-
公开(公告)号：US07196160B2
公开(公告)日：2007-03-27
申请号：US11110051
申请日：2005-04-20
CPC分类号： C08G63/85 , C08G63/181 , C08G2650/34
摘要： Cyclic oligomers containing ester linkages are polymerized in the presence of a catalyst having at least one oxygen atom bonded to two metal atoms. At least one of the metal atoms is a tin atom, which is preferably tetravalent, i.e., bonded to three other groups in addition to the oxygen atom. The other metal atom may also be another tin atom, which is again preferably tetravalent, or a zinc, aluminum or titanium atom. The catalyst may contain multiple oxygen atoms that are bonded to two such metal atoms as described. These catalysts are active, efficient polymerization catalysts. They are often liquids at polymerization temperatures. The catalysts can be formed in situ in the polymerization process, which provides additional flexibility in the process and increased storage stability of starting materials.
摘要翻译： 含有酯键的环状低聚物在具有键合至两个金属原子的至少一个氧原子的催化剂存在下聚合。 至少一个金属原子是锡原子，其优选是四价的，即除了氧原子之外还与三个其它基团键合。 另一个金属原子也可以是另一个锡原子，其又优选为四价，或者是锌，铝或钛原子。 催化剂可以含有多个氧原子，其与所述的两个这样的金属原子键合。 这些催化剂是活性的，有效的聚合催化剂。 它们在聚合温度下通常是液体。 催化剂可以在聚合过程中原位形成，这在工艺中提供了额外的灵活性并提高了原料的储存稳定性。
-
2.发明授权Hydro-oxidation process using a catalyst prepared from a gold cluster complex 失效使用由金簇复合物制备的催化剂的水解 - 氧化方法公开(公告)号：US08288311B2
公开(公告)日：2012-10-16
申请号：US12445547
申请日：2007-11-07
申请人： Sandeep S. Dhingra , Rick C. Schroden , Keith J. Watson , David G. Barton , Robert G. Bowman , Larry N. Ito , David L. Trent , Heiko Weiner
发明人： Sandeep S. Dhingra , Rick C. Schroden , Keith J. Watson , David G. Barton , Robert G. Bowman , Larry N. Ito , David L. Trent , Heiko Weiner
CPC分类号： B01J31/2404 , B01J23/52 , B01J23/66 , B01J29/89 , B01J31/1691 , B01J35/0013 , B01J37/0203 , B01J2229/186 , B01J2231/325 , B01J2231/72 , B01J2531/18 , B01J2531/62 , B01J2531/842 , C07D301/10 , Y02P20/52 , Y02P20/588
摘要： A process and catalyst for the hydro-oxidation of an olefin having three or more carbon atoms, such as propylene, to form an olefin oxide, such as propylene oxide. The process involves contacting the olefin with oxygen in the presence of hydrogen and a hydro-oxidation catalyst under reaction conditions; the catalyst comprising gold nanoparticles deposited on a nanoporous titanium-containing support, prepared by depositing a gold-ligand cluster complex onto the support to form a catalyst precursor, and then heating and/or chemically treating the catalyst precursor to form the hydro-oxidation catalyst composition. The hydro-oxidation catalyst exhibits stabilized catalyst activity, enhanced lifetime, and improved hydrogen efficiency.
摘要翻译： 用于将具有三个或更多个碳原子的烯烃如丙烯进行加氢氧化的方法和催化剂，以形成环氧丙烷等烯烃氧化物。 该方法包括在氢气和氢氧化催化剂存在下，在反应条件下使烯烃与氧接触; 催化剂包含沉积在纳米多孔含钛载体上的金纳米颗粒，其通过在载体上沉积金 - 配体簇复合物以形成催化剂前体，然后加热和/或化学处理催化剂前体以形成加氢氧化催化剂 组成。 氢氧化催化剂表现出稳定的催化剂活性，寿命延长，氢效率提高。
-
3.发明申请HYDRO-OXIDATION PROCESS USING A CATALYST PREPARED FROM A GOLD CLUSTER COMPLEX 失效使用从金色复合物制备的催化剂的氢氧化工艺公开(公告)号：US20100076208A1
公开(公告)日：2010-03-25
申请号：US12445547
申请日：2007-11-07
申请人： Sandeep S. Dhingra , Rick C. Schroden , Keith J. Watson , David G. Barton , Robert G. Bowman , Larry N. Ito , David L. Trent , Heiko Weiner
发明人： Sandeep S. Dhingra , Rick C. Schroden , Keith J. Watson , David G. Barton , Robert G. Bowman , Larry N. Ito , David L. Trent , Heiko Weiner
IPC分类号： C07D301/04 , B01J23/52 , B01J23/50 , B01J23/66 , C07D301/06
CPC分类号： B01J31/2404 , B01J23/52 , B01J23/66 , B01J29/89 , B01J31/1691 , B01J35/0013 , B01J37/0203 , B01J2229/186 , B01J2231/325 , B01J2231/72 , B01J2531/18 , B01J2531/62 , B01J2531/842 , C07D301/10 , Y02P20/52 , Y02P20/588
摘要： A process and catalyst for the hydro-oxidation of an olefin having three or more carbon atoms, such as propylene, to form an olefin oxide, such as propylene oxide. The process involves contacting the olefin with oxygen in the presence of hydrogen and a hydro-oxidation catalyst under reaction conditions; the catalyst comprising gold nanoparticles deposited on a nanoporous titanium-containing support, prepared by depositing a gold-ligand cluster complex onto the support to form a catalyst precursor, and then heating and/or chemically treating the catalyst precursor to form the hydro-oxidation catalyst composition. The hydro-oxidation catalyst exhibits stabilized catalyst activity, enhanced lifetime, and improved hydrogen efficiency.
摘要翻译： 用于将具有三个或更多个碳原子的烯烃如丙烯进行加氢氧化的方法和催化剂，以形成环氧丙烷等烯烃氧化物。 该方法包括在氢气和氢氧化催化剂存在下，在反应条件下使烯烃与氧接触; 催化剂包含沉积在纳米多孔含钛载体上的金纳米颗粒，其通过在载体上沉积金 - 配体簇复合物以形成催化剂前体，然后加热和/或化学处理催化剂前体以形成加氢氧化催化剂 组成。 氢氧化催化剂表现出稳定的催化剂活性，寿命延长，氢效率提高。
-
4.发明授权Aqueous developable, photosensitive benzocyclobutene-based oligomers and polymers with high moisture resistance 有权水性可显影，光敏苯并环丁烯低聚物和具有高耐湿性的聚合物公开(公告)号：US07198878B2
公开(公告)日：2007-04-03
申请号：US11146818
申请日：2005-06-07
申请人： Ying Hung So , Scott J. Bis , Keith J. Watson
发明人： Ying Hung So , Scott J. Bis , Keith J. Watson
摘要： The invention is a photoswitchable benzocyclobutene-based polymer that while remaining aqueous developable, avoids the problem of significant moisture uptake. The oligomer or polymer comprises a polymeric backbone, benzocyclobutene reactive groups, and photoswitchable pendant groups. The pendant groups are bonded to the polymeric backbone and are characterized by the presence of a moiety that converts to carboxylic acid upon exposure to activating wavelengths of radiation a carboxylic acid. When the oligomer or polymer is subsequently heated to cause cure of the oligomer or polymer, carbon dioxide is emitted and the group forms a substantially non-polar moiety. The invention is also a method of making such a polymer and a method of forming a patterned film using such a polymer.
摘要翻译： 本发明是一种可光切换的基于苯并环丁烯的聚合物，其在保持水可显影的同时，避免了显着吸湿的问题。 低聚物或聚合物包含聚合物主链，苯并环丁烯反应性基团和可照照开关的侧基。 侧基键合到聚合物骨架上，其特征在于存在一个部分，当暴露于活化的辐射波长的羧酸时，该部分转变成羧酸。 当低聚物或聚合物随后被加热以使低聚物或聚合物固化时，发出二氧化碳，并且该基团形成基本上非极性部分。 本发明也是制造这种聚合物的方法和使用这种聚合物形成图案化膜的方法。
-
5.发明授权Aqueous developable, photosensitive benzocyclobutene-based oligomers and polymers with high moisture resistance 有权水性可显影，光敏苯并环丁烯低聚物和具有高耐湿性的聚合物公开(公告)号：US07019093B2
公开(公告)日：2006-03-28
申请号：US10273540
申请日：2002-10-18
申请人： Ying Hung So , Keith J. Watson , Scott J. Bis
发明人： Ying Hung So , Keith J. Watson , Scott J. Bis
摘要： The invention is a photoswitchable benzocyclobutene-based polymer that while remaining aqueous developable, avoids the problem of significant moisture uptake. The oligomer or polymer comprises a polymeric backbone, benzocyclobutene reactive groups, and photoswitchable pendant groups. The pendant groups are bonded to the polymeric backbone and are characterized by the presence of a moiety that converts to carboxylic acid upon exposure to activating wavelengths of radiation a carboxylic acid. When the oligomer or polymer is subsequently heated to cause cure of the oligomer or polymer, carbon dioxide is emitted and the group forms a substantially non-polar moiety. The invention is also a method of making such a polymer and a method of forming a patterned film using such a polymer.
摘要翻译： 本发明是一种可光切换的基于苯并环丁烯的聚合物，其在保持水可显影的同时，避免了显着吸湿的问题。 低聚物或聚合物包含聚合物主链，苯并环丁烯反应性基团和可照照开关的侧基。 侧基键合到聚合物骨架上，其特征在于存在一个部分，当暴露于活化的辐射波长的羧酸时，该部分转变成羧酸。 当低聚物或聚合物随后被加热以使低聚物或聚合物固化时，发出二氧化碳，并且该基团形成基本上非极性部分。 本发明也是制造这种聚合物的方法和使用这种聚合物形成图案化膜的方法。
-
-
-
-
搜索结果
5 条记录 (耗时 0.025 秒)
