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公开(公告)号：US07196160B2
公开(公告)日：2007-03-27
申请号：US11110051
申请日：2005-04-20
CPC分类号： C08G63/85 , C08G63/181 , C08G2650/34
摘要： Cyclic oligomers containing ester linkages are polymerized in the presence of a catalyst having at least one oxygen atom bonded to two metal atoms. At least one of the metal atoms is a tin atom, which is preferably tetravalent, i.e., bonded to three other groups in addition to the oxygen atom. The other metal atom may also be another tin atom, which is again preferably tetravalent, or a zinc, aluminum or titanium atom. The catalyst may contain multiple oxygen atoms that are bonded to two such metal atoms as described. These catalysts are active, efficient polymerization catalysts. They are often liquids at polymerization temperatures. The catalysts can be formed in situ in the polymerization process, which provides additional flexibility in the process and increased storage stability of starting materials.
摘要翻译： 含有酯键的环状低聚物在具有键合至两个金属原子的至少一个氧原子的催化剂存在下聚合。 至少一个金属原子是锡原子，其优选是四价的，即除了氧原子之外还与三个其它基团键合。 另一个金属原子也可以是另一个锡原子，其又优选为四价，或者是锌，铝或钛原子。 催化剂可以含有多个氧原子，其与所述的两个这样的金属原子键合。 这些催化剂是活性的，有效的聚合催化剂。 它们在聚合温度下通常是液体。 催化剂可以在聚合过程中原位形成，这在工艺中提供了额外的灵活性并提高了原料的储存稳定性。
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12.发明授权公开(公告)号：US08048961B2
公开(公告)日：2011-11-01
申请号：US12377030
申请日：2007-08-23
申请人： Daniel J. Arriola , Brian A. Jazdzewski , Francis J. Timmers , Paul C. Vosejpka , Nicole L. Wagner , Brian G. Landes , Guenter A. Jueptner , David H. Bank , Timothy T. Wenzel
发明人： Daniel J. Arriola , Brian A. Jazdzewski , Francis J. Timmers , Paul C. Vosejpka , Nicole L. Wagner , Brian G. Landes , Guenter A. Jueptner , David H. Bank , Timothy T. Wenzel
IPC分类号： C08F8/00
CPC分类号： C08L53/00 , C08F299/00 , C08L53/005 , C08L2666/02
摘要： A cross-metathesized product mixture is prepared by contacting a metathesis catalyst under metathesis conditions with a composition comprising two or more chemically distinguishable ethylenically unsaturated polymers, at least one of said ethylenically unsaturated polymers (first polymer) having from 0.001 to 50 mole percent unsaturation and at least one other of said ethylenically unsaturated polymers (second polymer) being an amorphous polymer having a Tg less than 0° C. and having from 0.001 to 5 mole percent unsaturation.
摘要翻译： 通过在复分解条件下使复分解催化剂与包含两种或多种化学上可区分的烯键式不饱和聚合物的组合物，至少一种所述烯键式不饱和聚合物（第一聚合物）具有0.001至50摩尔％的不饱和度和 所述烯属不饱和聚合物（第二聚合物）中的至少一种是具有Tg小于0℃并具有0.001至5摩尔％不饱和度的无定形聚合物。
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公开(公告)号：US20100069573A1
公开(公告)日：2010-03-18
申请号：US12377034
申请日：2007-08-23
申请人： Daniel J. Arriola , Francis J. Timmers , Brian A. Jazdzewski , Paul C. Vosejpka , Nicole L. Wagner , Brian G. Landes , Guenter A. Jueptner , David H. Bank , Timothy T. Wenzel
发明人： Daniel J. Arriola , Francis J. Timmers , Brian A. Jazdzewski , Paul C. Vosejpka , Nicole L. Wagner , Brian G. Landes , Guenter A. Jueptner , David H. Bank , Timothy T. Wenzel
CPC分类号： C08G81/00 , C08F36/04 , C08F210/02 , C08F210/18 , C08F295/00 , C08F297/00 , C08F297/04 , C08F297/044 , C08F297/06 , C08F299/00 , C08F299/04 , C08F299/0478 , C08G81/024 , C08L53/00 , C08L53/02 , C08L2666/02 , C08F236/06 , C08F210/14
摘要： Meta-block copolymers and a process for preparing a product mixture comprising meta-block copolymers by contacting a metathesis catalyst under metathesis conditions with a composition comprising two or more ethylenically unsaturated polymers, said unsaturation defining one or more polymer segments in each ethylenically unsaturated polymer, at least one polymer segment in at least one ethylenically unsaturated polymer being chemically distinguishable from at least one polymer segment in at least one other ethylenically unsaturated polymer, characterized in that each meta-block copolymer in the product mixture comprises a random distribution of said chemically distinguishable polymer blocks.
摘要翻译： 元嵌段共聚物和通过使复分解催化剂在复分解条件下与包含两种或更多种烯属不饱和聚合物的组合物接触的复分解催化剂来制备产物混合物的方法，所述不饱和键定义每个烯属不饱和聚合物中的一个或多个聚合物链段， 至少一种烯键式不饱和聚合物中的至少一个聚合物链段与至少一种其它烯属不饱和聚合物中的至少一个聚合物链段在化学上是可区分的，其特征在于产物混合物中的每个间位嵌段共聚物包括所述化学可区分的 聚合物嵌段。
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公开(公告)号：US08557921B2
公开(公告)日：2013-10-15
申请号：US12377034
申请日：2007-08-23
申请人： Daniel J. Arriola , Francis J. Timmers , Brian A. Jazdzewski , Paul C. Vosejpka , Nicole L. Wagner , Brian G. Landes , Guenter A. Jueptner , David H. Bank , Timothy T. Wenzel
发明人： Daniel J. Arriola , Francis J. Timmers , Brian A. Jazdzewski , Paul C. Vosejpka , Nicole L. Wagner , Brian G. Landes , Guenter A. Jueptner , David H. Bank , Timothy T. Wenzel
CPC分类号： C08G81/00 , C08F36/04 , C08F210/02 , C08F210/18 , C08F295/00 , C08F297/00 , C08F297/04 , C08F297/044 , C08F297/06 , C08F299/00 , C08F299/04 , C08F299/0478 , C08G81/024 , C08L53/00 , C08L53/02 , C08L2666/02 , C08F236/06 , C08F210/14
摘要： Meta-block copolymers and a process for preparing a product mixture comprising meta-block copolymers by contacting a metathesis catalyst under metathesis conditions with a composition comprising two or more ethylenically unsaturated polymers, said unsaturation defining one or more polymer segments in each ethylenically unsaturated polymer, at least one polymer segment in at least one ethylenically unsaturated polymer being chemically distinguishable from at least one polymer segment in at least one other ethylenically unsaturated polymer, characterized in that each meta-block copolymer in the product mixture comprises a random distribution of said chemically distinguishable polymer blocks.
摘要翻译： 元嵌段共聚物和通过使复分解催化剂在复分解条件下与包含两种或更多种烯属不饱和聚合物的组合物接触的复分解催化剂来制备产物混合物的方法，所述不饱和键定义每个烯属不饱和聚合物中的一个或多个聚合物链段， 至少一种烯键式不饱和聚合物中的至少一个聚合物链段与至少一种其它烯属不饱和聚合物中的至少一个聚合物链段在化学上是可区分的，其特征在于产物混合物中的每个间位嵌段共聚物包括所述化学可区分的 聚合物嵌段。
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15.发明申请公开(公告)号：US20100010161A1
公开(公告)日：2010-01-14
申请号：US12377019
申请日：2007-08-23
申请人： Daniel J. Arriola , Brain A. Jazdzewski , Francis J. Timmers , Paul C. Vosejpka , Nicole L. Wagner , Brian G. Landes , Guenter A. Jueptner , David H. Bank , Timothy T. Wenzel
发明人： Daniel J. Arriola , Brain A. Jazdzewski , Francis J. Timmers , Paul C. Vosejpka , Nicole L. Wagner , Brian G. Landes , Guenter A. Jueptner , David H. Bank , Timothy T. Wenzel
IPC分类号： C08F8/00
CPC分类号： C08F299/00 , C08L9/00 , C08L23/16 , C08L2312/00 , C08L2666/08
摘要： Two or more chemically distinguishable ethylenically unsaturated polymers, at least one having from 0.001 to 50 mole percent unsaturation and at least one other having an expected Tg or measured Tm value greater than 100° C. are cross-metathesized to form thermoplastic elastomers having improved performance properties.
摘要翻译： 两种或更多种化学上可区分的烯键式不饱和聚合物，至少一种具有0.001至50摩尔％不饱和度和至少一种具有预期Tg或测量的Tm值大于100℃的其它聚合物进行交叉分层以形成具有改进性能的热塑性弹性体 属性。
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公开(公告)号：US06953764B2
公开(公告)日：2005-10-11
申请号：US10429024
申请日：2003-05-02
IPC分类号： C07F7/00 , C08F4/642 , C08F4/659 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/06 , C08F210/06 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： C08F10/02 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08F4/6411 , C08F2/06 , C08F4/659 , C08F2500/03 , C08F210/16 , C08F2500/08 , C08F2500/12
摘要： Group 4 metal complexes useful as addition polymerization catalysts of the formula: wherein G1 is a group containing from 1 to 40 atoms not counting hydrogen; T is a divalent bridging group of from 10 to 30 atoms not counting hydrogen, selected from mono- or di-aryl-substituted methylene or silylene groups or mono- or di-heteroaryl-substituted methylene or silylene groups, wherein at least one such aryl- or heteroaryl-substituent is substituted in one or both ortho-positions with a secondary or tertiary alkyl-group, a secondary or tertiary heteroalkyl group, a cycloalkyl group, or a heterocycloalkyl group, G2 is a C6-20 heteroaryl group containing Lewis base functionality, M is the Group 4 metal, X″″ is an anionic, neutral or dianionic ligand group, x″″ is a number from 0 to 5, and bonds, optional bonds and electron donative interactions are represented by lines, dotted lines and arrows respectively.
摘要翻译： 可用作下式的加成聚合催化剂的第4族金属络合物：其中G 1是含有1至40个不计氢的原子的基团; T是不计算氢的10至30个原子的二价桥连基团，选自单或二芳基取代的亚甲基或亚甲硅基或单 - 或二 - 杂芳基取代的亚甲基或亚甲硅烷基，其中至少一个这样的芳基 - 或杂芳基 - 取代基在一个或两个邻位与二级或三级烷基，二级或三级杂烷基，环烷基或杂环烷基取代，G 2是 含有路易斯碱官能团的6-20个杂芳基，M是第4族金属，X“是阴离子，中性或双离子配体基团，x”是0 至5，并且键，任选的键和电子给体相互作用分别由线，虚线和箭头表示。
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公开(公告)号：US09181368B2
公开(公告)日：2015-11-10
申请号：US14074426
申请日：2013-11-07
IPC分类号： C08F210/14 , C07F7/00 , C08F10/00 , C08F210/16 , C08F210/18 , C08F4/659 , C08F110/06 , C08F210/06
CPC分类号： C08F210/14 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , Y10S526/905 , C08F4/659 , C08F2500/04 , C08F2500/03 , C08F2500/17 , C08F2500/08 , C08F2500/20 , C08F4/6411
摘要： Group 4 metal complexes comprising a polyvalent, heteroaryl donor ligand and their use as components of olefin polymerization catalysts, especially suited for preparing propylene copolymer products having high isotacticity and low molecular weight, are disclosed.
摘要翻译： 公开了包含多价杂芳基供体配体的第4族金属络合物及其作为烯烃聚合催化剂的组分的用途，特别适用于制备具有高全同立构规整度和低分子量的丙烯共聚物产物。
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公开(公告)号：US07115689B2
公开(公告)日：2006-10-03
申请号：US10492139
申请日：2002-11-05
申请人： Joseph N. Coalter, III , Jan W. Van Egmond , Lewis J. Fouts, Jr. , Roger B. Painter , Paul C. Vosejpka
发明人： Joseph N. Coalter, III , Jan W. Van Egmond , Lewis J. Fouts, Jr. , Roger B. Painter , Paul C. Vosejpka
CPC分类号： C08J5/18 , B32B27/32 , C07B2200/11 , C07F7/00 , C08F4/65916 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08J2323/12 , C08J2323/14 , C08J2367/02 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/142 , C08L23/147 , C08L23/16 , C08L101/00 , C08L2205/02 , C08L2314/06 , C09K3/10 , C09K2200/0617 , C09K2200/062 , D01F6/06 , D01F6/30 , D01F6/46 , Y02P20/52 , Y10S526/943 , C08F4/659 , C08L2666/04 , C08L2666/06 , C08F2500/12 , C08F2500/20 , C08F2500/24 , C08F2500/15 , C08F2500/08 , C08F2500/03 , C08F2500/26 , C08F4/02 , C08F4/64144
摘要： A supported catalyst composition and process for preparing high molecular weight polymers of one or more addition polymerizable monomers, especially propylene, said composition comprising: 1) a substrate comprising the reaction product of a solid, particulated, high surface area, metal oxide, metalloid oxide, or a mixture thereof and an organoaluminum compound, 2) a Group 4 metal complex of a polyvalent, Lewis base ligand; and optionally, 3) an activating cocatalyst for the metal complex.
摘要翻译： 负载型催化剂组合物和制备一种或多种可加聚单体，特别是丙烯的高分子量聚合物的方法，所述组合物包括：1）包含固体，微粒，高表面积，金属氧化物，准金属氧化物的反应产物 ，或其混合物和有机铝化合物，2）多价路易斯碱配体的第4族金属络合物; 和任选地，3）金属络合物的活化助催化剂。
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公开(公告)号：US20140066585A1
公开(公告)日：2014-03-06
申请号：US14074426
申请日：2013-11-07
IPC分类号： C08F210/14
CPC分类号： C08F210/14 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , Y10S526/905 , C08F4/659 , C08F2500/04 , C08F2500/03 , C08F2500/17 , C08F2500/08 , C08F2500/20 , C08F4/6411
摘要： Group 4 metal complexes comprising a polyvalent, heteroaryl donor ligand and their use as components of olefin polymerization catalysts, especially suited for preparing propylene copolymer products having high isotacticity and low molecular weight, are disclosed.
摘要翻译： 公开了包含多价杂芳基供体配体的第4族金属络合物及其作为烯烃聚合催化剂的组分的用途，特别适用于制备具有高全同立构规整度和低分子量的丙烯共聚物产物。
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公开(公告)号：US08604145B2
公开(公告)日：2013-12-10
申请号：US13349860
申请日：2012-01-13
IPC分类号： C08F4/64 , C08F4/76 , C08F210/06
CPC分类号： C08F210/14 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , Y10S526/905 , C08F4/659 , C08F2500/04 , C08F2500/03 , C08F2500/17 , C08F2500/08 , C08F2500/20 , C08F4/6411
摘要： Group 4 metal complexes comprising a polyvalent, heteroaryl donor ligand and their use as components of olefin polymerization catalysts, especially suited for preparing propylene/ethylene copolymer products having high isotacticity and low molecular weight, are disclosed.
摘要翻译： 公开了包含多价杂芳基供体配体的第4族金属络合物及其作为烯烃聚合催化剂组分的用途，特别适用于制备具有高全同立构规整性和低分子量的丙烯/乙烯共聚物产物。
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