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公开(公告)号:US08034980B2
公开(公告)日:2011-10-11
申请号:US12302162
申请日:2007-05-22
申请人: Achim Loeffler , Wolfgang Loth , Ralf Boehling , Thomas Ostrowski , Michael Stoesser , Hartwig Voss , Axel Schimpf
发明人: Achim Loeffler , Wolfgang Loth , Ralf Boehling , Thomas Ostrowski , Michael Stoesser , Hartwig Voss , Axel Schimpf
CPC分类号: C08G65/2696 , C08G18/4866
摘要: A process for preparing polyether polyols by reaction of the following starting materials: a) one or more alkylene oxides and, if appropriate, carbon dioxide and also b) one or more H-functional starter substances, in the presence of a catalyst, in a reaction unit having a plurality of parallel layers A, B which are microstructured so that each layer has a multiplicity of channels which are arranged parallel to one another and form a continuous flow path from one side of the plate to the opposite side of this, wherein a distribution device for introduction of the starting materials and the catalyst is provided at one end of the channels of the layers A and a collection device for the reaction mixture is provided at the other end of these is proposed.
摘要翻译: 通过以下原料反应制备聚醚多元醇的方法:a)一种或多种环氧烷烃,如果合适的话,二氧化碳,以及b)一种或多种H官能起始物质,在催化剂存在下,在 反应单元具有多个平行层A,B,它们被微结构化,使得每个层具有多个彼此平行布置的通道,并形成从板的一侧到其相反侧的连续流动路径,其中 在层A的通道的一端设置用于引入起始材料和催化剂的分配装置,并且在另一端提供了用于反应混合物的收集装置。
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公开(公告)号:US20110065840A1
公开(公告)日:2011-03-17
申请号:US12992492
申请日:2009-05-11
申请人: Daniel Freidank , Andreas Emge , Sonja Judat , Robert Engel , Ingrid Martin , Thomas Danner , Achim Loeffler , Stephan Hess
发明人: Daniel Freidank , Andreas Emge , Sonja Judat , Robert Engel , Ingrid Martin , Thomas Danner , Achim Loeffler , Stephan Hess
CPC分类号: C08G18/0871 , B60R13/00 , C08G18/0876 , C08L75/04 , Y10T428/31551 , Y10T428/31558 , Y10T428/31591 , C08L23/00 , C08L31/00 , C08L71/00 , C08L35/08 , C08L29/06 , C08L23/20 , C08L67/00 , C08L9/06 , C08L77/00 , C08L33/10 , C08L29/02 , C08L33/08
摘要: The present invention relates to a dispersion comprising (i) at least one liquid polymer and (ii) at least one polymer particle mixture comprising at least one meltable solid and at least one copolymer (C), wherein said at least one copolymer (C) is a random copolymer synthesized from at least one α,β-ethylenically unsaturated monomer and at least one polymerizable polymer of the class of liquid polymers according to (i), to processes for preparing this dispersion, to the use of this dispersion to prepare polyurethanes, and to a process for preparing polyurethanes, in which at least one such dispersion is reacted with at least one polyisocyanate.
摘要翻译: 本发明涉及包含(i)至少一种液体聚合物和(ii)包含至少一种可熔融固体和至少一种共聚物(C)的至少一种聚合物颗粒混合物的分散体,其中所述至少一种共聚物(C) 是由至少一种α,β-烯键式不饱和单体和根据(i)的液体聚合物类的至少一种可聚合聚合物合成的无规共聚物,用于制备该分散体的方法,使用该分散体制备 聚氨酯,以及制备聚氨酯的方法,其中至少一种这样的分散体与至少一种多异氰酸酯反应。
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公开(公告)号:US08461285B2
公开(公告)日:2013-06-11
申请号:US13042780
申请日:2011-03-08
CPC分类号: C08G18/4841 , C08G18/4829 , C08G65/2696 , C08G2101/0008 , C08G2101/0083
摘要: The present invention relates to a process for the catalytic preparation of polyetherols, wherein the power input by means of at least one stirrer and/or by means of at least one pump, based on the reactor volume, is in the range from 0.001 to 8.2 kW/m3.
摘要翻译: 本发明涉及一种催化制备聚乙烯醇的方法,其中通过至少一个搅拌器和/或通过至少一个泵基于反应器体积输入的功率在0.001至8.2的范围内 kW / m3。
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公开(公告)号:US20120022179A1
公开(公告)日:2012-01-26
申请号:US13143144
申请日:2010-01-12
申请人: Andreas Emge , Marc Fricke , Roman Prochazka , Holger Seifert , Darijo Mijolovic , Achim Loeffler , Sirus Zarbakhsh
发明人: Andreas Emge , Marc Fricke , Roman Prochazka , Holger Seifert , Darijo Mijolovic , Achim Loeffler , Sirus Zarbakhsh
CPC分类号: C08G18/482 , C08G18/4879 , C08G2101/0025
摘要: The invention relates to a process for producing rigid polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups in the presence of c) blowing agents, wherein the component b) comprises at least one polyether alcohol bi) prepared by addition of alkylene oxides onto toluenediamine and at least one polyether alcohol bii) prepared by addition of alkylene oxides onto H-functional starter substances comprising oligomeric glycerol.
摘要翻译: 本发明涉及通过使a)多异氰酸酯与b)在c)发泡剂存在下具有至少两个对异氰酸酯基具有反应性的氢原子的化合物反应来制备硬质聚氨酯泡沫的方法,其中组分b)包含至少一个 通过在甲苯二胺和至少一种聚醚醇bii上加入环氧烷制备的聚醚醇bi),其通过在包含低聚甘油的H功能起始物质上加入环氧烷烃而制备。
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公开(公告)号:US07723465B2
公开(公告)日:2010-05-25
申请号:US11994507
申请日:2006-07-11
申请人: Stephan Herwig , Thomas Ostrowski , Dirk Meckelnburg , Achim Loeffler , Renata Jovanovic , Werner Weinle
发明人: Stephan Herwig , Thomas Ostrowski , Dirk Meckelnburg , Achim Loeffler , Renata Jovanovic , Werner Weinle
IPC分类号: C08G59/68
CPC分类号: C08G65/2663 , C08G65/2696
摘要: The invention provides a process for continuously preparing polyether alcohols using DMC catalysts, which comprises, in a first step, in a continuous reactor, adding alkylene oxides onto H-functional starter substances and transferring the output of this reactor to a second step in a reactor which is divided by closed trays into mutually separate sections, known as compartments, which are connected to one another by external pipelines, in which the output of the reactor from the first step of the reaction passes through the compartments in succession.
摘要翻译: 本发明提供了一种使用DMC催化剂连续制备聚醚醇的方法,该方法在第一步中包括在连续反应器中,在环氧化物起始物质中加入环氧烷并将反应器的输出转移到反应器中的第二步 其被封闭的托盘分成相互分离的部分,称为隔室,其通过外部管道彼此连接,其中来自反应器的第一步骤的反应器的输出依次通过隔室。
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公开(公告)号:US09234066B2
公开(公告)日:2016-01-12
申请号:US12992492
申请日:2009-05-11
申请人: Daniel Freidank , Andreas Emge , Sonja Judat , Robert Engel , Ingrid Martin , Thomas Danner , Achim Loeffler , Stephan Hess
发明人: Daniel Freidank , Andreas Emge , Sonja Judat , Robert Engel , Ingrid Martin , Thomas Danner , Achim Loeffler , Stephan Hess
CPC分类号: C08G18/0871 , B60R13/00 , C08G18/0876 , C08L75/04 , Y10T428/31551 , Y10T428/31558 , Y10T428/31591 , C08L23/00 , C08L31/00 , C08L71/00 , C08L35/08 , C08L29/06 , C08L23/20 , C08L67/00 , C08L9/06 , C08L77/00 , C08L33/10 , C08L29/02 , C08L33/08
摘要: The present invention relates to a dispersion comprising (i) at least one liquid polymer and (ii) at least one polymer particle mixture comprising at least one meltable solid and at least one copolymer (C), wherein said at least one copolymer (C) is a random copolymer synthesized from at least one α,β-ethylenically unsaturated monomer and at least one polymerizable polymer of the class of liquid polymers according to (i), to processes for preparing this dispersion, to the use of this dispersion to prepare polyurethanes, and to a process for preparing polyurethanes, in which at least one such dispersion is reacted with at least one polyisocyanate.
摘要翻译: 本发明涉及包含(i)至少一种液体聚合物和(ii)包含至少一种可熔融固体和至少一种共聚物(C)的至少一种聚合物颗粒混合物的分散体,其中所述至少一种共聚物(C) 是由至少一种α,β-烯键式不饱和单体和根据(i)的液体聚合物类的至少一种可聚合聚合物合成的无规共聚物,用于制备该分散体的方法,使用该分散体制备 聚氨酯,以及制备聚氨酯的方法,其中至少一种这样的分散体与至少一种多异氰酸酯反应。
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公开(公告)号:US09120731B2
公开(公告)日:2015-09-01
申请号:US13813300
申请日:2011-08-08
CPC分类号: C07C41/02 , C08G65/2696
摘要: What is proposed is a process for preparing polyether alcohols by conversion of the following reactants: a) one or more alkylene oxides and optionally carbon dioxide and b) one or more H-functional starter substances, in the presence of a catalyst, to form a liquid reaction mixture, in a reaction unit (1), which is characterized in that the reaction unit (1) has internals (2) which form a multitude of microstructured flow channels which bring about multiple splitting of the liquid reaction mixture into component flow paths and recombination thereof in altered arrangement, the multiple splitting and recombination being repeated several times and the microstructured flow channels having a characteristic dimension which is defined as the greatest possible distance of any particle in the liquid reaction mixture from the wall of a flow channel closest to the particle, in the range from 20 to 10 000 μm, the result being that the flow profile of the liquid reaction mixture approximates to ideal plug flow as a result of the microstructured flow channels.
摘要翻译: 提出的是通过以下反应物的转化来制备聚醚醇的方法:a)一种或多种环氧烷烃和任选的二氧化碳,和b)一种或多种H官能起始物质,在催化剂存在下,形成 液体反应混合物,在反应单元(1)中,其特征在于反应单元(1)具有形成多个微结构流动通道的内部(2),其导致液体反应混合物多次分离成组分流动路径 并且其重组在改变的布置中,多次分裂和重组被重复几次,并且微结构流动通道具有被定义为液体反应混合物中任何颗粒与流动通道的壁最接近的最大可能距离的特征尺寸 颗粒在20至1000000范围内,其结果是液体反应混合物的流动分布近似于id 作为微结构化流动通道的结果,流动的流动。
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公开(公告)号:US09109077B2
公开(公告)日:2015-08-18
申请号:US12741618
申请日:2008-11-13
申请人: Nils Mohmeyer , Daniel Freidank , Sibylle Schoeps , Andreas Emge , Achim Loeffler , Marco Ortalda
发明人: Nils Mohmeyer , Daniel Freidank , Sibylle Schoeps , Andreas Emge , Achim Loeffler , Marco Ortalda
IPC分类号: C08G18/63 , C08G18/10 , C08G18/40 , C08G101/00
CPC分类号: C08G18/632 , C08G18/10 , C08G18/4072 , C08G18/63 , C08G2101/0008 , C08G2101/0033 , C08G2101/0066 , C08G2101/0083 , C08G2410/00 , C08G18/40 , C08G18/6588
摘要: The present invention relates to foamed polyurethane obtainable by mixing a) polyisocyanates, b) relatively high molecular weight compounds having groups reactive toward isocyanate groups, c) solid particles, d) blowing agents, e) if appropriate, chain extender, crosslinking agent or mixtures thereof, f) if appropriate, catalyst and g) if appropriate, other additives to give a reaction mixture and allowing the reaction mixture to react to completion, the propotion of chain extender being less than 6% by weight, based on the total weight of the components a) to f), the content of solid particles being greater than 15% by weight, based on the total weight of the components a) to f), and the average functionality of the relatively high molecular weight compounds having groups reactive toward isocyanate groups being less 2.5. The present invention furthermore relates to a molding comprising a foamed polyurethane according to the invention, a process for the preparation of the foamed polyurethane according to the invention and the use of a molding according to the invention as a shoe sole.
摘要翻译: 本发明涉及通过混合a)多异氰酸酯得到的发泡聚氨酯,b)具有对异氰酸酯基团具有反应性的基团的相对高分子量化合物,c)固体颗粒,d)发泡剂,e)如果合适,扩链剂,交联剂或混合物 f)如果合适,催化剂和g)如果合适的话,其它添加剂以产生反应混合物并使反应混合物反应完成,扩链剂的用量小于6重量%,基于总重量的 组分a)至f),基于组分a)至f)的总重量,固体颗粒的含量大于15重量%,并且具有反应性的基团的相对高分子量化合物的平均官能度 异氰酸酯基团少2.5。 本发明还涉及包含根据本发明的发泡聚氨酯的模制品,用于制备根据本发明的泡沫聚氨酯的方法以及根据本发明的模制品作为鞋底的用途。
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公开(公告)号:US20130131389A1
公开(公告)日:2013-05-23
申请号:US13813300
申请日:2011-08-08
IPC分类号: C07C41/02
CPC分类号: C07C41/02 , C08G65/2696
摘要: What is proposed is a process for preparing polyether alcohols by conversion of the following reactants: a) one or more alkylene oxides and optionally carbon dioxide and b) one or more H-functional starter substances, in the presence of a catalyst, to form a liquid reaction mixture, in a reaction unit (1), which is characterized in that the reaction unit (1) has internals (2) which form a multitude of microstructured flow channels which bring about multiple splitting of the liquid reaction mixture into component flow paths and recombination thereof in altered arrangement, the multiple splitting and recombination being repeated several times and the microstructured flow channels having a characteristic dimension which is defined as the greatest possible distance of any particle in the liquid reaction mixture from the wall of a flow channel closest to the particle, in the range from 20 to 10 000 μm, the result being that the flow profile of the liquid reaction mixture approximates to ideal plug flow as a result of the microstructured flow channels.
摘要翻译: 提出的是通过以下反应物的转化来制备聚醚醇的方法:a)一种或多种环氧烷烃和任选的二氧化碳,和b)一种或多种H官能起始物质,在催化剂存在下,形成 液体反应混合物,在反应单元(1)中,其特征在于反应单元(1)具有形成多个微结构流动通道的内部(2),其导致液体反应混合物多次分离成组分流动路径 并且其重组在改变的布置中,多次分裂和重组被重复几次,并且微结构流动通道具有被定义为液体反应混合物中任何颗粒与流动通道的壁最接近的最大可能距离的特征尺寸 该颗粒在20至1000000m范围内,结果是液体反应混合物的流动分布近似于id 作为微结构化流动通道的结果,流动的流动。
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公开(公告)号:US07750191B2
公开(公告)日:2010-07-06
申请号:US11570794
申请日:2005-06-22
CPC分类号: C08G65/2663 , C08G18/4837 , C08G18/4866 , C08G2101/0008 , C08G2101/0083
摘要: The invention provides a process for continuously preparing polyether alcohols by adding alkylene oxides to H-functional starter substances using a DMC catalyst, comprising the steps of a) preparing a precursor by continuously metering an H-functional starter substance, an alkylene oxide or a mixture of at least two alkylene oxides and the required amount of DMC catalyst into a continuous reactor, b) continuously withdrawing the precursor from step a) from the reactor, c) continuously metering the product from step a), an alkylene oxide different from that in step a) or a mixture of at least two alkylene oxides different from that in step a) and, if appropriate, the required amount of DMC catalyst into a further continuous reactor.
摘要翻译: 本发明提供一种通过使用DMC催化剂向环氧化物加成烯键式氧化物连续制备聚醚醇的方法,该方法包括以下步骤:a)通过连续计量H-功能起始物质,烯化氧或混合物来制备前体 的至少两种烯化氧和所需量的DMC催化剂进入连续反应器,b)从反应器中连续地从步骤a)中取出前体,c)连续计量来自步骤a)的产物,不同于 步骤a)或至少两种不同于步骤a)中的环氧烷烃的混合物,如果合适的话,将所需量的DMC催化剂加入另外的连续反应器中。
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