摘要:
Two or more chemically distinguishable ethylenically unsaturated polymers, at least one having from 0.001 to 50 mole percent unsaturation and at least one other having an expected Tg or measured Tm value greater than 100° C. are cross-metathesized to form thermoplastic elastomers having improved performance properties.
摘要:
Two or more chemically distinguishable ethylenically unsaturated polymers, at least one having from 0.001 to 50 mole percent unsaturation and at least one other having an expected Tg or measured Tm value greater than 100° C. are cross-metathesized to form thermoplastic elastomers having improved performance properties.
摘要:
A cross-metathesized product mixture is prepared by contacting a metathesis catalyst under metathesis conditions with a composition comprising two or more chemically distinguishable ethylenically unsaturated polymers, at least one of said ethylenically unsaturated polymers (first polymer) having from 0.001 to 50 mole percent unsaturation and at least one other of said ethylenically unsaturated polymers (second polymer) being an amorphous polymer having a Tg less than 0° C. and having from 0.001 to 5 mole percent unsaturation.
摘要:
Meta-block copolymers and a process for preparing a product mixture comprising meta-block copolymers by contacting a metathesis catalyst under metathesis conditions with a composition comprising two or more ethylenically unsaturated polymers, said unsaturation defining one or more polymer segments in each ethylenically unsaturated polymer, at least one polymer segment in at least one ethylenically unsaturated polymer being chemically distinguishable from at least one polymer segment in at least one other ethylenically unsaturated polymer, characterized in that each meta-block copolymer in the product mixture comprises a random distribution of said chemically distinguishable polymer blocks.
摘要:
A cross-metathesized product mixture is prepared by contacting a metathesis catalyst under metathesis conditions with a composition comprising two or more chemically distinguishable ethylenically unsaturated polymers, at least one of said ethylenically unsaturated polymers (first polymer) having from 0.001 to 50 mole percent unsaturation and at least one other of said ethylenically unsaturated polymers (second polymer) being an amorphous polymer having a Tg less than 0° C. and having from 0.001 to 5 mole percent unsaturation.
摘要:
Meta-block copolymers and a process for preparing a product mixture comprising meta-block copolymers by contacting a metathesis catalyst under metathesis conditions with a composition comprising two or more ethylenically unsaturated polymers, said unsaturation defining one or more polymer segments in each ethylenically unsaturated polymer, at least one polymer segment in at least one ethylenically unsaturated polymer being chemically distinguishable from at least one polymer segment in at least one other ethylenically unsaturated polymer, characterized in that each meta-block copolymer in the product mixture comprises a random distribution of said chemically distinguishable polymer blocks.
摘要:
A combinatorial method for identifying a catalyst composition for use in the homogeneous addition polymerization of an olefin monomers, said catalyst composition comprising a transition metal compound, a cocatalyst and a polymerization modifier, as well as catalyst compositions and improved olefin polymerization processes resulting therefrom.
摘要:
Cyclic oligomers containing ester linkages are polymerized in the presence of a catalyst having at least one oxygen atom bonded to two metal atoms. At least one of the metal atoms is a tin atom, which is preferably tetravalent, i.e., bonded to three other groups in addition to the oxygen atom. The other metal atom may also be another tin atom, which is again preferably tetravalent, or a zinc, aluminum or titanium atom. The catalyst may contain multiple oxygen atoms that are bonded to two such metal atoms as described. These catalysts are active, efficient polymerization catalysts. They are often liquids at polymerization temperatures. The catalysts can be formed in situ in the polymerization process, which provides additional flexibility in the process and increased storage stability of starting materials.
摘要:
A composition comprising a polymerization modifier for the copolymerization of at least one olefin monomer and propylene and a polymerization process using the polymerization modifier.
摘要:
A composition comprising a polymerization modifier for the copolymerization of at least one olefin monomer and 1-octene and a polymerization process using the polymerization modifier.