FORMATION OF CHIRAL 4-CHROMANONES USING CHIRAL PYRROLIDINES IN THE PRESENCE OF PHENOLS OR THIOPHENOLS
    11.
    发明申请
    FORMATION OF CHIRAL 4-CHROMANONES USING CHIRAL PYRROLIDINES IN THE PRESENCE OF PHENOLS OR THIOPHENOLS 有权
    在苯酚或噻二醇存在下使用正丙基吡咯烷酮形成正四氯丙酮

    公开(公告)号:US20160168111A1

    公开(公告)日:2016-06-16

    申请号:US14902662

    申请日:2014-07-03

    CPC classification number: C07D311/22 C07B2200/09

    Abstract: The present invention relates to a synthesis of chromanones or chromanes in a stereospecific matter in view of the 2-position in the chromanone or chromane ring. It has been found that this synthesis is particularly possible in the presence of a chiral compound of formula of a specific type and of at least one phenol or thiophenol.

    Abstract translation: 本发明涉及在苯并二氢吡喃酮或苯并二氢吡喃环中2-位的立体特异性物质中的色满酮或色烷的合成。 已经发现,在特定类型的式的手性化合物和至少一种苯酚或苯硫酚的存在下,该合成是特别有可能的。

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