公开(公告)号：US11214632B2

公开(公告)日：2022-01-04

申请号：US16338209

申请日：2017-09-29

Applicant: Dow Global Technologies LLC

Inventor： Andrew M. Camelio ,  Arkady L. Krasovskiy ,  Matthew D. Christianson ,  Amaruka Hazari ,  Heather Spinney ,  Robert D J Froese

IPC: C08F10/02 ,  C07F9/28 ,  C08F10/14

Abstract: Embodiments are directed to monophosphaguanidine ligands and the bis ligated metal-complexes formed therefrom, wherein the metal-ligand complexes are polymerization catalysts comprising the following structure (I).

公开(公告)号：US11028190B2

公开(公告)日：2021-06-08

申请号：US16337602

申请日：2017-09-28

Applicant: Dow Global Technologies LLC

Inventor： Andrew M. Camelio ,  Arkady L. Krasovskiy ,  Matthew D. Christianson ,  Robert D J Froese

IPC: C07F9/02 ,  C07F9/28 ,  C08F4/64 ,  C08F210/16

Abstract: Embodiments are directed to bis- and poly-phosphaguanidine compounds, and the metal-ligand complexes formed therefrom, wherein the metal complexes can be used as procatalysts in polyolefin polymerization. Formulas (I) (II) and (III).

公开(公告)号：US20200024377A1

公开(公告)日：2020-01-23

申请号：US16338209

申请日：2017-09-29

Applicant: Dow Global Technologies LLC

Inventor： Andrew M. Camelio ,  Arkady L. Krasovskiy ,  Matthew D. Christianson ,  Amaruka Hazari ,  Heather Spinney ,  Robert DJ Froese

IPC: C08F10/02 ,  C07F9/28 ,  C08F10/14

Abstract: Embodiments are directed to monophosphaguanidine ligands and the bis ligated metal-complexes formed therefrom, wherein the metal-ligand complexes are polymerization catalysts comprising the following structure (I).

公开(公告)号：US20160053031A1

公开(公告)日：2016-02-25

申请号：US14931258

申请日：2015-11-03

Applicant: Dow Global Technologies LLC

Inventor： Matthew D. Christianson ,  Timothy S. De Vries ,  Robert DJ Froese ,  Matthias S. Ober ,  Jasson T. Patton ,  Duane R. Romer ,  Gordon R. Roof ,  Lixin Sun ,  Endre Szuromi ,  Curt N. Theriault ,  Dean M. Welsh ,  Timothy T. Wenzel ,  Paul H. Moran

IPC: C08F110/06 ,  C07F11/00 ,  C08F110/02

CPC classification number: C08F4/78 ,  C07F11/00 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/06 ,  C08F4/69112 ,  C08F210/16 ,  C08F2500/15

Abstract: Provided is a non-cyclopentadienyl-based chromium-ligand complex, preferably a chromium-ligand complex of formula (J): LCr(RA)m(D)k (J), wherein L is a non-Cp monoanionic ligand; Cr (chromium) is in a formal oxidation state of +3 or +2; when Cr formally is Cr+3, either m is 1 and RA is hydrocarbylene (a hydrocarbylene chromium-ligand complex of formula (J)) or m is 2 and each RA independently is hydrocarbyl (a dihydrocarbyl chromium-ligand complex of formula (J)), wherein each hydrocarbyl or hydrocarbylene of RA independently is unsubstituted or substituted by from 1 to 5 RAS; each RAS independently is a neutral aprotic heteroalkyl, neutral aprotic heterocycloalkyl, neutral aprotic heteroaryl, or neutral aprotic aryl; when Cr formally is Cr+2, m is 1 and RA is hydrocarbyl (a hydrocarbyl chromium-ligand complex of formula (J)); k is an integer of 0 or 1; D is absent when k is 0 or D is a neutral ligand when k is 1; wherein the chromium-ligand complex of formula (J) is overall neutral and lacks a cyclopentadienyl-based (Cp-based) moiety. Also provided is a chromium catalyst comprising or prepared from the complex. Also provided is a process of making the catalyst and a process employing the chromium catalyst for polymerizing the olefin monomer, especially a straight chain 1-alkene, to prepare the polyolefin, especially a partially chain-straightened poly(1-alkene) or olefin block copolymer. Further provided is the partially chain-straightened poly(1-alkene) or olefin block copolymer prepared thereby. Also provided is a high throughput workflow.

公开(公告)号：US12122862B2

公开(公告)日：2024-10-22

申请号：US17311530

申请日：2019-12-19

Applicant: Dow Global Technologies LLC

Inventor： Andrew M. Camelio ,  Endre Szuromi ,  David D. Devore ,  Robert D J Froese ,  Brad C. Bailey ,  Matthew D. Christianson ,  Sukrit Mukhopadhyay ,  Jerzy Klosin

IPC: C08F4/64 ,  C07F7/00 ,  C08F4/52 ,  C08F4/76 ,  C08F210/16

CPC classification number: C08F210/16 ,  C07F7/00 ,  C07F7/003 ,  C08F4/64193

Abstract: Catalyst systems that include a chain transfer agent and a metal-ligand complex according to formula (I).

公开(公告)号：US12037440B2

公开(公告)日：2024-07-16

申请号：US17043029

申请日：2019-03-28

Applicant: Dow Global Technologies LLC ,  Northwestern University

Inventor： Tobin J. Marks ,  Yanshan Gao ,  Tracy L. Lohr ,  Matthew D. Christianson ,  Jerzy Klosin ,  Edmund M. Carnahan ,  Andrew J. Young

IPC: C08F4/52 ,  C08F4/64 ,  C08F4/659 ,  C08F4/76 ,  C08F10/02 ,  C08F10/14

CPC classification number: C08F4/64048 ,  C08F4/64144 ,  C08F4/65908 ,  C08F10/02 ,  C08F10/14 ,  C08F4/52 ,  C08F2410/03

Abstract: Embodiments are directed to catalyst systems comprising: a procatalyst; and a co-catalyst dissolved in a non-halogenated aprotic hydrocarbon solvent, the co-catalyst comprising: a non-coordinating borate dianion having the formula: (III) and two cations, each cation being independently chosen from a cation according to formula (I) or formula (II).

公开(公告)号：US20230382929A1

公开(公告)日：2023-11-30

申请号：US18032039

申请日：2021-10-13

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Sanil Sreekumar ,  Brad C. Bailey ,  Arvind Jaganathan ,  James J. Henkelis ,  Matthew D. Christianson ,  Sukrit Mukhopadhyay ,  James A. Walker ,  Jordan C. Reddel

IPC: C07F7/00 ,  C08F4/76 ,  C08F210/16

CPC classification number: C07F7/00 ,  C08F4/76 ,  C08F210/16

Abstract: Embodiments are directed to a metal-ligand complex of formula (I). In addition, a polymerization process includes polymerizing at least one olefin in the presence of a catalyst system comprising the metal-ligand complex and at least one activator to produce an olefinic polymer.

公开(公告)号：US10919995B2

公开(公告)日：2021-02-16

申请号：US16089559

申请日：2017-03-30

Applicant: Dow Global Technologies LLC

Inventor： Brad C. Bailey ,  Matthew D. Christianson ,  Sanil Sreekumar

IPC: C08F210/16 ,  C07F7/00

Abstract: An olefin polymerization catalyst system includes a procatalyst component chosen from metal-ligand complexes of Formula (I): In Formula (I), each X is independently a monodentate or polydentate ligand that is neutral, monoanionic, or dianionic; the metal-ligand complex of Formula (I) is overall neutral; each Y1-Y4 and Y7-Y10 independently is selected from C or N such that six membered diaza (N2) or triaza (N3) rings are formed; wherein each R1 and R10 independently are chosen from (C1-C40) hydrocarbyl, substituted (C1-C40) hydrocarbyl, (C1-C40) heterohydrocarbyl, and substituted (C1-C40) heterohydrocarbyl or is absent; each R2, R3, R4, R7, R8, and R9 is chosen from hydrogen; (C1-C40) hydrocarbyl; substituted (C1-C40) hydrocarbyl; (C1-C40) heterohydrocarbyl; substituted (C1-C40) heterohydrocarbyl; halogen, nitro (NO2) or is absent; each R5 and R6 independently is chosen from (C1-C40) hydrocarbyl, substituted (C1-C40) hydrocarbyl, (C1-C40) heterohydrocarbyl, and substituted (C1-C40) heterohydrocarbyl.

公开(公告)号：US20200299430A1

公开(公告)日：2020-09-24

申请号：US16089559

申请日：2017-03-30

Applicant: Dow Global Technologies LLC

Inventor： Brad C. Bailey ,  Matthew D. Christianson ,  Sanil Sreekumar

IPC: C08F210/16 ,  C07F7/00

Abstract: An olefin polymerization catalyst system includes a procatalyst component chosen from metal-ligand complexes of Formula (I): In Formula (I), each X is independently a monodentate or polydentate ligand that is neutral, monoanionic, or dianionic; the metal-ligand complex of Formula (I) is overall neutral; each Y1-Y4 and Y7-Y10 independently is selected from C or N such that six membered diaza (N2) or triaza (N3) rings are formed; wherein each R1 and R10 independently are chosen from (C1-C40) hydrocarbyl, substituted (C1-C40) hydrocarbyl, (C1-C40) heterohydrocarbyl, and substituted (C1-C40) heterohydrocarbyl or is absent; each R2, R3, R4, R7, R8, and R9 is chosen from hydrogen; (C1-C40) hydrocarbyl; substituted (C1-C40) hydrocarbyl; (C1-C40) heterohydrocarbyl; substituted (C1-C40) heterohydrocarbyl; halogen, nitro (NO2) or is absent; each R5 and R6 independently is chosen from (C1-C40) hydrocarbyl, substituted (C1-C40) hydrocarbyl, (C1-C40) heterohydrocarbyl, and substituted (C1-C40) heterohydrocarbyl.

公开(公告)号：US20200299420A1

公开(公告)日：2020-09-24

申请号：US16089525

申请日：2017-03-30

Applicant: Dow Global Technologies LLC

Inventor： Brad C. Bailey ,  Matthew D. Christianson ,  Anna V. Davis ,  Andrew M. Camelio ,  Robert D.J. Froese ,  Jessica L. Klinkenberg

IPC: C08F4/64 ,  C08F2/38 ,  C08F210/02 ,  C08F210/04 ,  C08F210/14

Abstract: An olefin polymerization catalyst system comprising: a procatalyst component comprising a metal-ligand complex of Formula (I) wherein each X is independently a monodentate or polydentate ligand that is neutral, monoanionic, or dianionic, wherein n is an integer, and wherein X and n are chosen such that the metal-ligand complex of Formula (I) is overall neutral; wherein each R1 and R5 independently is selected from (C1-C40)hydrocarbyls, substituted (C1-C40)hydrocarbyls; (C1-C40)heterohydrocarbyls and substituted (C1-C40)heterohydrocarbyls; wherein each R2 and R4 independently is selected from (C1-C40)hydrocarbyls and substituted (C1-C40)hydrocarbyls; wherein R3 is selected from the group consisting of a (C3-C40)hydrocarbylene, substituted (C3-C40)hydrocarbylene, [(C+Si)3-(C+Si)40]organosilylene, substituted [(C+Si)3-(C+Si)40]organosilylene, [(C+Ge)3-(C+Ge)40]organogermylene, or substituted [(C+Ge)3-(C+Ge)40]organogermylene; wherein each N independently is nitrogen; and optionally, two or more R1-5 groups each independently can combine together to form mono-aza ring structures, with such ring structures having from 5 to 16 atoms in the ring excluding any hydrogen atoms.