摘要:
Ethylene-vinyl alcohol copolymer pellets comprise an ethylene-vinyl alcohol copolymer and water, and have a water content of not higher than 0.5 wt. %, wherein the ratio (Y/Z) of a lactone ring content (Y) to the sum (Z) of a carboxylic acid content (X) and the lactone ring content (Y) in terminal structures of the ethylene-vinyl alcohol copolymer is not less than 60 mol %. The pellets are excellent in high-temperature thermal decomposition-suppressing effect and thermal stability, and are free from odor emanation and coloration even if being processed at a higher temperature.
摘要:
An ethylene-vinyl alcohol copolymer has an ethylene content of 20 to 60 mol % and includes a carboxylic acid group and a lactone ring group present at terminals thereof, wherein the molar concentration (Y/Z) of a lactone ring molar content (Y) to a sum (Z) of a carboxylic acid molar content (X) and the lactone ring molar content (Y) is not less than 58 mol %. The ethylene-vinyl alcohol copolymer is excellent in high-temperature thermal stability substantially without thermal decomposition, and is free from odor emanation and coloration even if being processed at a higher temperature.
摘要:
The present invention relates to an unsaturated polyester resin composition comprising (a) an unsaturated polyester, (b) a vinyl group containing organic compound as reactive diluent and (c) a transition metal compound, wherein the resin composition comprises (d) a compound according to formula (1) as reactive diluent whereby n=0-3; R1 and R2 each individually represent H, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkylaryl or C7-C20 arylalkyl; X=O, S or NR3 whereby R3=H, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkylaryl, C7-C20 arylalkyl, part of a polymer chain or attached to a polymer chain, and the composition comprises at least one transition metal compound (c) selected from the group consisting of Co, Cu, Mn and Fe compounds; and the resin composition comprises, as vinyl group containing organic compound (b), styrene, a styrene derivative, a vinyl ether, a vinyl amine, a vinyl amide or a mixture of at least two of these compounds
摘要:
The invention relates to the stabilization of alkaline solutions of peroxide bleaching compounds using, as stabilizing agent, a water-soluble poly-.alpha.-hydroxyacrylic acid salt which in the sodium salt form has an average molecular weight Mw from 2000 to 10,000 and to the preparation of such a salt.
摘要:
Hydroxyl terminated polymeric C.sub.5 -C.sub.9 lactone adducts are made by reacting a C.sub.5 -C.sub.9 lactone with the reaction product of a C.sub.2 -C.sub.10 olefin polymer or a halogenated derivative thereof having a number average molecular weight of 300 to about 10,000, with an amine containing from 2 to 60 total carbon atoms and from 1 to 12 nitrogen atoms. The resulting adducts are useful per se as oil soluble dispersant additives. They are also useful in fuel and lubricating oil compositions, as well as in concentrates and additive packages.
摘要:
The invention relates to a process for the production of cyclocopolymers, characterised in that compounds of the general formula 1
In which n is 1 - 4; R.sup.3 is H, CH.sub.3 or --CH.sub.2 --CH; Y is OH or NH.sub.2 ; and R.sup.4 and R.sup.5 may be identical or different and mean hydrogen or (C.sub.1 -C.sub.4)-alkyl, Preferably in equimolar amounts, and possibly with the use of further unsaturated compounds which are copolymerisable with compounds of the formula 1 and to copolymers obtainable by the process of the invention.
Where R means hydrogen, an aliphatic or aromatic radical, are copolymerised with unsaturated compounds of the general formula 2
In which R.sup.1 and R.sup.2 may be identical or different and mean H, CH.sub.3, C1 or Br; and X means
摘要:
The present invention relates to a process for producing lactonized acrylic fibers having a high Young''s modulus and improved elongation at break by treating an acrylic fiber made from an acrylic copolymer containing at least 50 percent by mol of acrylonitrile and a monomer having a hydroxyl group and/or a monomer capable of forming a hydroxyl group in an acid medium at a pH of not more than 2, said medium containing an organic and/or inorganic acid present in such concentrations as to avoid swelling or dissolving the treated material.
摘要:
Comb polymers prepared by reacting an acrylic polyol or a siloxane polyol with a lactone are disclosed. These comb polymers find particular application as additives for powder coating compositions, to improve various performance properties thereof. Powder coating composition comprising the described comb polymers are also disclosed.
摘要:
Lactone modified adducts are made by first reacting a non-polymerizable lactone or thiolactone and then a polymerizable C.sub.5 -C.sub.9 lactone with an aminated hydrocarbyl substituted C.sub.4 -C.sub.10 monounsaturated dicarboxylic acid producing material, e.g. a polyisobutenyl succinimide, which, in turn, preferably is made by reacting a polymer of a C.sub.2 to C.sub.10 monoolefin, preferably polyisobutylene, having a molecular weight of about 700 to 5,000 with a C.sub.4 to C.sub.10 monounsaturated acid, anhydride or ester, preferably maleic anhydride, such that there are about 0.7 to 2.0 dicarboxylic acid producing moieties per molecule of said olefin polymer used in the reaction mixture, and then reacting the substituted acid, anhydride or ester with an amine. The resulting adducts are useful per se as oil soluble dispersant additives. They are also useful in fuel and lubricating oil compositions, as well as in concentrates and additive packages.