amino group.
摘要:
The present invention relates to a process for the production of polyhydroxyl compounds having a hydroxyl group content of 2 to 10% by weight and a viscosity at 23.degree. C. of 250 to 80,000 mPa.s by the radically initiated polymerization at a reaction temperature of 80.degree. to 220.degree. C. ofa) 100 parts by weight of a mixture of olefinically unsaturated monomers containing at least 1% by weight of monomers containing alcoholic hydroxyl groups in the presence ofb) 5 to 500 total parts by weight, which may be present at the beginning of the reaction or added during the reaction, of one or more cyclic compounds which, in the presence of initiator compounds containing alcoholic hydroxyl groups, are capable of a ring-opening polymerization reaction andc) 2 to 300 parts by weight, which may be present at the beginning of the reaction or added during the reaction, of one or more polyhydric alcohols having a molecular weight of 62 to 1000.The present invention also relates to the polyhydroxyl compounds obtained by this process and to their use in combination with suitable hardeners as binders for one-component or two-component coating compositions.
摘要:
Aqueous UV-hardenable dispersions are provided, as well as their use for the production of coating agents, in particular coatings for ligneous substrates. The dispersions comprise the reaction product of a) one or more polyisocyanates of which at least one polyisocyanate is an oligomeric polyisocyanate of hexamethylene diisocyanate with urethane, biuret, iminooxadiazindione and/or isocyanurate structural units, b) one or more monohydroxy-functional compounds containing (meth)acryloyl groups, c) at least one component c1), which has a hydrophilising effect on the basis of incorporated (potentially) ionic groups and comprises at least one further isocyanate-reactive group and/or at least one component c2) which contains non-ionically hydrophilically acting groups and comprises at least one further isocyanate-reactive group, d) one or more difunctional and/or polyfunctional amines or hydroxyamines as chain extender, and e) optionally other monomeric, oligomeric and/or polymeric substances, which may optionally also contain further unsaturated groups.
摘要:
The invention relates to novel UV-curable polyurethane dispersions based on unsaturated polyesters modified with dicyclopentadiene, the preparation of these polyurethane dispersions and the use thereof as a lacquer, coating and/or adhesive.